Multilayer Battery Case Wall for Electric Arc Protection
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Solution Overview
Problem
Existing battery cell, submodule, and system cases lack effective heat dissipation and resistance to electric arcs, which can lead to temperature increases, damage, and hazardous gas release.
Innovation Solution
A multilayer wall structure comprising an electrically insulating first layer, a thermally insulating ablative second layer, and a thermally conductive third layer, where the second layer delays heat transport and the third layer distributes heat over a larger area, preventing peak temperatures and mechanical instability.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Reliability
If a single-layer case structure is used, then the device complexity is low, but the heat dissipation performance and resistance to electric arcs are insufficient
Solution Approach 1:
The case wall is divided into three distinct functional layers: an inner electrically insulating layer (polymer material) to resist electric arcs, a middle ablative layer (intumescent or carbon-forming material) to manage heat through phase change and material loss, and an outer structurally strong layer (metal material) to maintain mechanical integrity. This segmentation allows each layer to specialize in one protective function, resolving the contradiction between reliability and complexity.
Solution Approach 2:
The case employs a composite multilayer structure combining different materials with complementary properties: electrically insulating polymers for arc resistance, ablative materials for thermal management, and metals for structural strength. This composite approach achieves superior overall performance that cannot be obtained with a single material, directly addressing the reliability requirement while accepting necessary structural complexity.
2Temperature
If the case wall is made thin to reduce weight, then the weight decreases, but the heat dissipation capability and mechanical strength are reduced
Solution Approach 1:
Each layer of the case wall has locally optimized properties tailored to its specific function: the inner layer has high electrical insulation properties, the middle layer has ablative characteristics for heat absorption, and the outer layer has high thermal conductivity and mechanical strength. This local quality optimization allows the case to achieve superior heat dissipation and arc resistance without requiring uniform thickness throughout, managing the weight-performance trade-off.
Solution Approach 2:
The middle ablative layer utilizes phase transitions (intumescence, carbonization, or melting) to absorb excessive heat from electric arcs and thermal runaway events. This phase change mechanism provides passive thermal management that protects the battery components without requiring active cooling systems, improving heat dissipation capability while keeping the case structure relatively lightweight.
3Reliability
If conventional single-layer case material is used, then the manufacturing process is simple, but the case cannot withstand electric arcs and high temperatures
Solution Approach 1:
The protective functions are built into the case structure during manufacturing through pre-applied coatings or laminated layers. The ablative layer is pre-coated onto the case wall, and the electrically insulating layer is integrated during case fabrication. This preliminary action ensures protection is already in place before the battery is assembled, maintaining manufacturing simplicity while achieving arc resistance.
Solution Approach 2:
The middle ablative layer is designed as a sacrificial component that consumes itself during thermal events to protect the valuable battery components. This disposable layer absorbs the damage from electric arcs and high temperatures, allowing the expensive battery cells and electronics to remain protected. This approach achieves high reliability at reasonable manufacturing cost by sacrificing a relatively inexpensive material layer.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The multilayer structure effectively manages heat dissipation and maintains mechanical stability during electric arcing, reducing the risk of case damage and hazardous gas release, thereby enhancing the safety and service life of battery systems.
Implementation Method 1
the first layer is configured for electrically insulating the second layer from an inner portion of the case
Implementation Method 2
the second layer comprises an ablative material and is configured for thermally shielding the third layer
Implementation Method 3
The third layer comprises a thermal conductivity that is higher than that of the second layer. The third layer is thus configured to distribute any heat that is transferred to the third layer
Implementation Method 4
the second layer comprises an ablative material and is configured for thermally shielding the third layer
Data Source
Figure 1
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Figure 4
AI summary
The present invention refers to a wall structure (60) of a case (26, 30, 93, 96, 101) of one selected of a battery cell (80), a battery submodule (90), a battery module and a battery system (100) as well as to a battery cell (80), a battery submodule (90), a battery module and a battery system (100) comprising such wall structure (60). The multilayer wall structure (60) has a first layer (61) facing an inner side (64) of the case (26, 30, 93, 96, 101), a third layer (63) facing an outer side (65) of the case (26, 30, 93, 96, 101) and a second layer (62) in between the first layer (61) and the third layer (63). According to the present invention, the first layer (61) is configured for electrically insulating the second layer (62) from an inner portion of the case (26, 30, 93, 96, 101), the second layer (62) comprises an ablative material and is configured for thermally shielding the third layer (63), and the third layer (63) comprises a thermal conductivity that is higher than that of the second layer (62). The ablative material is configured to dissipate a great quantity of heat due to sacrifice of material in an ablation process. Preferably, the ablative material is configured to transit into such ablation process in response to an electric arc impinging the first layer (61). Thus, the second layer (62) thermally shields the third layer (63) that might correspond to a conventional case and prevents a breach of the case during electric arcing within the case (26, 30, 93, 96, 101).