Chemically Strengthened Glass for Bend Forming

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Solution Overview

Problem

Existing chemically strengthened glasses face issues with cracking and poor forming precision during bend forming, particularly due to thermal stress and variations in shape, which are exacerbated by the demand for higher definition and waterproofness in display devices.

Innovation Solution

A chemically strengthened glass with a Young's modulus of 70 GPa or more, specific thermal expansion coefficients, and a viscosity profile that minimizes thermal stress, combined with a lithium aluminosilicate composition and a chemical strengthening process that includes ion exchange treatments to create a compressive stress layer, is developed to enhance scratch resistance and forming precision.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Shape

If a glass sheet is bend-formed by heating, then a curved surface shape can be produced, but thermal stress is generated causing cracking of the glass sheet

Engineering Contradiction:
Improvecurved surface shapeVSAvoidcracking resistance
Core Design Contradiction:
ShapeVSReliability

Solution Approach 1:

The patent applies parameter changes by precisely controlling the glass composition parameters (X1+X2+X3 ≤ 1760) and thermal properties (viscosity-temperature characteristics) to enable bend forming at lower temperatures with reduced thermal stress. This resolves the contradiction by modifying the material parameters to tolerate the forming process without cracking.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent implements preliminary action by pre-heating the glass sheet to a specific temperature range (softening temperature Ts - 50°C to Ts - 100°C) before bend forming. This preliminary heating prepares the glass in advance, reducing thermal shock and stress during the actual forming process, thereby preventing cracking while achieving the curved shape.

Inventive Principle:
Principle #10Preliminary action

2Shape

If a glass sheet is bend-formed, then a curved surface shape can be produced, but the shape of the formed glass sheet varies

Engineering Contradiction:
Improvecurved surface shapeVSAvoidforming precision
Core Design Contradiction:
ShapeVSManufacturing precision

Solution Approach 1:

The patent uses parameter changes by optimizing the glass composition (X1+X2+X3 ≤ 1760) and viscosity characteristics to ensure uniform deformation during bend forming. This control over material parameters ensures consistent shape reproduction and high forming precision while maintaining the desired curved surface geometry.

Inventive Principle:
Principle #35Parameter changes

3Shape

If the glass is subjected to three-dimensional forming, then a curved surface shape can be achieved, but the glass is prone to easy cracking during the process

Engineering Contradiction:
Improvecurved surface shapeVSAvoidcracking resistance during forming
Core Design Contradiction:
ShapeVSStrength

Solution Approach 1:

The patent applies parameter changes by controlling the glass composition parameters (X1+X2+X3 ≤ 1760) and thermal expansion characteristics to reduce internal stress during three-dimensional forming. This resolves the contradiction by modifying material parameters to enhance strength and cracking resistance while achieving the curved shape.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent implements preliminary action by pre-heating the glass to a controlled temperature range before three-dimensional forming. This advance preparation reduces thermal shock and internal stress during the forming process, preventing cracking while achieving the desired curved surface shape.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution results in a high-strength, crack-resistant glass with improved forming precision and safety, suitable for curved surfaces in display devices, by reducing thermal stress and maintaining shape integrity during the bend forming process.

Implementation Method 1

chemical strengthening process that includes ion exchange treatments to create a compressive stress layer

Methodology Applied
Scientific EffectIon exchange: Ion Exchange

Implementation Method 2

thermal stress is generated by heating the glass sheet

Methodology Applied
Scientific EffectThermal expansion: Thermal Expansion

Implementation Method 3

thermal stress is generated by heating the glass sheet, which sometimes causes cracking of the glass sheet

Methodology Applied
Scientific EffectThermal stress: Thermal Shock

Implementation Method 4

X2 is a numeral value equivalent to a value of a temperature Tf at which a viscosity of the glass reaches 100 MPa·s

Methodology Applied
Scientific EffectViscosity-temperature relationship:

Data Source

PatentUS11535548B2Glass for chemical strengthening, chemically strengthened glass and method for manufacturing chemically strengthened glass
Publication Date: 2022.12.27 AGC INC
  • US11535548B2 patent drawing

AI summary

A glass for chemical strengthening has a Young's modulus E of 70 GPa or more. The glass satisfies X1+X2+X3 being 1760 or less. Here, X1 is a numerical value equivalent to a value [unit: kPa/° C.] obtained by multiplying the Young's modulus E by an average coefficient α of thermal expansion at 50° C. to 350° C., X2 is a numeral value equivalent to a value of a temperature Tf [unit: ° C.] at which a viscosity of the glass reaches 100 MPa·s, and X3 is a numerical value equivalent to a value of a difference [unit: 105 Pa·s] between the viscosity (100 MPa·s) at the Tf and a viscosity η+10 at a temperature 10° C. higher than the Tf.