Benzene Sensor Using UV-Iodine Complex for Low Power Detection

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Solution Overview

Problem

Current benzene sensors are limited in sensitivity, detecting gases only at high concentrations above 50 ppm, and have high power consumption, making them inadequate for detecting lower concentrations and safe for field operations, where they are required to detect benzene levels as low as 0.5 ppm and consume less than 100 mW of electric power.

Innovation Solution

A benzene sensor utilizing an iodine complex on a substrate, irradiated with UV radiation, which forms an iodine-benzene complex, allowing for UV absorption detection to determine benzene presence, with cyclodextrine-iodine complexes stabilizing iodine and enhancing sensitivity and reducing power consumption.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If conventional benzene sensors (SnO2 thick film, electrochemical detectors, PIDs) are used, then they can detect benzene at high concentrations above 50 ppm, but they have high power consumption (about 660 mW for SnO2 sensors) and cannot detect lower concentrations below 50 ppm

Engineering Contradiction:
Improvedetection sensitivityVSAvoidpower consumption
Core Design Contradiction:
Measurement precisionVSUse of energy by moving object

Solution Approach 1:

The patent changes the operating parameters by using UV irradiation instead of thermal heating to activate the sensing material. The iodine complex on the substrate is activated by UV light at room temperature, eliminating the need for high-temperature heating (660 mW) while enabling detection at much lower concentrations (below 50 ppm, down to 0.5 ppm TLV level).

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses a composite sensing system consisting of a substrate with an iodine complex coating. This composite structure combines the substrate providing mechanical support with the iodine complex providing selective benzene detection capability through charge transfer complex formation, achieving both high sensitivity and low power consumption.

Inventive Principle:
Principle #40Composite materials

2Reliability

If conventional sensors are used for field operations, then they provide detection capability, but the high power consumption (660 mW) requires frequent battery replacement which raises safety issues

Engineering Contradiction:
Improvecontinuous operation capabilityVSAvoidpower consumption
Core Design Contradiction:
ReliabilityVSUse of energy by moving object

Solution Approach 1:

The patent replaces the thermal/chemical sensing mechanism (requiring heated elements and continuous power) with an optical sensing mechanism using UV irradiation. This substitution enables room-temperature operation with minimal power consumption, ensuring continuous reliable operation in field conditions without frequent battery replacement or safety hazards.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Temperature

If sensors operate at high power consumption levels, then they can maintain sensing temperature, but this is unsafe for field operations where portability and safety are critical

Engineering Contradiction:
Improvesensing temperatureVSAvoidsafety hazards
Core Design Contradiction:
TemperatureVSObject-affected harmful factors

Solution Approach 1:

The patent uses periodic UV irradiation pulses to activate the iodine complex sensing mechanism at room temperature, eliminating the need for continuous high-temperature heating. This periodic optical activation maintains sensing capability while operating safely at ambient temperature, removing the safety hazards associated with hot components in portable field devices.

Inventive Principle:
Principle #19Periodic action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The sensor achieves increased sensitivity for detecting benzene at lower concentrations and reduces power consumption, enabling early detection of hazardous benzene levels and improving safety in industrial applications.

Implementation Method 1

detecting a UV absorption in the intensity of radiation reflected from the iodine-benzene complex

Methodology Applied
Scientific EffectUV absorption: Absorption (EM radiation)

Implementation Method 2

forming an iodine-benzene complex

Methodology Applied
Scientific EffectCharge transfer complex formation: Chemical Bonding

Implementation Method 3

The iodine complex can include a cyclodextrine-iodine complex such as an alpha-cyclodextrine-iodine complex, a β-cyclodextrine iodine complex

Methodology Applied
Scientific EffectInclusion complex formation: Solvation

Data Source

PatentUS10254217B2Benzene sensors and associated methods
Publication Date: 2019.04.09 HONEYWELL INTERNATIONAL INC
  • US10254217B2 patent drawing

AI summary

In an embodiment, a benzene sensor comprises a substrate having an iodine complex disposed thereon, a radiation source configured to project UV radiation onto the complex, and a UV detector configured to detect a UV reflection off of the substrate having the iodine complex. The iodine complex can include a cyclodextrine-iodine complex such as an alpha-cyclodextrine-iodine complex, a β-cyclodextrine iodine complex, or any combination thereof.