Lithium Battery Electrolyte Additives for High-Temperature Cycle Life
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Solution Overview
Problem
Rechargeable lithium batteries face challenges in maintaining cycle life characteristics and suppressing resistance increase and gas generation at high temperatures.
Innovation Solution
An electrolyte comprising a non-aqueous organic solvent, lithium salt, a first additive represented by Chemical Formula 1, and a second additive represented by Chemical Formula 2, which includes specific functional groups and concentrations to enhance performance at high temperatures.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Reliability
If conventional electrolytes are used in rechargeable lithium batteries, then the batteries can operate at high temperatures, but the cycle life characteristics deteriorate and resistance increases
Solution Approach 1:
The patent modifies the chemical composition parameters of the electrolyte by introducing specific additives (first additive with isocyanate groups and second additive with electron-withdrawing groups) to change the chemical environment at the electrode interface. This parameter change enables the electrolyte to form stable protective films that prevent resistance increase and maintain cycle life at high temperatures
Solution Approach 2:
The patent creates a composite electrolyte system by combining multiple components: non-aqueous organic solvent, lithium salt, first additive (isocyanate-containing compound), and second additive (compound with electron-withdrawing groups). This composite formulation works synergistically to suppress resistance increase and improve high-temperature cycle life characteristics
2Object-generated harmful factors
If conventional electrolytes are used in rechargeable lithium batteries, then the batteries can function at high temperatures, but gas generation increases
Solution Approach 1:
The patent changes the chemical parameters of the electrolyte by incorporating specific functional groups (isocyanate groups in the first additive and electron-withdrawing groups in the second additive) that modify the electrochemical behavior at high temperatures. These parameter changes suppress unwanted side reactions that lead to gas generation during high-temperature storage
Solution Approach 2:
The patent converts the potentially harmful high-temperature environment into a beneficial condition by using the heat to promote the formation of stable protective films through the additive components. The high temperature accelerates the formation of stable SEI layers that actually protect against further degradation and gas generation
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The electrolyte effectively suppresses resistance increase and gas generation, improving cycle life characteristics and high-temperature stability of rechargeable lithium batteries.
Implementation Method 1
A lithium salt dissolved in a non-aqueous organic solvent is used as the electrolyte of the rechargeable lithium battery
Implementation Method 2
Electrical energy is produced (generated) via oxidation and reduction reactions if (e.g., when) lithium ions are intercalated and deintercalated
Implementation Method 3
a first additive represented by Chemical Formula 1... wherein at least one selected from among R1(s) is an isocyanate group, wherein at least one selected from among R2(s) is an isocyanate group
Implementation Method 4
a second additive represented by Chemical Formula 2... R4 may be identical to or different from each other and may each independently be hydrogen, a halogen, a cyano (CN) group, a nitro (NO2) group, or a C1 to C5 alkyl group
Data Source
AI summary
Electrolytes and rechargeable lithium batteries are disclosed. The electrolyte includes a non-aqueous organic solvent, a lithium salt, a first additive represented by Chemical Formula 1, and a second additive represented by Chemical Formula 2.


