Bi-Metallocene Catalyst for Polyethylene Stiffness and ESCR Balance

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Solution Overview

Problem

Conventional metallocene catalyst systems for polyethylene production face a trade-off between achieving high stiffness and high environmental stress cracking resistance (ESCR), failing to produce materials with both properties simultaneously.

Innovation Solution

A catalyst composition comprising a first metallocene compound, a second metallocene compound, an activator-support, and an organoaluminum compound, specifically designed to balance stiffness and slow crack growth resistance, utilizing tightly bridged and unbridged metallocenes with specific structural features and ratios, along with a chemically-treated solid oxide activator.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If conventional metallocene catalyst systems are used to produce polyethylene with high stiffness, then stiffness is improved, but environmental stress cracking resistance deteriorates

Engineering Contradiction:
ImprovestiffnessVSAvoidenvironmental stress cracking resistance
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The invention divides the catalyst system into two distinct metallocene components: a bridged metallocene (providing stiffness) and an unbridged metallocene (providing ESCR). This segmentation allows each catalyst component to independently contribute its strengths, resolving the contradiction between stiffness and environmental stress cracking resistance that plagues conventional single-catalyst systems

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention creates a composite catalyst system combining two different metallocene types with complementary properties. The bridged metallocene (e.g., ansa-metallocene) produces polymer chains conferring high stiffness, while the unbridged metallocene produces chains providing excellent environmental stress cracking resistance. The synergistic combination yields a polyethylene resin that simultaneously achieves both high stiffness and high ESCR

Inventive Principle:
Principle #40Composite materials

2Reliability

If conventional metallocene catalyst systems are used to produce polyethylene with high environmental stress cracking resistance, then environmental stress cracking resistance is improved, but stiffness deteriorates

Engineering Contradiction:
Improveenvironmental stress cracking resistanceVSAvoidstiffness
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The invention segments the catalyst function between two specialized metallocenes: the unbridged metallocene optimized for producing chains with high environmental stress cracking resistance, and the bridged metallocene optimized for producing chains with high stiffness. This functional segmentation eliminates the need to compromise either property

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The composite catalyst system integrates unbridged metallocene (for ESCR) and bridged metallocene (for stiffness) in specific ratios. This composite approach allows the final polyethylene resin to exhibit both high environmental stress cracking resistance and high stiffness, overcoming the limitation of conventional single-catalyst systems that could only optimize for one property at a time

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The bi-metallocene catalyst system achieves a balance of high stiffness and slow crack growth resistance, making the resulting polyolefins suitable for applications like PE-100 pipe production, which meets stringent physical and chemical requirements.

Implementation Method 1

Hitchcock et al, Polyhedron, 14(19), 2745-52 describes ligand redistribution reactions as a route to cyclopentadienyl or 1-aza-allylzirconium(IV) trichlorides. Hitchcock et al describes mixing equimolar portions of ZrCl4 and [Zr(Cp)x(R-C5H4-xCl)2] in toluene to form [Zr(Cp)(R-C5H4Cl)Cl2]

Methodology Applied
Scientific EffectLigand redistribution reaction: Chemical Bonding

Implementation Method 2

The catalyst composition comprises a first metallocene compound, a second metallocene compound, an activator-support, and an organoaluminum compound

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 3

The activator-support may be fluorided alumina, chlorided alumina, bromided alumina, sulfated alumina, fluorided silica-alumina, chlorided silica-alumina, bromided silica-alumina, sulfated silica-alumina

Methodology Applied
Scientific EffectLewis acid catalysis: Catalysis

Data Source

PatentEP2329882B1Process for producing monocyclopentadienyl compounds
Publication Date: 2013.07.10 CHEVRON PHILLIPS CHEMICAL COMPANY LP
  • EP2329882B1 patent drawingFigure 1
  • EP2329882B1 patent drawingFigure 2
  • EP2329882B1 patent drawingFigure 3

AI summary

Catalyst compositions comprising a first metallocene compound, a second metallocene compound, an activator-support, and an organoaluminum compound are provided. An improved method for preparing cyclopentadienyl complexes used to produce polyolefins is also provided.