Bimaterial Valve Seat Ring Sintering Process

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Solution Overview

Problem

The powder-technological production of valve seat rings from two materials is technically challenging due to significant density changes at medium temperatures, leading to mechanical stresses and difficulties in achieving a damage-free bond between the materials, which affects the reliability and performance of the composite component.

Innovation Solution

A method involving the selection of a function material and a secondary material with specific compositions and processing techniques, such as atomization and fluidized bed granulation, to produce fine powders that are then pressed and sintered together, ensuring a bond without damage and matching mechanical properties like heat resistance and expansion coefficients, resulting in a reliable bimaterial valve seat ring.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If powder of two different materials is filled into a cavity and jointly processed into a composite body, then a bimaterial valve seat ring can be produced with combined material properties, but significant density changes at medium temperatures during sintering lead to mechanical stresses and bonding difficulties

Engineering Contradiction:
Improvematerial combination capabilityVSAvoidbond integrity
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent applies parameter changes by carefully controlling sintering temperature parameters and holding times to manage density changes. The sintering process uses specific temperature ranges (900-1300°C) with controlled heating rates (3-10°C/min) and holding times (30-120 minutes) to minimize differential density changes between the two materials, thereby reducing mechanical stresses at the interface while achieving proper bonding.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite materials by combining two different metal powders (e.g., WC-Fe hard metal and Fe-based tough material) into a layered composite structure. The composite is designed with specific layer configurations where each material contributes its advantageous properties, and the interface is engineered to accommodate thermal expansion differences through controlled sintering that creates a transition zone reducing stress concentration.

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If conventional powder metallurgy is used to produce bimaterial components, then material combinations with different densities can be joined, but the process requires precise control of filling sequence and results in technical mastery difficulties

Engineering Contradiction:
Improveprocessing simplicityVSAvoiddensity distribution control
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent applies segmentation by dividing the composite component into distinct layers, each made from a different material powder. The filling process is segmented into sequential steps where each material layer is compacted separately with optimized pressing forces (400-600 MPa), allowing independent control of each layer's density before sintering, thereby simplifying the overall manufacturing process while maintaining precision.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent uses preliminary action by pre-compacting each material layer to achieve target green densities (69-74% TD) before sintering. The pressing operation is performed in advance with material-specific parameters to ensure uniform density distribution in each layer, preventing density-related defects during subsequent sintering and eliminating the need for complex real-time adjustments.

Inventive Principle:
Principle #10Preliminary action

3Strength

If sintering is performed to create a solid composite of two materials, then a manageable body is formed, but density curves differ significantly in the medium temperature range causing mechanical stresses

Engineering Contradiction:
Improvecomposite solidificationVSAvoidthermal stress
Core Design Contradiction:
StrengthVSStress or pressure

Solution Approach 1:

The patent introduces an intermediary approach by using a transition layer or intermediate material composition at the interface between the two materials. This intermediate zone has properties that bridge the gap between the two materials' thermal expansion coefficients and density changes, acting as a stress buffer during sintering in the medium temperature range (600-900°C) where differential expansion is most pronounced, thereby reducing mechanical stresses while maintaining composite strength.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method enables the production of valve seat rings with improved function characteristics, including reduced thermal expansion and creep, providing a stronger press fit and enhanced reliability against relaxation and deformation, outperforming cast Co-based materials in terms of thermal stability and performance.

Implementation Method 1

The two materials are produced by atomising a metal melt, as a result of which they reach a mean particle size of approximately 5 to 13 μm.

Methodology Applied
Scientific EffectAtomization:

Implementation Method 2

Following this, the powdery materials are each processed into a flowable granulate with a granulate size of substantially smaller than 2 and then the granulated second material 3, and subsequently uniaxially pressed

Methodology Applied
Scientific EffectFluidized bed granulation: Fluidisation

Implementation Method 3

After the joint uniaxial pressing at 600 MPa, a moulded body is created which after the sintering permits a solid composite of both materials.

Methodology Applied
Scientific EffectUniaxial pressing: Compression

Implementation Method 4

After the joint uniaxial pressing at 600 MPa, a moulded body is created which after the sintering permits a solid composite of both materials.

Methodology Applied
Scientific EffectSintering: Sintering

Data Source

PatentUS10272496B2Method for producing a valve seat ring
Publication Date: 2019.04.30 MAHLE INT GMBH
  • US10272496B2 patent drawing
  • US10272496B2 patent drawing
  • US10272496B2 patent drawing

AI summary

A valve seat ring and a method for producing the same may include a first material and a second material. The first material may be composed of approximately 15 to 30% by weight of Mo, approximately 5 to 30% by weight of chromium, approximately 0 to 5% by weight of Si, approximately 0 to 2% by weight of C, and up to 5% by weight of other elements and a portion of Co. The second material may be composed of approximately 10 to 12% by weight of Cr, approximately 0.5 to 0.8% by weight of Mn, approximately 0.5 to 1% by weight of Si, approximately 0.5 to 0.9% by weight of C, up to approximately 3% by weight of other elements and a reminder of Fe.