Barrier Ply for Composite Adhesive Bonding

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Solution Overview

Problem

The commercial air transport fleet is expected to double by 2035, requiring efficient composite structures, but current adhesive bonding methods in composite manufacturing are uncertain due to contamination issues and lack of predictable bond strength, necessitating redundant fasteners and costly co-cure processes.

Innovation Solution

The use of a barrier ply that gels early in the cure cycle to prevent excessive mixing between conventional and stoichiometrically-offset composite precursors, improving the mechanical properties and efficiency of composite production while reducing the likelihood of delamination.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Device complexity

If adhesive bonding methods are used to join composite structures, then manufacturing complexity is reduced compared to co-cure processes, but bond strength becomes uncertain due to contamination and material discontinuity

Engineering Contradiction:
Improvemanufacturing complexityVSAvoidbond strength
Core Design Contradiction:
Device complexityVSReliability

Solution Approach 1:

A barrier ply is introduced as an intermediary layer between the adhesive and the composite substrate. This barrier ply prevents contamination from reaching the adhesive interface while providing a controlled bonding surface, thus maintaining reliable bond strength without requiring complex co-cure tooling

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The barrier ply creates a localized controlled environment at the bonding interface, where the adhesive bonds to the barrier ply rather than directly to the composite substrate. This local modification ensures consistent bond properties without affecting the overall composite structure or requiring complex manufacturing processes

Inventive Principle:
Principle #3Local quality

2Reliability

If co-cure processes are used to join composite preforms, then predictable joint properties are achieved, but manufacturing cost and technical complexity increase due to specialized mold and tool requirements

Engineering Contradiction:
Improvejoint properties predictabilityVSAvoidmold and tool requirements
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The barrier ply serves as a mediator that enables secondary bonding to achieve joint properties comparable to co-cure. By controlling the interface between adhesive and composite through this intermediate layer, predictable joint properties are obtained without requiring expensive co-cure tooling

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The barrier ply is pre-applied to the composite substrate before adhesive bonding. This preliminary action creates a prepared bonding surface that ensures consistent adhesive performance and predictable joint properties, eliminating the need for complex co-cure molds while maintaining reliability

Inventive Principle:
Principle #10Preliminary action

3Strength

If adhesive bonds are made sensitive to contamination for stronger bonding, then bond strength may improve, but measurement precision and quality control become more difficult

Engineering Contradiction:
Improveadhesive bond strengthVSAvoidbond quality assessment
Core Design Contradiction:
StrengthVSMeasurement precision

Solution Approach 1:

The barrier ply acts as a protective intermediary that prevents contamination from compromising the adhesive bond. This allows the adhesive interface to remain clean and controlled, making bond quality easier to measure and assess without requiring destructive testing or complex quality control procedures

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances the mechanical properties and manufacturing efficiency of composite products, allowing for predictable material properties and reduced delamination risks, thereby addressing the challenges of bond strength uncertainty and process costs.

Implementation Method 1

The barrier-ply prevents excessive mixing between conventional composite precursors and stoichiometrically-offset precursors during a cure process by gelling early in the cure cycle before extensive mixing can occur

Methodology Applied
Scientific EffectGelation: Gel

Data Source

PatentUS20220168970A1Composites produced with a barrier ply and methods for making the same
Publication Date: 2022.06.02 UNITED STATES OF AMERICA AS REPRESENTED BY THE ADMINISTRATOR NAT AERONAUTICS & SPACE ADMINISTRATION
  • US20220168970A1 patent drawing
  • US20220168970A1 patent drawing
  • US20220168970A1 patent drawing

AI summary

Described herein are composites produced with a barrier ply. The barrier-ply prevents excessive mixing between conventional composite precursors and stoichiometrically-offset precursors during a cure process by gelling early in the cure cycle before extensive mixing can occur. Excess mixing requires the use of thicker offset resin layers with a large stoichiometric offset, which may limit the performance of unitized structures. The use of the barrier plies described herein address this issue and improves the mechanical properties of the final composite product as well as the efficiency for making the composites.