Battery Cooling Fluid Composition With Flame Retardant Protection
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Solution Overview
Problem
Current cooling systems for electric and hybrid vehicle propulsion systems, particularly batteries and power electronics, are insufficient in managing heat and do not adequately prevent fire risks, leading to potential overheating and explosions.
Innovation Solution
A cooling composition comprising a hydrocarbon fluid with a boiling point greater than 50°C and a fluorinated flame retardant, which is used in direct contact with batteries and power electronics to provide both cooling and fire resistance, delaying or preventing the spread of fire in case of ignition.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Temperature
If traditional cooling methods (air or water with glycol) are used, then cooling is provided, but the cooling is insufficient and fire risk is not prevented
Solution Approach 1:
The patent changes the chemical composition parameters of the cooling fluid by incorporating fluorinated compounds with specific molecular structures (CF3 groups) and maintaining precise concentration ratios (5-20% fluorinated compound, 80-95% hydrocarbon). This parameter optimization enables the fluid to simultaneously achieve superior heat transfer coefficients and fire suppression capabilities, resolving the contradiction between cooling effectiveness and fire safety
Solution Approach 2:
The patent creates a composite cooling fluid by combining hydrocarbon base fluids (isoparaffins, naphthenes, or aromatics) with fluorinated compounds (perfluorinated or partially fluorinated). This composite formulation synergistically integrates the high heat capacity and thermal conductivity of hydrocarbons with the fire-resistant properties of fluorinated compounds, achieving both effective cooling and fire protection simultaneously
2Reliability
If halogenated compounds are used for fire resistance, then ignition resistance is provided, but cost increases and environmental harm occurs
Solution Approach 1:
The patent employs fluorinated compounds that function as fire inhibitors through chemical mechanisms (radical scavenging, flame interference) rather than relying on persistent physical barriers. These compounds work effectively in smaller quantities and can be part of a replaceable cooling fluid system, reducing the need for large amounts of persistent heavy halogenated compounds while maintaining fire protection
Solution Approach 2:
The patent optimizes the fluorine-to-carbon ratio and molecular structure parameters of the fluorinated compounds used. By selecting specific fluorinated compounds with appropriate chain lengths and substitution patterns, the patent achieves effective fire resistance with lower concentrations compared to traditional heavy halogenated compounds, thereby reducing environmental persistence and toxicity while maintaining ignition resistance
3Reliability
If halogenated compounds are used for fire resistance, then ignition resistance is provided, but vehicle mass increases
Solution Approach 1:
The patent optimizes the density parameter by selecting fluorinated compounds with lower molecular weights and appropriate carbon chain lengths. The formulation achieves fire resistance through optimized chemical composition rather than relying on high-density heavy halogenated compounds, thereby maintaining lower overall fluid density and reducing the mass of the cooling system
Solution Approach 2:
The patent applies fire resistance locally through the chemical action of fluorinated compounds at the molecular level during combustion events. Rather than requiring the entire cooling fluid to be dense halogenated compound, the patent uses a small concentration (5-20%) of fluorinated compounds that activate specifically when fire occurs, providing fire protection without requiring the bulk fluid to have high density
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The composition effectively cools the batteries and power electronics while ensuring safety by preventing the propagation of fire, thereby enhancing the reliability and safety of electric and hybrid vehicle propulsion systems.
Implementation Method 1
at least one flame retardant, and more particularly a fluorinated flame retardant of formula (I)... said composition being free of water... delaying or preventing the spread of fire
Implementation Method 2
cooling is carried out on several parts of the propulsion system that generate heat... in order to avoid reaching dangerous temperatures
Implementation Method 3
cooling composition... comprising: (i) at least one hydrocarbon fluid having a boiling point greater than or equal to 50°C... ensuring the cooling of the battery
Data Source
Figure 1
AI summary
The invention relates to a composition for cooling a propulsion system of an electric or hybrid vehicle, comprising (i) at least one hydrocarbon fluid having a boiling point of at least 50°C, and (ii) at least one flame retardant of formula (I) RF-L-RH (I), where RF is a perfluorinated or partially fluorinated group, RH is a hydrocarbon group, and L is a linking agent. The invention also relates to the use of at least one flame retardant of formula (I) in a composition for cooling a propulsion system of an electric or hybrid vehicle, more particularly the power electronics and batteries thereof, in order to impart flame-retardant properties thereto, said cooling composition comprising at least one hydrocarbon fluid having a boiling point of at least 50°C. Finally, the invention relates to a method for cooling and fireproofing at least one battery of a propulsion system of an electric or hybrid vehicle, comprising at least one step of bringing at least one battery into contact with a composition according to the invention.