BCC Iron Cobalt Multilayers for MRAM PMA

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Solution Overview

Problem

Spin torque magnetic random access memory (MRAM) faces challenges in achieving high tunnel magnetoresistance (MR) with magnesium oxide (MgO) tunnel barriers, requiring a material with a two-dimensional interface and sufficient lattice match, while also exhibiting perpendicular magnetic anisotropy (PMA), which is difficult to develop simultaneously with high MR and large PMA.

Innovation Solution

A multilayer magnetic material comprising alternating body-centered cubic (BCC) iron and BCC or amorphous cobalt layers, with each layer thickness between 2 to 10 angstroms, providing high MR and large PMA through anisotropy at interfaces or strain, optimized for use in magnetic tunnel junctions (MTJs).

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a material is designed to exhibit high tunnel magnetoresistance with MgO tunnel barriers, then the MR is improved, but it becomes difficult to simultaneously achieve large perpendicular magnetic anisotropy (PMA)

Engineering Contradiction:
Improvetunnel magnetoresistanceVSAvoidperpendicular magnetic anisotropy
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The patent employs composite multilayer structures consisting of alternating BCC iron layers and BCC or amorphous cobalt layers. This composite approach allows the material to simultaneously achieve high tunnel magnetoresistance and large perpendicular magnetic anisotropy, as the combination of different magnetic materials with specific crystal structures creates synergistic effects that neither material alone can provide.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The magnetic material is divided into multiple thin alternating layers of iron and cobalt, each with thickness between 2 to 10 angstroms. This segmentation into ultrathin layers creates numerous interfaces that contribute to perpendicular magnetic anisotropy while maintaining the magnetic properties needed for high tunnel magnetoresistance in MgO-based tunnel junctions.

Inventive Principle:
Principle #1Segmentation

2Area of moving object

If the MTJ size is reduced to enable smaller bit reading, then the write current for magnetization reversal becomes smaller, but the write current density increases

Engineering Contradiction:
ImproveMTJ areaVSAvoidwrite current density
Core Design Contradiction:
Area of moving objectVSUse of energy by moving object

Solution Approach 1:

The patent changes the magnetic anisotropy parameter from in-plane to perpendicular magnetic anisotropy by using alternating BCC iron and BCC or amorphous cobalt layers. This parameter change reduces the write current density required for magnetization reversal, allowing smaller MTJ areas to be used without proportionally increasing the write current density, thus enabling smaller bit reading with manageable energy requirements.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent utilizes the phase transition or structural transition between BCC and amorphous states in cobalt layers to achieve perpendicular magnetic anisotropy. This structural phase transition in the cobalt layers creates the necessary magnetic anisotropy that reduces the energy barrier for magnetization switching, thereby lowering the write current density even in reduced-size MTJs.

Inventive Principle:
Principle #36Phase transitions

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The multilayer structure enhances spin torque switching efficiency by reducing the necessary write current density, enabling smaller bit reading and improving MRAM performance with high MR and large PMA, suitable for efficient data storage.

Implementation Method 1

the magnetic material has a perpendicular magnetic anisotropy (PMA)

Methodology Applied
Scientific EffectPerpendicular magnetic anisotropy: Anisotropy

Implementation Method 2

providing high MR and large PMA through anisotropy at interfaces or strain

Methodology Applied
Scientific EffectInterface anisotropy: Anisotropy

Implementation Method 3

uses tunneling magnetoresistance (TMR or MR) to store information

Methodology Applied
Scientific EffectTunneling magnetoresistance: Magnetoresistance

Data Source

PatentUS10003016B2Perpendicular magnetic anisotropy BCC multilayers
Publication Date: 2018.06.19 INTERNATIONAL BUSINESS MACHINE CORPORATION
  • US10003016B2 patent drawing
  • US10003016B2 patent drawing
  • US10003016B2 patent drawing

AI summary

A magnetic material includes a cobalt layer between opposing iron layers. The iron layers include iron and are body-centered cubic (BCC), the cobalt layer comprises cobalt and is BCC or amorphous, and the magnetic material has a perpendicular magnetic anisotropy (PMA).