Benzoate Stabilized Peroxide Hardener for Fastening Systems

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Solution Overview

Problem

Existing fastening systems using peroxide-based hardeners face challenges with phthalates, which are difficult to process, pose health hazards, and result in trade restrictions, while water-based stabilizers can disrupt the mixing process and reduce bond strength.

Innovation Solution

The use of ethylene glycol dibenzoate and diethylene glycol dibenzoate as phlegmatizers with dibenzoyl peroxide in the hardener component eliminates the need for phthalates and water, allowing for stable storage and easy processing, including filling into glass cartridges without waste, and maintains high temperature stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If phthalates are used as stabilizers in peroxide-based hardeners, then storage stability is improved, but health hazards and trade restrictions worsen

Engineering Contradiction:
Improvestorage stabilityVSAvoidhealth hazards
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent changes the chemical parameter of the stabilizer from phthalates to benzoates (specifically ethylene glycol dibenzoate and diethylene glycol dibenzoate). This parameter change maintains the stabilizing function while eliminating the harmful effects and trade restrictions associated with phthalates.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces problematic phthalate stabilizers with benzoate stabilizers that have shorter regulatory concerns and no trade restrictions. This substitution allows the product to be freely traded without the bureaucratic burden associated with phthalate-containing products.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

2Reliability

If phthalates are used as stabilizers in peroxide-based hardeners, then storage stability is improved, but processing difficulty worsens

Engineering Contradiction:
Improvestorage stabilityVSAvoidprocessing difficulty
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent changes the chemical parameter of the stabilizer from phthalates to benzoates, which have different physical and chemical properties. The benzoates provide comparable stabilization while being easier to process during manufacturing and cartridge filling operations.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If water is used as a stabilizer in hardener components, then storage stability is improved, but mixing performance and bond strength worsen

Engineering Contradiction:
Improvestorage stabilityVSAvoidbond strength
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent changes the physical state parameter of the stabilizer from aqueous (water-based) to organic (benzoate-based). This parameter change eliminates the water-related problems of disrupted mixing and reduced bond strength while maintaining storage stability through the chemical stabilizing action of the benzoates.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This solution provides a safe, efficient, and waste-free fastening system that is free from health hazards and trade restrictions, ensuring strong anchoring without the issues associated with phthalates and water-based stabilizers, and maintains stability across varying temperatures.

Implementation Method 1

Radical-curing resin components are widely used. Consequently, a corresponding hardener component typically contains a radical initiator, especially in the form of peroxides, to enable the resin component to cure.

Methodology Applied
Scientific EffectRadical polymerization: Photopolymerisation

Implementation Method 2

the hardener component contains other components/compounds that enable stable storage not only of the hardener component but ultimately also of the entire fastening system. Such additional compounds, usually present at least in the hardener component, can be fillers and/or phlegmatizing agents.

Methodology Applied
Scientific EffectPhlegmatization:

Data Source

PatentEP3712184B1Fastening system comprising a curing component with at least one benzoate
Publication Date: 2023.04.26 MKT METALL KUNSTSTOFF TECHNIK GMBH & CO KG
  • EP3712184B1 patent drawing
  • EP3712184B1 patent drawing

AI summary

The invention relates to a fastening system comprising two separate components (A) and (B). Component (A) contains at least one resin, while component (B), which acts as a hardener, contains at least one peroxide and at least one benzoate. The invention further relates to the use of such a fastening system, for example, for inserting anchoring elements into holes or crevices, particularly drill holes and/or concrete holes. A further object of the present invention is thus a method for fastening anchoring elements in holes or crevices. Likewise, the use of at least one benzoate for producing the fastening system according to the invention is a further object of the present invention.