Secondary Battery Electrolyte Composition for Cycle Life
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Solution Overview
Problem
Secondary batteries used in portable electronic devices experience decreased cycle characteristics due to repeated charge and discharge cycles, leading to electrolyte decomposition and reduced performance.
Innovation Solution
An electrolyte composition containing sulfone compounds, nitrile compounds, and isocyanate compounds is used, which improves chemical stability and inhibits electrolyte decomposition, thereby enhancing cycle characteristics in secondary batteries.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Reliability
If conventional electrolyte compositions are used in secondary batteries, then high energy density can be achieved, but cycle characteristics deteriorate due to electrolyte decomposition during repeated charge and discharge cycles
Solution Approach 1:
The patent modifies the chemical composition parameters of the electrolyte by introducing specific compounds (sulfone compounds of Formula (1) and (2), nitrile compounds, and isocyanate compounds of Formula (3) and (4)) with controlled amounts (0.01-5 wt% for sulfone compounds, 0.01-10 wt% for nitrile compounds, 0.01-5 wt% for isocyanate compounds). These parameter changes enhance the electrolyte's chemical stability during charge-discharge cycles while maintaining high energy density, directly resolving the contradiction between reliability and compositional stability.
Solution Approach 2:
The patent creates a composite electrolyte system by combining multiple types of compounds: sulfone compounds (Formula (1) and (2)), nitrile compounds, and isocyanate compounds (Formula (3) and (4)) with conventional electrolyte components. This composite approach synergistically improves cycle characteristics through the combined effects of these compounds in suppressing electrolyte decomposition, while maintaining the high energy density properties of the base electrolyte system.
2Duration of action of moving object
If repeated charge and discharge cycles are performed to meet portable device power demands, then device functionality is maintained, but electrolyte decomposition occurs and performance decreases
Solution Approach 1:
The patent applies preliminary action by incorporating specific protective compounds (sulfone, nitrile, and isocyanate compounds) into the electrolyte composition before the battery is put into service. These compounds pre-establish a stable chemical environment that prevents decomposition during subsequent charge-discharge cycles, thereby extending operational life while maintaining reliability from the first cycle onward.
Solution Approach 2:
The patent converts the potentially harmful effect of repeated charge-discharge cycles (which cause electrolyte decomposition) into a beneficial outcome by using specific compounds that not only resist decomposition but also improve cycle characteristics. The sulfone, nitrile, and isocyanate compounds transform the stress of repeated cycling into an opportunity to demonstrate enhanced stability and extended battery life.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The proposed electrolyte composition significantly improves the chemical stability and cycle characteristics of secondary batteries, even under repeated charge and discharge cycles, by combining sulfone compounds, nitrile compounds, and isocyanate compounds, leading to better performance and longevity.
Implementation Method 1
An electrolyte composition containing sulfone compounds, nitrile compounds, and isocyanate compounds is used, which improves chemical stability and inhibits electrolyte decomposition
Implementation Method 2
improves chemical stability and inhibits electrolyte decomposition, thereby enhancing cycle characteristics in secondary batteries
Data Source
AI summary
Secondary batteries capable of improving cycle characteristics are provided. The secondary battery includes a cathode, an anode, and an electrolytic solution. A separator provided between the cathode and the anode is impregnated with the electrolytic solution. The electrolytic solution contains a solvent and an electrolyte salt. The solvent contains a cyclic compound having a disulfonic acid anhydride group (—S(═O)2-O—S(═O)2-) and at least one of a nitrile compound. Compared to a case that the solvent does not contain both the cyclic compound having the disulfonic acid anhydride group and succinonitrile or a case that that the solvent contains at least one thereof, chemical stability of the electrolytic solution is improved. Thus, even if charge and discharge are repeated, electrolytic solution decomposition is inhibited.


