BeCu Ring Heat Treatment for Fine Grain and Conductivity

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Solution Overview

Problem

Conventional metal rings made from beryllium-copper alloys face issues with surface quality longevity, ductility, formability, ultrasonic inspectability, conductivity, and lack of grain size refinement, leading to increased manufacturing costs and reduced productivity.

Innovation Solution

A process involving pre-forging, hot working, solution annealing, quenching, and age hardening of beryllium-copper alloy billets to produce metal rings with a fine and uniform grain structure, enhanced yield strength, hardness, and electrical conductivity, while maintaining surface quality and reducing wall thickness significantly.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If conventional metal ring manufacturing processes are used, then manufacturing cost is reduced, but surface quality longevity deteriorates

Engineering Contradiction:
Improvemanufacturing costVSAvoidsurface quality longevity
Core Design Contradiction:
Ease of manufactureVSDuration of action of stationary object

Solution Approach 1:

The patent applies parameter changes by implementing specific heat treatment parameters (solution annealing at 780-800°C for 1.5-4 hours, quenching from 750-850°C, age hardening at 385-400°C for 2-4 hours) and processing parameters (preheating at 800-850°C for 8+ hours, hot working at 750-850°C) to achieve superior surface quality longevity while maintaining economical manufacturing through process optimization

Inventive Principle:
Principle #35Parameter changes

2Device complexity

If conventional metal ring manufacturing processes are used, then manufacturing simplicity is maintained, but ductility deteriorates

Engineering Contradiction:
Improveprocess complexityVSAvoidductility
Core Design Contradiction:
Device complexityVSStrength

Solution Approach 1:

The patent segments the manufacturing process into distinct sequential stages: preheating, hot working/forging, soaking, ring rolling, solution annealing, quenching, age hardening, and air cooling. Each stage is optimized independently to contribute to overall ductility improvement, with the multi-stage approach achieving percent elongation of at least 6% while maintaining manageable process complexity through standardized procedures

Inventive Principle:
Principle #1Segmentation

3Loss of time

If conventional metal ring manufacturing processes are used, then processing time is reduced, but grain size refinement deteriorates

Engineering Contradiction:
Improveprocessing timeVSAvoidgrain size refinement
Core Design Contradiction:
Loss of timeVSManufacturing precision

Solution Approach 1:

The patent applies preliminary action through extended preheating (at least 8 hours at 800-850°C) and soaking (at least 2 hours at 815-835°C) stages before the main heat treatment processes. These preliminary actions ensure uniform temperature distribution and proper microstructural preparation, enabling effective grain size refinement to achieve fine and uniform grain structure while managing overall processing time through optimized subsequent faster cooling and hardening stages

Inventive Principle:
Principle #10Preliminary action

4Device complexity

If conventional metal ring manufacturing processes are used, then manufacturing simplicity is maintained, but yield strength deteriorates

Engineering Contradiction:
Improveprocess complexityVSAvoidyield strength
Core Design Contradiction:
Device complexityVSStrength

Solution Approach 1:

The patent exploits phase transitions through solution annealing (780-800°C for 1.5-4 hours) where the alloy reaches a single-phase beta region, followed by quenching that transforms the microstructure, and age hardening (385-400°C for 2-4 hours) that precipitates strengthening phases. This controlled phase transition sequence achieves 0.2% offset yield strength of at least 760 MPa while maintaining process simplicity through well-established heat treatment methodologies

Inventive Principle:
Principle #36Phase transitions

5Ease of manufacture

If conventional metal ring manufacturing processes are used, then manufacturing cost is reduced, but electrical conductivity deteriorates

Engineering Contradiction:
Improvemanufacturing costVSAvoidelectrical conductivity
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent optimizes parameter changes by controlling the timing and temperature of heat treatment stages, particularly solution annealing at 780-800°C followed by quenching and age hardening at lower temperatures (385-400°C). This parameter control achieves electrical conductivity of at least 25% IACS while maintaining cost-effectiveness by avoiding excessive heat treatment durations and utilizing efficient cooling methods

Inventive Principle:
Principle #35Parameter changes

6Device complexity

If conventional metal ring manufacturing processes are used, then manufacturing simplicity is maintained, but formability deteriorates

Engineering Contradiction:
Improveprocess complexityVSAvoidformability
Core Design Contradiction:
Device complexityVSEase of operation

Solution Approach 1:

The patent applies dynamics by implementing hot working and ring rolling at elevated temperatures (750-850°C) where the material exhibits enhanced plasticity and formability. The dynamic temperature control during forming operations, combined with the sequential heat treatment stages, enables complex ring geometries with uniform wall thickness while maintaining process simplicity through standardized hot working procedures

Inventive Principle:
Principle #15Dynamics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The process results in metal rings with improved mechanical properties, extended surface longevity, and increased productivity, allowing for more economical processing and enhanced performance in various applications.

Implementation Method 1

The billet is preheated at a temperature of 800°C to 850°C, including 820°C, for a period of at least 8 hours

Methodology Applied
Scientific EffectHeating: Heating

Implementation Method 2

The ring is then solution annealed at a temperature of 780°C to 800°C for a period of at least 1.5 hours

Methodology Applied
Scientific EffectSolution annealing: Annealing

Implementation Method 3

Immediately following solution annealing, the ring is quenched in a quench medium (such as water)

Methodology Applied
Scientific EffectQuenching: Cooling

Implementation Method 4

The ring is then age hardened by heat treating at a temperature of 385°C to 400°C for a period of about 3 hours

Methodology Applied
Scientific EffectAge hardening: Heat Treatment

Implementation Method 5

The preform is then hot worked again via ring rolling the preform at a temperature of 750°C to 850°C to form a ring having a wall thickness

Methodology Applied
Scientific EffectHot working: Deformation

Data Source

PatentEP3710608B1Process for making a metal ring from a beryllium-copper alloy, metal ring made of a beryllium-copper alloy, an amorphous metal casting apparatus
Publication Date: 2024.02.14 MATERION CORP
  • EP3710608B1 patent drawingFigure 1
  • EP3710608B1 patent drawingFigure 2
  • EP3710608B1 patent drawingFigure 3

AI summary

Processes are disclosed for forming beryllium-copper metal rings having a fine and uniform grain structure. A raw BeCu casting is pre-forged and turned to form a BeCu billet. The BeCu billet is subjected to various heat treatment and cooling cycles to obtain / maintain combinations of advantageous material properties. Generally, the BeCu billet is preheated, hot worked via forging, heated again, hot worked again via ring rolling followed by air cooling, solution annealed followed by quenching, and heated a final time followed by air cooling.