Bauxite Residue Sintering for Hazardous Waste Stabilization

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Solution Overview

Problem

Bauxite residue, or 'red mud,' generated during the Bayer process for alumina production poses significant environmental and disposal challenges due to its high alkalinity and hazardous content, leading to contamination risks and difficulties in safe disposal.

Innovation Solution

A method involving mixing bauxite residue with glass material and fines, followed by compression and sintering at elevated temperatures to create a solid product that reduces hazardous elements below acceptable thresholds, making it suitable for landfill disposal and potentially usable in construction materials.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If bauxite residue is stored in lagoons to prevent environmental contamination, then environmental safety is improved, but the process requires continuous water consumption and creates long-term disposal liabilities

Engineering Contradiction:
Improveenvironmental contaminationVSAvoidwater consumption
Core Design Contradiction:
Object-affected harmful factorsVSQuantity of substance

Solution Approach 1:

The invention changes the chemical and physical parameters of bauxite residue through sintering at high temperatures (900-1500°C), transforming it from a hazardous slurry into a stable, inert solid product with reduced leachability, thereby eliminating the need for continuous water maintenance in lagoons

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The process utilizes phase transition by heating bauxite residue through sintering, transforming it from a liquid/slurry state in lagoons to a solid, stable form that can be safely disposed of without continuous water consumption for containment

Inventive Principle:
Principle #36Phase transitions

2Object-affected harmful factors

If bauxite residue is sintered at high temperature to reduce hazardous content, then environmental safety is improved, but energy consumption increases

Engineering Contradiction:
Improvehazardous contentVSAvoidenergy consumption
Core Design Contradiction:
Object-affected harmful factorsVSUse of energy by moving object

Solution Approach 1:

The invention optimizes the sintering temperature parameter within the range of 900-1500°C to achieve effective hazardous element reduction while managing energy consumption, transforming the residue into a stable product that meets disposal criteria

Inventive Principle:
Principle #35Parameter changes

3Object-affected harmful factors

If bauxite residue is mixed with glass material and sintered to produce solid product, then hazardous content is reduced, but manufacturing complexity increases

Engineering Contradiction:
Improvehazardous contentVSAvoidmanufacturing process complexity
Core Design Contradiction:
Object-affected harmful factorsVSDevice complexity

Solution Approach 1:

The invention creates a composite material by mixing bauxite residue with glass material before sintering, where the glass acts as a binding agent and stabilizer, forming a stable solid product that encapsulates hazardous elements and reduces their leachability

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

Glass material serves as an intermediary substance that facilitates the transformation of hazardous bauxite residue into a stable product, acting as both a binding agent during compression and a stabilizing matrix during sintering that reduces hazardous element mobility

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The process transforms hazardous bauxite residue into a stable, inert product that meets Waste Acceptance Criteria, reducing environmental risks and enabling its use in building products, such as bricks and aggregates, while minimizing leachable contaminants.

Implementation Method 1

sintering the green body (e.g. preferably at a temperature sufficient to melt the glass material)

Methodology Applied
Scientific EffectMelting: Melting

Implementation Method 2

sintering the green body (e.g. preferably at a temperature sufficient to melt the glass material)

Methodology Applied
Scientific EffectSintering: Sintering

Data Source

PatentEP3708553B1Method of treatment of bauxite residue to produce a solid product
Publication Date: 2023.09.27 PURGO GRP LTD
  • EP3708553B1 patent drawingFigure 1
  • EP3708553B1 patent drawingFigure 2~3
  • EP3708553B1 patent drawingFigure 4

AI summary

A method of treatment of bauxite residue resulting from a Bayer process of bauxite treatment in order to produce a solid product. The method comprises mixing a quantity of the bauxite residue (1) with a quantity of a glass material (2) to form a mixture. Then, compressing the mixture (4) to form a green body, and sintering (5) the green body. After cooling, the sintered green body thereby provides the solid product.