Lithium-ion Battery Electrode Density Gradient Design

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Solution Overview

Problem

Lithium-ion secondary batteries face performance drops due to high manufacturing costs and reduced capacity caused by the uneven distribution of high-density and low-density portions in the electrode mixture layers, leading to inefficient electrolyte impregnation and increased manufacturing steps.

Innovation Solution

A lithium-ion secondary battery design featuring high-density and low-density portions with a smaller area ratio in the electrode mixture layers, optimized for improved electrolyte impregnation and capacity retention, achieved through controlled application and rolling of the electrode coating material, with a density gradient region at the boundary to enhance solution penetration.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Power

If high-density and low-density portions are periodically disposed at narrow intervals to balance lithium ion conduction and electron conduction rates, then output characteristic is improved, but the proportion of low-density portion becomes equal to or higher than high-density portion, lowering mixture layer capacity

Engineering Contradiction:
Improveoutput characteristicVSAvoidmixture layer capacity
Core Design Contradiction:
PowerVSQuantity of substance

Solution Approach 1:

The invention applies local quality by creating distinct high-density portions and low-density portions with different mixture densities within the same electrode plate. The high-density portions have higher active material concentration for capacity, while low-density portions have lower concentration for better electrolyte penetration. This local differentiation resolves the contradiction by allowing each region to optimize for its specific function rather than using a uniform structure throughout.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The invention employs asymmetry by making the high-density portions larger in area than the low-density portions, breaking the symmetric alternating pattern of equal-sized regions. This asymmetric design ensures that the total capacity-contributing high-density regions dominate the electrode plate area, while the smaller low-density regions provide sufficient electrolyte pathways without compromising overall capacity.

Inventive Principle:
Principle #4Asymmetry

2Power

If a second mixture layer is applied to predetermined regions and dried and rolled to form high-density portions, then conduction rates are balanced, but the manufacturing process requires extra steps of re-applying electrode coating material, increasing manufacturing cost

Engineering Contradiction:
Improveconduction rate balanceVSAvoidmanufacturing cost
Core Design Contradiction:
PowerVSEase of manufacture

Solution Approach 1:

The invention applies preliminary action by incorporating the density differentiation directly into the initial electrode coating application process. Instead of applying a uniform coating and then adding a second layer to create high-density portions, the method initially applies the electrode coating material with spatially varying thickness or composition to directly form both high-density and low-density portions in a single step, eliminating subsequent re-application operations.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The invention merges the functions of creating density variations and forming the electrode structure into a single coating and drying process. By combining what would otherwise be separate operations (applying coating material, creating density variations, drying, rolling) into an integrated process where the coating application itself establishes the density pattern, the manufacturing complexity and cost are reduced while maintaining the conduction rate balance.

Inventive Principle:
Principle #5Merging (Combining)

Data Source

PatentUS10847803B2Lithium-ion secondary battery and method of manufacture thereof
Publication Date: 2020.11.24 PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO LTD
  • US10847803B2 patent drawing
  • US10847803B2 patent drawing
  • US10847803B2 patent drawing

AI summary

A lithium-ion secondary battery that includes an electricity-generating unit that includes: a positive electrode having a positive electrode collector, and a positive electrode mixture layer formed on a surface of the positive electrode collector; a negative electrode having a negative electrode collector, and a negative electrode mixture layer formed on a surface of the negative electrode collector; and a separator disposed between the positive electrode and the negative electrode. At least one of the positive electrode mixture layer and the negative electrode mixture layer has a high-density portion of high mixture density, and a low-density portion having a lower mixture density than the high-density portion and being in contact with the high-density portion. The low-density portion has a smaller area than the high-density portion when viewed in plan.