Low- and medium-temperature refrigeration

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Solution Overview

Problem

Current refrigeration and air conditioning systems face challenges due to the high Global Warming Potential (GWP) of hydrofluorocarbons (HFCs) and the high pressure requirements of carbon dioxide, which are not environmentally friendly, and existing heat transfer fluids like R-404A have high GWPs, necessitating the need for more efficient and environmentally friendly alternatives.

Innovation Solution

The use of binary compositions of 2,3,3-tetrafluoropropene and difluoromethane as heat transfer fluids in compression systems, particularly in counter-current or cross-current modes, offering zero ODP and low GWP, which can replace R-404A and R-407C, with existing compressors suitable and stabilized with minimal stabilizers.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If hydrofluorocarbons (HFCs) are used as refrigerants, then ozone depletion is reduced, but global warming potential increases

Engineering Contradiction:
Improveozone depletionVSAvoidglobal warming potential
Core Design Contradiction:
Object-affected harmful factorsVSObject-generated harmful factors

Solution Approach 1:

The invention changes the chemical composition parameters by using binary compositions of HFO-1234yf and HFC-32 with specific weight ratios (10-90% HFO-1234yf and 90-10% HFC-32), achieving a balance between ozone protection and reduced GWP compared to conventional HFCs

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses composite refrigerant formulations by combining two different compounds (HFO-1234yf and HFC-32) in specific proportions to achieve properties that neither component alone could provide, specifically low GWP while maintaining refrigeration effectiveness

Inventive Principle:
Principle #40Composite materials

2Object-generated harmful factors

If carbon dioxide is used as refrigerant, then global warming potential is reduced, but operating pressure increases

Engineering Contradiction:
Improveglobal warming potentialVSAvoidoperating pressure
Core Design Contradiction:
Object-generated harmful factorsVSStress or pressure

Solution Approach 1:

The invention changes the physical and chemical parameters of the refrigerant system by using HFO-1234yf/HFC-32 binary compositions that operate at moderate pressures, avoiding the extremely high pressures required by CO2 systems while maintaining low GWP

Inventive Principle:
Principle #35Parameter changes

3Productivity

If R-404A is used as refrigerant, then refrigeration performance is maintained, but global warming potential increases

Engineering Contradiction:
Improverefrigeration performanceVSAvoidglobal warming potential
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The invention changes the refrigerant composition parameters by replacing R-404A (GWP 3900) with HFO-1234yf/HFC-32 binary compositions having GWP ≤ 150, while maintaining refrigeration performance through optimized weight ratios and heat exchanger design

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention extracts and eliminates the high-GWP components from conventional refrigerant blends, specifically removing the trifluoroethane and pentafluoroethane components that contribute to high GWP in R-404A, and replacing them with low-GWP HFO-1234yf

Inventive Principle:
Principle #2Taking out (Extraction)

4Device complexity

If existing compressors are used with new refrigerants, then device complexity is reduced, but coefficient of performance decreases

Engineering Contradiction:
Improvecompressor developmentVSAvoidcoefficient of performance
Core Design Contradiction:
Device complexityVSUse of energy by moving object

Solution Approach 1:

The invention optimizes the operating parameters of existing compressors by adjusting refrigerant charge amounts, expansion valve settings, and heat exchanger configurations to accommodate the specific thermodynamic properties of HFO-1234yf/HFC-32 binary compositions, thereby maintaining high COP without developing new compressors

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

These binary compositions provide a higher coefficient of performance (COP) in low and medium temperature refrigeration, reducing the need for new compressor development and offering a more environmentally friendly solution with improved energy efficiency.

Implementation Method 1

A heat exchanger is a device that transfers thermal energy from one fluid to another without mixing them. The heat flows through the exchange surface that separates the fluids.

Methodology Applied
Scientific EffectHeat transfer: Conduction (thermal)

Implementation Method 2

The two fluids are arranged parallel but flow in opposite directions: counter-current (counter-current) flow

Methodology Applied
Scientific EffectCounter-current heat exchange: Convection

Data Source

PatentEP3059292B1Low- and medium-temperature refrigeration
Publication Date: 2024.11.20 ARKEMA FRANCE SA
  • EP3059292B1 patent drawing
  • EP3059292B1 patent drawing
  • EP3059292B1 patent drawing

AI summary

The subject of the present invention is the use of the binary compositions of 2,3,3,3-tetrafluoropropene and difluoromethane as a heat transfer fluid in compression refrigeration systems, low and medium temperature, with exchangers operating in counter-current or in cross-current mode with counter-current tendency. It also relates to a heat transfer process.