Bidirectional Solid-State Capacitor for Alkali Vapor Control

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Solution Overview

Problem

Miniature vapor cells for atomic clocks and navigation systems face challenges in achieving precise alkali metal loading, stability, and rapid response due to high surface-area-to-volume ratios, slow loading processes, and contamination issues, which hinder their integration into chip-scale devices.

Innovation Solution

A bidirectional solid-state electrochemical charge-depletion capacitor system with an ion conductor that allows for electrical control of alkali metal and alkaline earth metal vapor pressure, using a first electrode permeable to mobile ions and a second electrode that does not form these ions, enabling rapid and controlled loading and unloading of alkali metals at low voltages and temperatures.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If traditional manual preparation steps are used to load alkali metal into miniature vapor cells, then alkali metal can be introduced into the system, but the process is difficult to control, requires external heating, and is slow with little control over the amount delivered

Engineering Contradiction:
Improvecontrol over alkali metal amountVSAvoidloading speed
Core Design Contradiction:
Measurement precisionVSProductivity

Solution Approach 1:

The patent replaces manual mechanical preparation steps with an automated electrochemical system. A solid electrolyte layer loaded with alkali metal ions is used, where applying a voltage causes ions to migrate and be released into the vapor cell. This substitution of mechanical manual operations with an electrical field-driven process enables precise control over the amount and timing of alkali metal delivery, while dramatically increasing loading speed and automating the entire process.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Extent of automation

If alkali metal dispensers are used to automate alkali metal release, then the process is automated, but fabrication compatibility with chip-scale devices is difficult and the timescales are still on the order of seconds to minutes

Engineering Contradiction:
Improveautomation of alkali metal releaseVSAvoidfabrication compatibility
Core Design Contradiction:
Extent of automationVSDevice complexity

Solution Approach 1:

The patent changes the fundamental operating parameters of alkali metal dispensing by using solid-state electrochemical processes instead of thermal or chemical reaction-based dispensing. By applying voltages across a solid electrolyte layer containing alkali metal ions, the system achieves automated release with response times in the millisecond range, far faster than traditional dispensers. The solid-state nature of the electrolyte layer enables direct integration with chip-scale fabrication processes, eliminating the complexity associated with traditional dispenser mechanisms.

Inventive Principle:
Principle #35Parameter changes

3Volume of moving object

If miniature vapor cells are used to reduce system size, then the vapor cell volume is reduced for chip-scale applications, but the surface-area-to-volume ratio increases making precise alkali metal loading difficult and vapor pressure unstable

Engineering Contradiction:
Improvevapor cell volumeVSAvoidalkali metal loading precision
Core Design Contradiction:
Volume of moving objectVSManufacturing precision

Solution Approach 1:

The patent implements a self-regulating system where the solid electrolyte layer acts as both the alkali metal source and a controlled release mechanism. The layer is initially loaded with a known amount of alkali metal ions, and applying a voltage causes a precise stoichiometric amount of ions to migrate and be released into the vapor cell. This self-service mechanism eliminates the need for complex external loading equipment, enabling precise loading even in miniature cells with high surface-area-to-volume ratios. The system automatically controls the release amount based on the applied voltage and electrolyte properties.

Inventive Principle:
Principle #25Self-service

4Quantity of substance

If traditional alkali metal sources are used in miniature vapor cells, then vapor pressure can be maintained, but contamination occurs and longevity is reduced

Engineering Contradiction:
Improvealkali metal vapor pressureVSAvoidsystem longevity
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The patent introduces a solid electrolyte layer as an intermediary between the alkali metal source and the vapor cell environment. This electrolyte layer contains alkali metal ions in a controlled solid-state matrix, preventing direct contact and contamination between the alkali metal and the vapor cell walls or other components. When voltage is applied, ions migrate through the electrolyte and are released in a controlled manner, maintaining vapor pressure while preventing the contamination and degradation issues associated with traditional alkali metal sources. This intermediary structure significantly extends system longevity and reliability.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This solution enables fast and precise control of alkali vapor pressure, extending cold-atom lifetimes, simplifying fabrication, and reducing contamination, thus addressing the limitations of traditional vapor cell systems in miniaturization and stability.

Implementation Method 1

an ion conductor interposed between the first electrode and the second electrode, wherein the ion conductor is ionically conductive for the mobile ions

Methodology Applied
Scientific EffectIonic conduction: Conduction (electrical)

Implementation Method 2

a first electrode disposed in contact with the vapor-cell region... wherein the first electrode is permeable to mobile ions and/or neutral atoms formed from the mobile ions

Methodology Applied
Scientific EffectIonization: Ionisation

Data Source

PatentUS9837177B1Vapor cells with a bidirectional solid-state charge-depletion capacitor for mobile ions
Publication Date: 2017.12.05 HRL LAB
  • US9837177B1 patent drawing
  • US9837177B1 patent drawing
  • US9837177B1 patent drawing

AI summary

The present invention provides a vapor-cell system comprising: a vapor-cell region configured for vapor-cell optical paths; a first electrode disposed in contact with the vapor-cell region; a second electrode electrically isolated from the first electrode; and an ion conductor interposed between the first electrode and the second electrode. The first electrode, the ion conductor, and the second electrode collectively form a bidirectional solid-state electrochemical charge-depletion capacitor. The ion conductor is ionically conductive for mobile ions, such as Rb+, Cs+, Na+, K+, or Sr2+. The first electrode is permeable to the mobile ions and/or neutral atoms formed from the mobile ions. The system can be electrically controlled to quickly pump mobile ions into or out of the vapor-cell region. The system may further contain an atom chip, and the vapor-cell optical paths may be configured to trap a population of cold atoms. Methods of operating these vapor-cell systems are also disclosed.