Non-aqueous Battery Intermediate Layer Arc-Shaped Insulating Particles

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Solution Overview

Problem

Existing non-aqueous electrolyte secondary batteries face challenges in inhibiting short-circuit currents due to uneven packing of insulating and conductive particles in the intermediate layer, leading to regions with low electrical resistance and increased short-circuit currents.

Innovation Solution

The battery design incorporates an intermediate layer with hollow particles that break under compression, forming arc-shaped insulating particles with a biased distribution of conductive particles on the outer circumference, which inhibits the formation of low-resistance current pathways by ensuring dense packing and controlled conductive particle distribution.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If insulating particles are used in the intermediate layer, then short-circuit current is inhibited, but the compression rate cannot be increased due to the hardness of insulating particles

Engineering Contradiction:
Improveshort-circuit current inhibitionVSAvoidcompression rate
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent changes the physical state parameter of insulating particles from solid to hollow structure. This parameter change allows the particles to be compressed more easily while maintaining their insulating function, thereby resolving the contradiction between achieving high compression rate and using hard insulating particles.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite intermediate layer containing both hollow insulating particles and conductive particles. The hollow insulating particles provide compression capability and structural framework, while conductive particles fill spaces and provide electrical pathways. This composite structure resolves the contradiction by combining the advantages of both particle types.

Inventive Principle:
Principle #40Composite materials

2Reliability

If a low compression rate intermediate layer is formed, then insulating particles can be used, but uneven packing occurs leading to regions with low electrical resistance

Engineering Contradiction:
Improveshort-circuit current inhibitionVSAvoidpacking uniformity
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

By changing insulating particles from solid to hollow structure, the patent enables high compression rate achievement. This parameter change ensures uniform packing of particles in the intermediate layer, eliminating uneven regions that would create low-resistance pathways, thus resolving the contradiction between short-circuit inhibition and packing uniformity.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a uniformly distributed composite structure where hollow insulating particles and conductive particles are evenly mixed throughout the intermediate layer. This local quality distribution ensures consistent electrical resistance properties across all regions, preventing localized low-resistance pathways while maintaining overall short-circuit inhibition capability.

Inventive Principle:
Principle #3Local quality

3Use of energy by moving object

If more conductive particles are added to improve conductivity, then normal operation resistance decreases, but short-circuit current increases

Engineering Contradiction:
Improveelectrical conductivityVSAvoidshort-circuit current inhibition
Core Design Contradiction:
Use of energy by moving objectVSReliability

Solution Approach 1:

The patent creates a non-uniform distribution of conductive particles within the composite intermediate layer. Conductive particles are strategically positioned to provide necessary electrical conductivity for normal battery operation while being constrained by the hollow insulating particle framework to prevent formation of continuous high-conductivity pathways that would enable short-circuit currents.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The composite structure combining hollow insulating particles with conductive particles allows the system to achieve optimal balance between conductivity and short-circuit inhibition. The insulating particles provide structural framework and short-circuit protection, while conductive particles fill interstices and provide necessary electrical pathways for normal operation.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration effectively inhibits the increase of short-circuit currents while maintaining low resistance during normal battery operation, as demonstrated by the controlled distribution of conductive particles and the arc shape of insulating particles, enhancing the battery's safety and performance.

Implementation Method 1

Compression of the intermediate layer causes breakage of the hollow particles. Breakage of the hollow particles causes formation of insulating particles

Methodology Applied
Scientific EffectCompression: Compression

Implementation Method 2

More conductive particles are present on an outer-circumference side of each arc shape than on an inner-circumference side of the arc shape

Methodology Applied
Scientific EffectElectrical Resistance: Electrical Resistance

Data Source

PatentUS10897047B2Non-aqueous electrolyte secondary battery and method of producing the same
Publication Date: 2021.01.19 TOYOTA JIDOSHA KK
  • US10897047B2 patent drawing
  • US10897047B2 patent drawing
  • US10897047B2 patent drawing

AI summary

A non-aqueous electrolyte secondary battery includes at least an electrode composite material layer, an intermediate layer, and an electrode current collector. Intermediate layer is interposed between electrode composite material layer and electrode current collector. Intermediate layer contains at least insulating particles and conductive particles. Each insulating particle has an arc shape in a cross section of intermediate layer along a thickness direction. More conductive particles are present on an outer-circumference side of each arc shape than on an inner-circumference side of the arc shape.