Battery Material Drying via Organic Solvent Vapor Hydrogen Bonding

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Solution Overview

Problem

Lithium batteries are sensitive to moisture, leading to corrosion, reduced capacity, and shorter life cycles, requiring expensive and energy-intensive dry room environments to maintain low humidity, which is inefficient and costly.

Innovation Solution

A method involving a sealed channel where a gaseous mixture with organic solvent vapor is used to hydrogen bond with residual water in battery materials, reducing water content through controlled temperature, pressure, and time, eliminating the need for extensive dry room environments during manufacturing.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If traditional dry room environments are used to maintain low humidity during battery manufacturing, then moisture sensitivity is controlled, but manufacturing cost and energy consumption increase significantly

Engineering Contradiction:
Improvemoisture controlVSAvoidenergy consumption
Core Design Contradiction:
ReliabilityVSUse of energy by stationary object

Solution Approach 1:

The invention changes the physical-chemical parameters of the drying environment by introducing organic solvent vapor (such as ethanol or acetone) into the drying atmosphere. The solvent vapor forms hydrogen bonds with water molecules, enabling effective water removal at lower temperatures and shorter durations compared to traditional hot air drying, thus reducing energy consumption while maintaining moisture control

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention introduces an intermediary substance (organic solvent vapor) that acts as a mediator between the battery material and the drying environment. The solvent vapor molecules interact with adsorbed water through hydrogen bonding, facilitating water desorption from the battery material surface without requiring extreme dry room conditions, thereby reducing the need for energy-intensive moisture control infrastructure

Inventive Principle:
Principle #24Intermediary (Mediator)

2Quantity of substance

If traditional hot air drying is used to remove residual water, then water content is reduced, but processing time and energy consumption increase

Engineering Contradiction:
Improvewater contentVSAvoidprocessing time
Core Design Contradiction:
Quantity of substanceVSLoss of time

Solution Approach 1:

The invention changes the chemical composition parameter of the drying medium from pure hot air to a mixture containing organic solvent vapor. This parameter change enables the drying process to occur at lower temperatures with faster kinetics, as the solvent vapor creates a more favorable chemical environment for water desorption through hydrogen bonding interactions

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention substitutes the purely thermal mechanism of hot air drying with a combined chemical-physical mechanism involving solvent-water hydrogen bonding. This substitution replaces the energy-intensive thermal field with a more efficient chemical interaction field, significantly reducing both processing time and energy consumption while achieving the same water removal effect

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Quantity of substance

If extended drying time is used to reduce residual water, then water content decreases, but production efficiency decreases

Engineering Contradiction:
Improveresidual water contentVSAvoidproduction efficiency
Core Design Contradiction:
Quantity of substanceVSProductivity

Solution Approach 1:

The invention performs preliminary action by pre-saturating the drying environment with organic solvent vapor before introducing the battery material. This preliminary preparation of the drying atmosphere ensures that solvent molecules are immediately available to interact with adsorbed water upon material introduction, accelerating the drying process and eliminating the need for extended drying times, thereby maintaining high production efficiency

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method effectively reduces residual water content in battery materials, increasing battery life cycle, decreasing corrosion, and reducing capacity loss while minimizing energy and resource consumption.

Implementation Method 1

The gaseous mixture includes an organic solvent vapor present in an amount effective to hydrogen bond with at least some water molecules from the battery material

Methodology Applied
Scientific EffectHydrogen bonding: Chemical Bonding

Data Source

PatentUS10665852B2Method for reducing residual water content in battery material
Publication Date: 2020.05.26 GM GLOBAL TECHNOLOGY OPERATIONS LLC
  • US10665852B2 patent drawing
  • US10665852B2 patent drawing
  • US10665852B2 patent drawing

AI summary

A method for reducing residual water content in a battery material includes placing the battery material having residual water adsorbed therein in a channel substantially sealed from an ambient environment. A gaseous mixture is caused to flow through the battery material in the channel. The gaseous mixture includes an organic solvent vapor present in an amount effective to hydrogen bond with at least some water molecules from the battery material. The gaseous mixture is caused to flow through the battery material for a predetermined amount of time, at a predetermined temperature, and at a predetermined pressure. The organic solvent vapor having at least some water molecules bonded thereto is removed from the battery material. The removing takes place for a predetermined amount of time, at a predetermined temperature, and at a predetermined pressure, thereby forming the battery material having reduced residual water content.