Binder-Jet SOFC Interconnects for Dense, Warp-Free Manufacturing

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Solution Overview

Problem

Conventional powder metallurgy processes for forming solid oxide fuel cell (SOFC) interconnects are costly due to high capital and operating expenses, and result in density variations and warping, with additional steps required to achieve a dense, gas-tight interconnect.

Innovation Solution

The method involves binder jet printing a metal alloy powder or mixture to form a green interconnect, followed by debinding and pressureless sintering, eliminating the need for high-temperature oxidation and grit blasting, and allowing for the production of dense, chromium-iron alloy interconnects with reduced thickness and improved thermal conductivity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional powder metallurgy processes are used to form interconnects, then the manufacturing process is established, but production costs are high and density variations occur

Engineering Contradiction:
Improvedensity uniformityVSAvoidproduction cost
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The invention changes the manufacturing process parameters by using binder jet printing technology instead of conventional powder metallurgy. This involves depositing binder material selectively on metal powder layers to form green interconnects, which are then sintered at controlled temperatures. This parameter change achieves uniform density distribution while reducing production costs through automated layer-by-layer manufacturing.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention replaces the conventional mechanical powder metallurgy process with a binder jet printing system that uses controlled binder deposition. Instead of traditional mechanical pressing and sintering, the system uses inkjet-like deposition of binder material to selectively bind metal particles, followed by controlled thermal processing. This substitution eliminates density variations and reduces manufacturing complexity.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Reliability

If conventional powder metallurgy processes are used, then interconnects can be produced, but warping and density variations occur requiring additional steps

Engineering Contradiction:
Improveinterconnect density consistencyVSAvoidmanufacturing process steps
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The invention performs preliminary binding action during the layer-by-layer manufacturing process itself. The binder jet printing process selectively deposits binder material to form a green interconnect structure with uniform density from the beginning. This preliminary action eliminates the need for subsequent oxidation and grit blasting steps required in conventional processes to correct density variations and warping.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The invention extracts and eliminates the problematic oxidation and grit blasting steps from the manufacturing process. By using binder jet printing with controlled binder deposition and selective sintering, the process directly produces dense, warping-free interconnects, removing the need for additional post-processing steps that were previously necessary to correct defects.

Inventive Principle:
Principle #2Taking out (Extraction)

3Ease of manufacture

If binder jet printing is used to form green interconnects, then production costs are reduced and density uniformity is improved, but additional debinding and sintering steps are required

Engineering Contradiction:
Improveproduction costVSAvoidmanufacturing cycle time
Core Design Contradiction:
Ease of manufactureVSProductivity

Solution Approach 1:

The invention maintains continuous useful action throughout the manufacturing process. The binder jet printing process builds the green interconnect layer by layer in a continuous automated sequence. The subsequent debinding and sintering steps are integrated into a continuous thermal processing sequence, eliminating idle time and maximizing productivity while keeping production costs low through automated operation.

Inventive Principle:
Principle #20Continuity of useful action

Solution Approach 2:

The invention merges the debinding and sintering steps into a single integrated thermal processing operation. Instead of separate sequential steps with intermediate handling, the green interconnect undergoes combined thermal treatment that simultaneously removes binder and densifies the structure. This merging reduces cycle time and increases productivity while maintaining cost efficiency.

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach reduces production costs and eliminates density variations, enabling the creation of dense, gas-tight interconnects with improved thermal conductivity and reduced warping, while simplifying the manufacturing process.

Implementation Method 1

binder jet printing a metal alloy powder or a metal powder mixture to form a green interconnect

Methodology Applied
Scientific EffectBinder jet printing: 3D Printing

Implementation Method 2

debinding the green interconnect

Methodology Applied
Scientific EffectThermal decomposition: Pyrolysis

Implementation Method 3

sintering the green interconnect to form a metal alloy interconnect for an electrochemical stack

Methodology Applied
Scientific EffectSintering: Sintering

Data Source

PatentUS20240139810A1Binder jet printing of metallic interconnect for solid oxide electrochemical cell stack
Publication Date: 2024.05.02 BLOOM ENERGY CORP
  • US20240139810A1 patent drawing
  • US20240139810A1 patent drawing
  • US20240139810A1 patent drawing

AI summary

A method includes binder jet printing a metal alloy powder or a metal powder mixture to form a green interconnect, debinding the green interconnect, and sintering the green interconnect to form a metal alloy interconnect for an electrochemical stack.