Bi-layer elastomeric printing plates for high resolution

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Solution Overview

Problem

Current printing technologies face challenges in achieving high resolution and mechanical durability for elastomeric printing plates, particularly in large-scale reel-to-reel printing processes, as existing materials are either mechanically fragile or unsuitable for high-resolution applications.

Innovation Solution

A bi-layer printing plate design featuring a thermo- or photo-crosslinkable elastomeric floor layer and a thin photo-imageable elastomeric layer with chemically modified polymers, optimized for differential inking with hydrophilic or hydrophobic inks, utilizing semi-interpenetrating polymer networks (SIPNs) to enhance mechanical properties and resolution.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If unmodified elastomeric polymers are used for printing plates, then mechanical durability is improved, but relief feature depths become very large precluding high resolution printing

Engineering Contradiction:
Improvemechanical durabilityVSAvoidprinting resolution
Core Design Contradiction:
StrengthVSManufacturing precision

Solution Approach 1:

The printing plate is divided into a multilayered structure with different elastomeric polymer layers, each having different hardness and relief feature depths. The top layer has smaller relief features for high resolution printing, while the bottom layer has larger relief features for mechanical durability and conformal contact.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Different regions of the printing plate have different properties - the top layer has softer, smaller relief features optimized for high resolution, while the bottom layer has harder, larger relief features optimized for durability. This local differentiation allows each layer to perform its specific function optimally.

Inventive Principle:
Principle #3Local quality

2Manufacturing precision

If PDMS elastomeric stamps are used for high resolution printing, then printing resolution is improved, but mechanical fragility increases making them unsuitable for large scale reel-to-reel printing

Engineering Contradiction:
Improveprinting resolutionVSAvoidmechanical durability
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The printing plate is segmented into multiple layers where the top PDMS layer provides high resolution printing capability while the bottom layer provides mechanical durability. This segmentation allows the fragile high-resolution layer to be supported by a robust base layer.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention uses composite elastomeric polymer materials with different properties in each layer. The top layer uses PDMS or similar soft elastomers for high resolution, while the bottom layer uses harder elastomeric polymers for mechanical strength, creating a composite structure that combines both benefits.

Inventive Principle:
Principle #40Composite materials

3Strength

If standard elastomeric printing plates are used, then mechanical durability is maintained, but compatibility with hydrophilic inks is reduced

Engineering Contradiction:
Improvemechanical durabilityVSAvoidink compatibility
Core Design Contradiction:
StrengthVSAdaptability or versatility

Solution Approach 1:

The surface properties of the printing plate are locally modified to create hydrophobic regions that are compatible with hydrophilic inks. The chemically modified polymers with fluoroalkyl or hydroxyl side groups create differential wetting patterns that enable selective inking while maintaining the overall mechanical durability of the elastomeric structure.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The chemical composition of the polymer is changed by adding side groups (fluoroalkyl or hydroxyl) that alter the surface energy and wettability properties. This parameter change enables the elastomeric polymer to become compatible with hydrophilic inks while retaining its mechanical properties.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The bi-layer plate achieves high resolution printing with improved mechanical durability, enabling selective inking and compatibility with hydrophilic or hydrophobic inks, addressing the limitations of existing materials in high-resolution and large-scale printing applications.

Implementation Method 1

the polymer is photoimageable and has been chemically modified to contain either hydrophobic fluoroalkyl side groups or hydrophilic hydroxyl side groups to provide differential wetting with hydrophilic inks

Methodology Applied
Scientific EffectHydrophobic effect: Hydrophobe

Implementation Method 2

the polymer is photoimageable and has been chemically modified to contain either hydrophobic fluoroalkyl side groups or hydrophilic hydroxyl side groups to provide differential wetting with hydrophilic inks

Methodology Applied
Scientific EffectHydrophilic effect: Hydrophile

Implementation Method 3

chemically modified to contain either hydrophobic fluoroalkyl side groups or hydrophilic hydroxyl side groups to provide differential wetting with hydrophilic inks

Methodology Applied
Scientific EffectWetting: Wetting

Implementation Method 4

the polymer layer comprises an elastomeric block copolymer... that has been chemically modified... along with separate photoimaging constituents

Methodology Applied
Scientific EffectPhotopolymerisation: Photopolymerisation

Data Source

PatentUS9248686B2High resolution, solvent resistant, thin elastomeric printing plates
Publication Date: 2016.02.02 DUPONT ELECTRONICS INC

AI summary

The present invention relates to a printing element having at least one polymer layer which has photoimageable constituents and a chemically functionalized polymer to make the polymer layer either more hydrophobic or hydrophilic. In one embodiment, the printing element comprises two adjacent polymer layers on a substrate in which the photoimaged layer comprises a polymer chemically modified with hydrophobic fluoroalkyl side groups to provide differential wetting with hydrophilic inks.