Barrier Layer Electrode Process for Low Resistance Connections

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

The existing methods for forming electrodes in electronic devices face challenges in achieving low resistance and high physical strength connections between substrates and packages, often compromised by insulating materials and requiring high-temperature processes that are not practical in all equipment setups.

Innovation Solution

A process involving the formation of an adhesion layer, a barrier layer, and a conductive layer on the substrate's second surface, where the adhesion layer is deposited using chemical vapor deposition without breaking vacuum, and the barrier layer is formed using titanium to prevent diffusion and maintain connection strength, independent of mount process temperature.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If argon sputter etch is used to remove insulating material, then electrical resistance is reduced, but physical connection strength is compromised

Engineering Contradiction:
Improveelectrical connection qualityVSAvoidphysical connection strength
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The substrate surface is prepared through mechanical polishing and chemical cleaning before electrode deposition, creating a clean surface that enables both strong adhesion and low resistance without requiring aggressive sputter etching

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent changes the surface preparation method from physical sputter etching to chemical-mechanical polishing and chemical cleaning, altering the approach from removing material aggressively to preparing the surface gently, thereby maintaining both electrical and mechanical properties

Inventive Principle:
Principle #35Parameter changes

2Strength

If native oxide is formed to improve physical connection, then adhesion is improved, but electrical resistance increases

Engineering Contradiction:
Improveadhesion strengthVSAvoidelectrical connection quality
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The substrate surface is cleaned and prepared before electrode deposition to ensure proper adhesion without forming thick native oxide layers that would increase electrical resistance

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent controls the oxidation state of the substrate surface through chemical cleaning and timing of deposition, maintaining just enough oxide for adhesion while preventing excessive oxide formation that would harm electrical conductivity

Inventive Principle:
Principle #35Parameter changes

3Strength

If high temperature baking is performed to improve connection, then adhesion is enhanced, but equipment complexity and cost increase

Engineering Contradiction:
Improveconnection strengthVSAvoidequipment complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

Adhesion is established through surface preparation and controlled deposition processes performed at lower temperatures, eliminating the need for subsequent high-temperature baking steps

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent replaces thermal processing (high-temperature baking) with chemical-mechanical polishing and chemical cleaning processes, substituting a thermal field approach with chemical and mechanical approaches to achieve adhesion

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

4Reliability

If high temperature processes are used for electrode formation, then connection quality is improved, but adaptability to equipment is reduced

Engineering Contradiction:
Improveconnection qualityVSAvoidequipment compatibility
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The patent changes the temperature parameter from high (380°C or greater) to low (below 380°C), enabling the process to be performed in standard deposition equipment without specialized heat control, thereby improving equipment compatibility while maintaining connection quality

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach provides an improved physical and electrical connection with reduced resistance, independent of the mount process temperature, and can be performed in a wider variety of equipment setups, reducing equipment replacement costs and process complexity.

Implementation Method 1

the adhesion layer is deposited using chemical vapor deposition without breaking vacuum

Methodology Applied
Scientific EffectChemical vapor deposition: Chemical Vapour Deposition

Implementation Method 2

the barrier layer is formed using titanium to prevent diffusion and maintain connection strength

Methodology Applied
Scientific EffectDiffusion barrier: Diffusion Barrier

Data Source

PatentUS7595257B2Process of forming an electronic device including a barrier layer
Publication Date: 2009.09.29 NXP USA INC
  • US7595257B2 patent drawing
  • US7595257B2 patent drawing
  • US7595257B2 patent drawing

AI summary

An electronic device can include a substrate (12) having a primary surface (14), a second surface (16, 22) opposite the primary surface (14), and an electrode (50). In one embodiment, the electrode (50) can lie adjacent to the second surface (22) and include, a barrier layer (54) lying between a conductive layer (56) and a metal-containing layer (52), wherein the metal-containing layer (52) includes a first metallic element and not a second metal element, and the barrier layer (54) includes the second metal element and not the first metallic element. In another embodiment, an adhesion layer (52) and a conductive layer (56) can each include a metallic element, and lie immediately adjacent to a barrier layer (54). In still another embodiment, a process for forming an electronic device can include removing a portion of the substrate (12) opposite a primary surface (14).