Lithium Ion Battery Thermal Runaway Termination System

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Solution Overview

Problem

Existing fire suppression systems for lithium ion batteries are unable to terminate thermal runaway, and current methods fail to prevent reignition after initial flame extinguishment.

Innovation Solution

A fire protection system that uses a thermal runaway termination agent, such as HFC-227ea, delivered through a temperature-sensitive tube and controlled by a two-way or three-way valve, which is activated upon detecting a threshold temperature, ensuring a specific discharge time, concentration, and hold time to effectively extinguish flames and terminate thermal runaway.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If gaseous clean fire extinguishing agents are used to extinguish flames, then flame extinguishment is achieved, but thermal runaway cannot be terminated and reignition may occur

Engineering Contradiction:
Improveflame extinguishmentVSAvoidthermal runaway termination
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent changes the parameters of the fire suppression system by introducing a thermal runaway termination agent with specific properties (HFC-227ea at concentrations of 17-30% v/v) and controlling delivery parameters (discharge time of 18-180 seconds, hold time of 10-60 minutes) to achieve both flame extinguishment and thermal runaway termination, preventing reignition

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The system uses a composite approach by combining a thermal runaway termination agent (HFC-227ea) with a fire extinguishing agent, delivering them through a temperature-sensitive tube and control valve system to simultaneously address both flame suppression and thermal runaway termination requirements

Inventive Principle:
Principle #40Composite materials

2Speed

If fire extinguishing agent is delivered quickly to extinguish flame, then flame suppression is improved, but thermal runaway cannot be sufficiently terminated

Engineering Contradiction:
Improvefire extinguishing speedVSAvoidthermal runaway termination
Core Design Contradiction:
SpeedVSReliability

Solution Approach 1:

The patent implements continuous action by maintaining the thermal runaway termination agent at a hold time of 10-60 minutes after delivery, ensuring sustained concentration (17-30% v/v) in the enclosure to continuously suppress thermal runaway reactions and prevent reignition, rather than providing a single brief discharge

Inventive Principle:
Principle #20Continuity of useful action

3Reliability

If concentration of thermal runaway termination agent is increased to ensure termination, then thermal runaway termination is improved, but system complexity and substance quantity requirements increase

Engineering Contradiction:
Improvethermal runaway terminationVSAvoidagent concentration and quantity
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

The patent optimizes the concentration parameter by specifying a precise range (17-30% v/v) for the thermal runaway termination agent HFC-227ea, which is sufficient to achieve thermal runaway termination while avoiding excessive quantities. The controlled delivery system ensures this optimal concentration is achieved through regulated discharge over 18-180 seconds

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The system successfully extinguishes flames, terminates thermal runaway, and prevents reignition in lithium ion battery fires by ensuring the appropriate concentration and duration of the thermal runaway termination agent is delivered.

Implementation Method 1

the tube is located within the enclosure and comprises a temperature sensor for detection of a threshold temperature

Methodology Applied
Scientific EffectTemperature sensing:

Implementation Method 2

The delivery of the thermal runaway termination agent is characterized by a discharge time of at least 18 seconds, a HFC-227ea concentration of at least 17% v/v, and a hold time of 10 to 15 minutes or 15 to 30 minutes or 30 to 60 minutes that are sufficient to extinguish the flame and terminate thermal runaway

Methodology Applied
Scientific EffectFlame extinguishment:

Implementation Method 3

the hold time is sufficient to cool the enclosure and the lithium ion battery to a temperature sufficient to prevent reignition following the extinguishment of the flame

Methodology Applied
Scientific EffectThermal cooling: Cooling

Data Source

PatentEP4237102B1Thermal protection of lithium ion batteries
Publication Date: 2025.06.11 THE CHEMOURS CO FC LLC
  • EP4237102B1 patent drawingFigure 1a
  • EP4237102B1 patent drawingFigure 1b
  • EP4237102B1 patent drawingFigure 2

AI summary

A method for extinguishing a flame and terminating thermal runaway in a device powered by a lithium ion battery. The disclosure also provides a system for extinguishing fires generated by lithium ion batteries exhibiting thermal runaway.