Benefit Agent Delivery Particle with Optimized Solubility Shell

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Solution Overview

Problem

Existing benefit agents in consumer products, such as perfumes and fragrances, face challenges in delivery efficiency due to physical or chemical incompatibilities with other components, leading to poor encapsulation and leakage issues in microcapsules.

Innovation Solution

The development of benefit agent delivery particles with a core material and a shell material that have an optimized solubility parameter difference, resulting in increased encapsulation efficiency and minimal leakage, achieved through a process involving the preparation of an organic phase with a core material and a first shell forming material, followed by interfacial polymerization with a second shell forming material.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stability of the object's composition

If the core material and shell are compatible, then the core material may act as a plasticizer and increase diffusion through the shell, but encapsulation efficiency deteriorates

Engineering Contradiction:
Improveshell integrityVSAvoidencapsulation efficiency
Core Design Contradiction:
Stability of the object's compositionVSReliability

Solution Approach 1:

The patent applies parameter changes by carefully controlling the solubility parameter difference between core and shell materials. By optimizing this parameter within a specific range (0.5-2.0 MPa^1/2), the invention achieves both shell integrity and encapsulation efficiency, resolving the contradiction between compatibility and leakage prevention

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite materials by combining the core material with a shell material that has a specifically matched solubility parameter. This composite structure allows the shell to maintain integrity while preventing core material diffusion, thus resolving the contradiction between stability and reliability

Inventive Principle:
Principle #40Composite materials

2Reliability

If the shell and core material are incompatible, then encapsulation efficiency may be poor, but diffusion through the shell is reduced

Engineering Contradiction:
Improveencapsulation efficiencyVSAvoidencapsulation efficiency
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent resolves this contradiction by precisely controlling the solubility parameter difference within an optimal range. This parameter optimization ensures that the materials are neither too compatible (which would cause leakage) nor too incompatible (which would cause poor encapsulation), achieving both high encapsulation efficiency and shell stability

Inventive Principle:
Principle #35Parameter changes

3Quantity of substance

If benefit agents are employed at high levels in consumer products, then effectiveness may be increased, but cost and physical/chemical incompatibilities increase

Engineering Contradiction:
Improvebenefit agent concentrationVSAvoidformulation compatibility
Core Design Contradiction:
Quantity of substanceVSEase of manufacture

Solution Approach 1:

The patent uses the delivery particle as an intermediary between the benefit agent and the consumer product formulation. This intermediary structure protects the benefit agent from incompatibilities with other formulation components, allowing higher concentrations to be used without suffering from the usual compatibility problems

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent employs a flexible shell structure that can accommodate the benefit agent while protecting it from the external environment. This shell acts as a barrier that prevents physical and chemical incompatibilities between the benefit agent and other formulation components, enabling higher effective concentrations

Inventive Principle:
Principle #30Flexible shells and thin films

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances the encapsulation efficiency of benefit agents, minimizing leakage and achieving a desired fracture profile, thereby maximizing the effectiveness of these agents in consumer products.

Implementation Method 1

microcapsules manufactured by an interfacial polymerization process comprising the formation of a shell at an oil/water interface. Generally, such processes require that a first shell forming material be dissolved in a core material. Upon adding a second shell forming material, the first and second materials react to form a shell that encapsulates the core material.

Methodology Applied
Scientific EffectInterfacial polymerization: Chemical Bonding

Data Source

PatentEP2349551B2Benefit agent containing delivery particle
Publication Date: 2023.07.26 PROCTER & GAMBLE CO
  • EP2349551B2 patent drawing
  • EP2349551B2 patent drawing
  • EP2349551B2 patent drawing

AI summary

The present invention relates to benefit agent containing delivery particles, compositions comprising said particles, and processes for making and using the aforementioned particles and compositions. When employed in compositions, for example, cleaning or fabric care compositions, such particles increase the efficiency of benefit agent delivery, there by allowing reduced amounts of benefit agents to be employed. In addition to allowing the amount of benefit agent to be reduced, such particles allow a broad range of benefit agents to be employed.