Battery Cell Electrolyte Sensor for Real-Time Separator Interface Measurement

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Solution Overview

Problem

Existing methods for measuring electrolyte concentration in lithium secondary batteries are unable to directly and accurately measure the concentration between the electrode and separator in real-time, often resulting in low accuracy and stability issues due to the risk of short circuits and complex manufacturing processes.

Innovation Solution

A battery cell with a measuring unit comprising a first and second electrode plate stacked with an insulating film, allowing for direct measurement of electrolyte concentration by inserting the unit between the separator and electrode, with through-holes for improved electrolyte impregnation and using wires connected to a resistance measuring device for real-time data collection.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If a conventional conductive metal rod method is used to measure electrolyte concentration, then the measurement can be performed indirectly, but the measurement accuracy is low and real-time measurement between electrode and separator is not possible

Engineering Contradiction:
Improveelectrolyte concentration measurement accuracyVSAvoidmeasurement device structure
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The invention extracts the measurement function from a separate external device and integrates it directly into the battery cell structure. The measuring unit with first and second electrode plates is inserted between the separator and electrode, allowing direct measurement of electrolyte concentration at the critical interface where lithium ions are transferred, eliminating the need for indirect external measurements

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The measuring unit is nested within the battery cell structure itself. The first electrode plate, insulating film, and second electrode plate are stacked and inserted into the battery cell, with the measuring unit becoming an integral part of the cell assembly. This nested approach enables direct measurement without adding external complexity

Inventive Principle:
Principle #7Nested doll (Nesting)

2Measurement precision

If measuring devices are inserted between separator and electrode to measure electrolyte concentration directly, then measurement accuracy improves, but the risk of short circuit increases and manufacturing complexity increases

Engineering Contradiction:
Improveelectrolyte concentration measurement accuracyVSAvoidshort circuit risk
Core Design Contradiction:
Measurement precisionVSReliability

Solution Approach 1:

An insulating film is introduced as an intermediary layer between the first electrode plate and the separator, and between the second electrode plate and the electrode. This insulating film prevents direct electrical contact that would cause short circuits, while still allowing the measuring unit to function and measure electrolyte concentration accurately at the electrode-separator interface

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The insulating film is applied selectively only at critical locations where short circuit risk exists (between electrode plates and conductive components), while other areas maintain their original conductive properties. This localized application of insulation preserves measurement functionality while preventing short circuits

Inventive Principle:
Principle #3Local quality

3Reliability

If a separate insulating film attachment process is added to prevent short circuits, then reliability improves, but manufacturing complexity and difficulty increase

Engineering Contradiction:
Improveshort circuit preventionVSAvoidmanufacturing process complexity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The insulating film is integrated into the measuring unit assembly itself during manufacturing, rather than being attached separately to the separator or electrode plates after assembly. The first electrode plate, insulating film, and second electrode plate are stacked and pre-assembled as a complete measuring unit, which is then inserted into the battery cell as a single component. This merging of steps eliminates separate insulating film attachment processes and reduces manufacturing complexity

Inventive Principle:
Principle #5Merging (Combining)

4Ease of manufacture

If the measuring unit structure is simplified, then ease of manufacture improves, but the speed and accuracy of electrolyte concentration measurement may be compromised

Engineering Contradiction:
Improvemeasuring unit fabricationVSAvoidelectrolyte concentration measurement speed and accuracy
Core Design Contradiction:
Ease of manufactureVSMeasurement precision

Solution Approach 1:

The measuring unit uses thin film structures for the electrode plates and insulating film, which are easy to manufacture and assemble. These thin films provide sufficient functionality for measurement while simplifying the manufacturing process compared to bulky rigid structures. The thin film design maintains electrical properties needed for accurate and rapid measurement

Inventive Principle:
Principle #30Flexible shells and thin films

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables precise, real-time measurement of electrolyte concentration with enhanced stability and simplified manufacturing, reducing the risk of short circuits and improving the accuracy and speed of electrolyte concentration measurement compared to prior methods.

Implementation Method 1

an insulating film which absorbs the electrolyte

Methodology Applied
Scientific EffectCapillary action: Capillary Action

Implementation Method 2

the resistance value between the wires attached to the rod is calculated

Methodology Applied
Scientific EffectElectrical resistance: Electrical Resistance

Data Source

PatentUS11881570B2Battery cell including electrolyte ion concentration measurement unit and method for measuring electrolyte concentration using same
Publication Date: 2024.01.23 LG ENERGY SOLUTION LTD
  • US11881570B2 patent drawing
  • US11881570B2 patent drawing
  • US11881570B2 patent drawing

AI summary

The present invention relates to a battery cell including an electrolyte ion concentration measurement unit and a method for measuring an electrolyte concentration using same. The battery cell according to the present invention comprises a measurement unit in which a first electrode plate, an insulation film, and a second electrode plate are sequentially stacked on one another, wherein the measurement unit is inserted between a separator of the battery cell and an electrode thereof, and thus can directly measure an electrolyte concentration between the separator and the electrode. Therefore, the battery cell can be simply manufactured and has excellent stability. In addition, according to the present invention, the method for measuring an electrolyte concentration of a secondary battery using the battery cell enables measurement of electrolyte concentration in real time even during the use of the battery and can measure an electrolyte concentration of the separator more accurately and quickly than a conventional technology.