Non-Aqueous Battery Electrode Resin Layout for High-Rate Heat Control

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Solution Overview

Problem

Non-aqueous electrolyte secondary batteries face challenges in maintaining high rate resistance due to temperature rise, which leads to electrolyte outflow and increased internal resistance, especially at the end portions of the electrode body.

Innovation Solution

Incorporating a resin portion made of swellable resin in the mixture layer non-forming areas of the electrodes, which increases the thermal capacity of the end portions and effectively suppresses temperature rise, thereby improving high rate resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Power

If a sheet-shaped electrode body is used for high rate charge and discharge, then power output is improved, but temperature rise occurs leading to electrolyte outflow and increased internal resistance

Engineering Contradiction:
Improvepower outputVSAvoidtemperature rise
Core Design Contradiction:
PowerVSTemperature

Solution Approach 1:

The patent applies local quality by forming resin portions specifically at the end portions of the electrode body where temperature rise is most severe during high rate charge and discharge. These resin portions are not uniformly distributed but localized to the critical heat-generating areas, providing targeted thermal management where it is most needed while maintaining power output performance.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent uses composite materials by combining resin portions with the electrode body structure. The resin portions are formed of swellable resin that absorbs electrolyte, creating a composite structure that integrates thermal management functionality directly into the electrode body without requiring separate cooling systems.

Inventive Principle:
Principle #40Composite materials

2Temperature

If the amount of non-aqueous electrolyte held in the center portion is increased, then temperature rise of the center portion is suppressed, but outflow of electrolyte from the end portion cannot be sufficiently suppressed

Engineering Contradiction:
Improvetemperature of center portionVSAvoidelectrolyte outflow from end portion
Core Design Contradiction:
TemperatureVSLoss of substance

Solution Approach 1:

The patent addresses this contradiction by applying local quality differently - instead of uniformly increasing electrolyte holding throughout, it locally concentrates electrolyte absorption capacity at the end portions through resin portions. This localized approach specifically targets the problem area (end portions) where electrolyte outflow occurs, while the center portion maintains its original electrolyte distribution.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The resin portions act as intermediaries that absorb and retain electrolyte at the end portions. These resin portions serve as a buffer between the electrolyte and the external environment, preventing direct outflow while maintaining the electrolyte supply to active materials during high rate operations.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Productivity

If rapid charge and discharge is performed, then power output is improved, but internal resistance increases due to electrolyte outflow

Engineering Contradiction:
Improvecharge and discharge rateVSAvoidhigh rate resistance
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent applies preliminary action by pre-forming resin portions at the end portions of the electrode body before high rate charge and discharge operations begin. These resin portions are pre-positioned to absorb electrolyte in advance, creating a reservoir that prevents electrolyte outflow during subsequent rapid charge and discharge cycles, thereby maintaining low internal resistance.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The resin portions provide beforehand cushioning by absorbing excess electrolyte and creating a buffer zone at the end portions. This cushioning effect prevents the harmful outflow of electrolyte during high rate operations, protecting the battery's internal resistance from increasing while allowing high productivity operations to proceed.

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of swellable resin in the non-forming portions of the electrode mixture layers enhances thermal capacity and uniformly reduces temperature unevenness, effectively improving the high rate resistance of the non-aqueous electrolyte secondary battery.

Implementation Method 1

a resin portion substantially formed of a swellable resin having a property of swelling the non-aqueous electrolyte

Methodology Applied
Scientific EffectSwelling: Absorption (physical)

Data Source

PatentUS11862788B2Non-aqueous electrolyte secondary battery
Publication Date: 2024.01.02 TOYOTA JIDOSHA KK
  • US11862788B2 patent drawing
  • US11862788B2 patent drawing
  • US11862788B2 patent drawing

AI summary

A non-aqueous electrolyte secondary battery, in which a positive electrode includes a positive electrode mixture layer in which a mixture containing a positive electrode active material is formed and a positive electrode mixture layer non-forming portion in which the positive electrode mixture layer is not formed, and a negative electrode includes a negative electrode mixture layer in which a mixture containing a negative electrode active material is formed and a negative electrode mixture layer non-forming portion in which the negative electrode mixture layer is not formed. At least one of the positive electrode mixture layer non-forming portion and the negative electrode mixture layer non-forming portion has a resin portion substantially formed of a swellable resin having a property of swelling the non-aqueous electrolyte.