Battery Electrode Surface Carbon Gradient for Stable Conduction
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Solution Overview
Problem
The uneven distribution of conductive additives in the active material layer of electrodes leads to poor electron conduction paths, resulting in decreased discharge capacity retention rates of batteries.
Innovation Solution
The electrode design includes a surface layer with a carbon atom concentration greater than 29.8% at the main surface not in contact with the support, ensuring even distribution of carbon-based conductive additives, which facilitates better electron conduction paths.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Reliability
If conductive additives are added to the active material layer, then electron conduction is improved, but uneven distribution of conductive additives occurs leading to poor electron conduction paths
Solution Approach 1:
The patent applies local quality by creating a surface layer with higher carbon atom concentration (greater than 29.8 at %) at the first main surface of the active material layer. This localized concentration of conductive additives at the surface ensures adequate electron conduction paths without requiring uniform distribution throughout the entire layer, thus resolving the contradiction between improving discharge capacity retention and maintaining compositional uniformity.
2Reliability
If carbon-based conductive additives are distributed evenly, then electron conduction paths are improved, but the complexity of controlling additive distribution increases
Solution Approach 1:
The patent changes the concentration parameter of carbon-based conductive additives by specifying that the carbon atom concentration at the surface layer portion must be greater than 29.8 at %. This parameter change approach simplifies the control of conductive additive distribution by focusing on achieving a specific concentration threshold at the surface rather than controlling uniform distribution throughout the entire layer.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
This design improves the discharge capacity retention rate of the battery by enhancing electron exchange and reducing inner resistance.
Implementation Method 1
a carbon-based conductive additive... facilitates better electron conduction paths
Data Source
AI summary
An electrode of the present disclosure includes a support and an active material layer that contains an active material, a solid electrolyte, and a carbon-based conductive additive and that has a first main surface not in contact with the support and a second main surface in contact with the support, in which a carbon atom concentration of a surface layer portion of the active material layer at the first main surface is greater than 29.8 at %.


