Benzo-Indolocarbazole Derivatives for OLED Driving Voltage Reduction

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Solution Overview

Problem

Conventional organic electroluminescent materials suffer from high driving voltage requirements, low power efficiency, and short operational lifespan due to poor thermal stability and high glass transition temperatures, necessitating the development of materials with improved voltage properties and luminous efficiency for medium- and large-sized OLED panels.

Innovation Solution

Incorporating a benzo-indolocarbazole derivative as an organic electroluminescent compound, specifically a [a]benzo-indolocarbazole or [b]benzo-indolocarbazole derivative, which reduces driving voltage and enhances power efficiency by optimizing the host material's energy levels and mobility in the organic electroluminescent device.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Power

If phosphorescent host materials are used to achieve higher current efficiency, then current efficiency is improved, but driving voltage becomes significantly high

Engineering Contradiction:
Improvecurrent efficiencyVSAvoiddriving voltage
Core Design Contradiction:
PowerVSStress or pressure

Solution Approach 1:

The patent modifies the molecular structure of indolocarbazole derivatives by introducing benzo-fusion at specific positions ([a]benzo or [b]benzo-indolocarbazole structures) to change the HOMO energy level parameter. This structural modification achieves a balance between current efficiency and driving voltage by optimizing the energy level alignment in the light-emitting layer, resolving the contradiction between high current efficiency and low driving voltage

Inventive Principle:
Principle #35Parameter changes

2Power

If conventional organic electroluminescent materials are used to achieve good luminous characteristics, then luminous efficiency is improved, but thermal stability deteriorates

Engineering Contradiction:
Improveluminous efficiencyVSAvoidthermal stability
Core Design Contradiction:
PowerVSStability of the object's composition

Solution Approach 1:

The patent creates a composite molecular structure by fusing benzo rings with the indolocarbazole core at specific positions. This composite structure combines the beneficial properties of both components: the indolocarbazole provides good luminous characteristics and charge transport, while the benzo-fusion enhances thermal stability and raises the glass transition temperature, preventing material degradation during vacuum deposition

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of benzo-indolocarbazole derivatives in organic electroluminescent compounds results in devices with lower driving voltage and higher power efficiency, improving the operational lifespan and luminous characteristics, thereby addressing the limitations of conventional materials.

Implementation Method 1

The organic light-emitting compound moves into an excited state by the energy and emits light from energy when the organic light-emitting compound returns to the ground state from the excited state

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS11283028B2Organic electroluminescent compound and organic electroluminescent device comprising the same
Publication Date: 2022.03.22 DUPONT SPECIALTY MATERIALS KOREA LTD
  • US11283028B2 patent drawing
  • US11283028B2 patent drawing
  • US11283028B2 patent drawing

AI summary

The present disclosure relates to an organic electroluminescent compound and an organic electroluminescent device comprising the same. The organic electroluminescent compound of the present disclosure can provide an organic electroluminescent device having low driving voltage and/or high power efficiency properties.