Bicomponent Reactive Ink for Non-Porous Substrates

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Solution Overview

Problem

Current inkjet printing technologies face challenges in fixing ink on non-porous surfaces like plastic, glass, and metal, as existing methods require high temperatures or UV exposure, and reactive inks with mixed monomers and catalysts are unstable and prone to clogging, limiting substrate options and printer reliability.

Innovation Solution

A two-component reactive ink system comprising a polymerizable monomer and a polymerization catalyst, where the monomer forms a polymeric film at low temperatures within thirty minutes, allowing simultaneous or successive jetting of components using a multichamber printing head, ensuring stable polymerization and adhesion without undesired polymerization in the printing head.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If reactive inks with mixed monomers and catalysts are used, then polymerization can occur, but the ink becomes unstable and prone to clogging

Engineering Contradiction:
Improveink stabilityVSAvoidclogging
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The ink system is divided into two separate components: Component A containing the monomer and Component B containing the catalyst. These components are stored separately and only mix after ejection from the printhead, preventing premature polymerization and clogging while enabling controlled polymerization on the substrate surface.

Inventive Principle:
Principle #1Segmentation

2Reliability

If high temperatures are used for thermal polymerization, then polymerization occurs, but substrate selection is limited to thermally stable materials

Engineering Contradiction:
Improvepolymerization efficiencyVSAvoidsubstrate compatibility
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The polymerization process is shifted from high-temperature thermal initiation to low-temperature catalytic initiation. The catalyst enables polymerization to proceed at temperatures suitable for a wide range of substrates including plastics, glass, and metal, expanding substrate compatibility while maintaining polymerization efficiency.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If UV polymerization is used, then polymerization occurs, but three-dimensional objects and non-planar surfaces cannot be effectively printed

Engineering Contradiction:
Improvepolymerization efficiencyVSAvoidsurface geometry compatibility
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The UV light-based polymerization mechanism is replaced with a chemical catalysis mechanism. The catalyst-containing component enables polymerization through chemical reaction rather than photochemical initiation, allowing the ink to polymerize on complex three-dimensional surfaces and non-planar objects without requiring UV light access from all angles.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

4Productivity

If thermal ink-jet systems are used with polymerizable inks, then ink ejection occurs, but the high temperature promotes premature polymerization

Engineering Contradiction:
Improveink ejection capabilityVSAvoidink stability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The ink is segmented into two separate components that are stored and transported independently. Component A (monomer) and Component B (catalyst) are ejected separately through the thermal ink-jet system, preventing premature polymerization in the heated ejection chamber while maintaining the ability to polymerize after deposition on the substrate.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution enables efficient and stable ink fixation on non-porous surfaces at low temperatures, preventing clogging and maintaining printer reliability, while allowing for the printing of diverse substrates, including those with high thermal stability and complex geometries.

Implementation Method 1

the ink may comprise reactive components able to polymerise by thermal or photochemical treatments and to form a film which fixes and keeps the colorant on the surface of the substrate

Methodology Applied
Scientific EffectPolymerization: Photopolymerisation

Implementation Method 2

The thermal resistance causes the evaporation of the ink solvent (usually water) and the formation of a bubble, which in turn causes the ink ejection through the head nozzle

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 3

A first kind of device consists in a piezoelectric system which comprises a head fed with an ink which is ejected from a nozzle by a piezoelectric transducer which produces a pressure pulse

Methodology Applied
Scientific EffectPiezoelectric effect: Piezoelectric Effect

Implementation Method 4

A second kind consists in an acoustic system employing the ability of a sound pulse of provoking the release of droplets from a liquid surface

Methodology Applied
Scientific EffectAcoustic cavitation: Acoustic Cavitation

Data Source

PatentUS9574096B2Bicomponent reactive ink for ink jet printing
Publication Date: 2017.02.21 SICPA HOLDING SA
  • US9574096B2 patent drawing
  • US9574096B2 patent drawing

AI summary

The present invention relates to (i) a reactive ink for ink jet printing comprising a two-component system, the first component comprising a polymerizable monomer, and the second component comprising a polymerization catalyst, wherein the monomer is able to form a polymeric film at low temperature within thirty minutes, preferably within ten minutes, from contacting the catalyst, (ii) a process of making an image on a non-porous substrate using such a reactive ink, and an ink jet print head including a two component ink-system.