Bicontinuous Coating Composition Chip Resistance

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Solution Overview

Problem

The automotive industry faces challenges in developing coating systems with improved chip resistance without the need for additional coating layers, particularly on difficult-to-coat substrates like zinc-coated metals, while maintaining efficiency and cost-effectiveness.

Innovation Solution

A coating composition featuring a film-forming component with a functional group-containing resinous binder and a crosslinking agent, forming a bicontinuous morphology when cured, which can be used in various coating layers such as primer, basecoat, and clearcoat, potentially eliminating the need for an anti-chip primer layer.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If multiple coating layers are applied to improve chip resistance, then chip resistance and corrosion protection are improved, but coating system complexity and processing time increase

Engineering Contradiction:
Improvechip resistanceVSAvoidcoating system complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent combines multiple coating layers into a single-layer coating that integrates the protective functions previously distributed across separate layers. The single-layer coating incorporates crosslinked polymer networks and functional additives that simultaneously provide chip resistance, corrosion protection, and adhesion, eliminating the need for multiple individually applied layers.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The single-layer coating is designed to perform multiple functions that were previously divided among different coating layers. It provides anti-chip protection, corrosion resistance, adhesion to difficult substrates, and surface protection simultaneously, making it a universal coating solution that replaces specialized multi-layer systems.

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Reliability

If multiple coating layers are applied to improve chip resistance, then protection against paint loss is improved, but processing time and cost increase

Engineering Contradiction:
Improveprotection against paint lossVSAvoidprocessing time
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The patent merges the protective functions of multiple coating layers into a single application step. The single-layer coating is formulated with crosslinked polymers and functional additives that provide equivalent or superior protection against paint loss while being applied in one coat, thereby reducing the total number of coating cycles and drying times required.

Inventive Principle:
Principle #5Merging (Combining)

3Reliability

If an anti-chip primer layer is applied to improve chip resistance on difficult substrates, then adhesion and chip resistance are improved, but coating system complexity increases

Engineering Contradiction:
Improveadhesion on difficult substratesVSAvoidcoating system complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The single-layer coating is designed to function as both the adhesion promoter and the protective topcoat simultaneously. It contains functional groups and crosslinked structures that provide strong adhesion to difficult substrates like zinc-coated metals, while also delivering chip resistance and corrosion protection, eliminating the need for a separate anti-chip primer layer.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The patent extracts and eliminates the separate anti-chip primer layer from the coating system by incorporating its adhesion-promoting functions directly into the single-layer coating formulation. The single-layer coating contains reactive functional groups and crosslinked structures that perform the adhesion function previously requiring a dedicated primer layer.

Inventive Principle:
Principle #2Taking out (Extraction)

4Strength

If coating layers with excessive hardness differences are used, then specific protective properties are achieved, but delamination between layers occurs reducing chip resistance

Engineering Contradiction:
Improveprotective propertiesVSAvoidchip resistance
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The single-layer coating incorporates a crosslinked polymer network with spatially varying properties that provide both hardness for protection and flexibility to prevent delamination. The crosslinked structure creates local regions of different mechanical properties within the same layer, allowing the coating to resist chipping while maintaining adhesion to the substrate.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The coating composition provides enhanced chip resistance and flexibility, reducing the risk of delamination and paint loss, while allowing for a more compact and efficient coating process by eliminating unnecessary layers.

Implementation Method 1

a crosslinking agent having at least two functional groups that are reactive with the functional groups of the film-forming component (a), wherein, when the composition is applied and cured to form a cured coating, the cured coating is characterized as having a bicontinuous morphology

Methodology Applied
Scientific EffectCrosslinking: Chemical Bonding

Data Source

PatentUS7709093B2Coatings with improved chip resistance and methods of making the same
Publication Date: 2010.05.04 PPG INDUSTRIES OHIO INC
  • US7709093B2 patent drawing
  • US7709093B2 patent drawing
  • US7709093B2 patent drawing

AI summary

A coating composition, formed of a film-forming component comprising a functional group-containing resinous binder and, optionally, a crosslinking agent having at least two functional groups that are reactive with the functional groups of the film-forming component, wherein, when the composition is applied and cured to form a cured coating, the cured coating is characterized as having a bicontinuous morphology. Methods of making the coating composition and coatings prepared therefrom are also provided. The coating composition can provide improved physical properties, such as chip resistance, when incorporated into a coating.