Secondary Battery Electrode Lamination With Succinonitrile Binder

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Solution Overview

Problem

The lamination process for secondary batteries, particularly for stack and stack/folding types, often damages separators and increases resistance due to high temperature and pressure, leading to poor adhesive forces between electrodes and separators.

Innovation Solution

A method involving an electrode slurry with succinonitrile is used, where succinonitrile acts as a binder between electrodes and separators, allowing for lower temperature and pressure lamination, minimizing damage and resistance by rearranging its distribution during drying and dissolving in the electrolyte solution.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If high temperature and high pressure are applied during lamination to improve adhesive force between negative electrode and separator, then adhesive force is improved, but binder melts and acts as resistance, deteriorating battery performance

Engineering Contradiction:
Improveadhesive forceVSAvoidresistance
Core Design Contradiction:
StrengthVSObject-generated harmful factors

Solution Approach 1:

The patent changes the chemical composition parameter of the binder from conventional materials (PVDF, CMC, SBR) to succinonitrile, which has a higher melting point and does not melt under lamination conditions. This parameter change allows the binder to maintain adhesive force without melting and forming resistance, thus resolving the contradiction between improving adhesive force and preventing resistance generation.

Inventive Principle:
Principle #35Parameter changes

2Strength

If high pressure is applied during lamination to improve adhesive force of negative electrode, then adhesive force is improved, but pores of separator are reduced, increasing resistance

Engineering Contradiction:
Improveadhesive forceVSAvoidresistance
Core Design Contradiction:
StrengthVSObject-generated harmful factors

Solution Approach 1:

The patent changes the binder material parameter to succinonitrile, which provides sufficient adhesive force at lower pressures. This allows the lamination process to be performed at reduced pressure, preventing excessive compression of separator pores while still achieving strong adhesive bonding between the negative electrode and separator.

Inventive Principle:
Principle #35Parameter changes

3Strength

If high temperature and high pressure are applied during lamination to secure adhesive force, then adhesive force is improved, but damage to separator occurs

Engineering Contradiction:
Improveadhesive forceVSAvoiddamage to separator
Core Design Contradiction:
StrengthVSObject-affected harmful factors

Solution Approach 1:

The patent changes the binder material to succinonitrile, which maintains its binding properties at lower temperatures and pressures. This parameter change enables the lamination process to proceed under milder conditions, reducing thermal and mechanical stress on the separator and preventing damage while still achieving strong adhesive force.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method enhances adhesive forces between electrodes and separators, reduces battery resistance, and lowers manufacturing costs by avoiding high-pressure processes, while maintaining battery performance.

Implementation Method 1

succinonitrile acts as a binder between electrodes and separators

Methodology Applied
Scientific EffectAdhesion: Adhesive

Implementation Method 2

dissolving in the electrolyte solution

Methodology Applied
Scientific EffectDissolution: Solvation

Data Source

PatentEP3985778B1Method for manufacturing secondary battery having improved resistance
Publication Date: 2024.02.14 LG ENERGY SOLUTION LTD
  • EP3985778B1 patent drawingFigure 1(a)~1(b)
  • EP3985778B1 patent drawingFigure 2
  • EP3985778B1 patent drawingFigure 3(a)~3(e)

AI summary

The present invention relates to a method for manufacturing a secondary battery having improved resistance, in which an electrode is manufactured using an electrode slurry comprising succinonitrile, and by which, compared to the prior art, an effect is achieved of, in a process for laminating the electrode with a separator, improving an adhesive force between the electrode and the separator even without requiring a high-pressure process. In addition, the succinonitrile in the electrode dissolves in an electrolyte, and thus an effect is achieved of improving the resistance of the battery.