Betaine Ester Triggerable Composition for Controlled Release

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Solution Overview

Problem

Functionally active chemicals in personal care and beauty products are unstable under environmental conditions, leading to short shelf lives, packaging challenges, and inefficient release mechanisms, which limits their adoption and efficacy.

Innovation Solution

A two-stage triggerable composition using betaine esters and stimuli-sensitive encapsulation polymers to stabilize and control the release of active chemicals, where betaine esters are converted into a nonvolatile form and released through hydrolysis upon exposure to an aqueous medium, triggered by environmental stimuli such as pH changes or enzymatic activity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If active chemicals are used in personal care products, then functional efficacy is improved, but stability under environmental conditions deteriorates

Engineering Contradiction:
Improvefunctional efficacyVSAvoidstability under environmental conditions
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The active chemical is nested within a betaine ester molecule, which is subsequently encapsulated within a polymer matrix. This nested structure provides multiple layers of protection: the betaine ester protects the active from environmental degradation, while the polymer capsule provides additional stabilization during storage and transport, resolving the contradiction between maintaining functional efficacy and ensuring environmental stability.

Inventive Principle:
Principle #7Nested doll (Nesting)

Solution Approach 2:

The betaine ester acts as an intermediary between the active chemical and the external environment. It serves as a protected carrier that can be stored stably but releases the active when triggered by specific stimuli (pH change, enzymes, or aqueous exposure), thus maintaining both stability during storage and functional efficacy when needed.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If active chemicals are released immediately, then functional efficacy is improved, but shelf life deteriorates

Engineering Contradiction:
Improvefunctional efficacyVSAvoidshelf life
Core Design Contradiction:
ReliabilityVSDuration of action of stationary object

Solution Approach 1:

The active chemical is converted into a betaine ester form in advance, which is inherently more stable and non-volatile. This preliminary transformation allows the product to be stored for extended periods without degradation, while the betaine ester remains primed to release the active chemical when exposed to triggering stimuli during use.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The invention changes the chemical parameter of the active from a volatile, unstable form to a non-volatile, stable betaine ester form. This parameter change enables long-term storage stability while preserving the ability to release the active chemical functionality when triggered by environmental conditions such as pH change, enzymatic activity, or aqueous exposure.

Inventive Principle:
Principle #35Parameter changes

3Stability of the object's composition

If encapsulation is used to stabilize actives, then stability is improved, but controlled release capability deteriorates

Engineering Contradiction:
ImprovestabilityVSAvoidcontrolled release capability
Core Design Contradiction:
Stability of the object's compositionVSEase of operation

Solution Approach 1:

The polymer capsule and betaine ester system transitions from a static, stable state during storage to a dynamic, responsive state when triggered. The capsule remains intact and protective under normal conditions, but undergoes structural changes when exposed to triggering stimuli (pH change, enzymes, or aqueous exposure), enabling controlled release of the active chemical at the desired time and location.

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The system is designed to automatically respond to environmental triggers without external intervention. When the product encounters specific conditions (such as skin pH, enzymatic environments, or aqueous exposure), the betaine ester self-hydrolyzes and the polymer capsule self-dissolves or opens, releasing the active chemical in a controlled manner that serves the product's function autonomously.

Inventive Principle:
Principle #25Self-service

4Ease of operation

If betaine esters are used for fragrance release, then controlled release is improved, but stability in acidic environments deteriorates

Engineering Contradiction:
Improvecontrolled releaseVSAvoidstability in acidic environments
Core Design Contradiction:
Ease of operationVSStability of the object's composition

Solution Approach 1:

The polymer capsule provides beforehand protection for the betaine ester against acidic degradation. The capsule acts as a cushioning barrier that protects the betaine ester from premature hydrolysis in acidic environments during storage and application, while still allowing the betaine ester to perform its controlled release function when triggered by appropriate stimuli such as neutral pH, enzymatic activity, or aqueous exposure.

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition provides long-term stability and controlled release of active chemicals, enhancing the shelf life and efficacy of products while minimizing side effects and packaging requirements.

Implementation Method 1

a betaine ester or betaine ester derivative of a functional active that releases the functional active through a hydrolysis reaction upon contact with an aqueous medium

Methodology Applied
Scientific EffectHydrolysis: Hydrolysis

Implementation Method 2

an encapsulation material for encapsulating the betaine ester or betaine ester derivative including a functional active, the encapsulation material triggerable to release the betaine ester or betaine ester derivative upon the occurrence of an environmental stimulus

Methodology Applied
Scientific EffectpH-sensitive encapsulation:

Data Source

PatentEP2916878B1Triggerable compositions for two-stage, controlled release of active chemistry
Publication Date: 2017.08.30 KIMBERLY CLARK WORLDWIDE INC
  • EP2916878B1 patent drawingFigure 1
  • EP2916878B1 patent drawingFigure 2
  • EP2916878B1 patent drawingFigure 3

AI summary

A triggerable composition for two-stage, controlled release of a functional active chemical includes an ecapsulation material for encapsulating a betaine ester or betaine ester derivative including a functional active. The encapsulation material is triggerable to release the betaine ester or betaine ester derivative at a first stage upon the occurrence with an environmental stimulus, such as a pH change, an enzymatic change, and a temperature change. The betaine ester or betaine ester derivative of a functional active with at least one hydroxyl group releases the functional active through a hydrolysis reaction upon contact with an aqueous medium.