Metal Binder-Jetting Liquid Composition for Stable Discharge and Sintering

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Solution Overview

Problem

Existing methods for producing metal objects using binder jetting and powder metallurgy face issues with high viscosity of the object forming liquid, insufficient bending strength of green bodies, and low sintering density of sintered bodies.

Innovation Solution

An object forming liquid containing specific structural units in resins and an organic solvent, free of water, is applied to a layer of metal particles, which improves the binding strength and sintering density through controlled thermal decomposition and solubility in organic solvents, allowing for better discharge and formation of objects.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If conventional object forming liquid is used in binder jetting, then the liquid can be applied to metal particles, but the viscosity is high and discharge is unstable

Engineering Contradiction:
Improvedischarge stabilityVSAvoidviscosity
Core Design Contradiction:
Ease of operationVSForce

Solution Approach 1:

The patent changes the chemical composition parameters of the object forming liquid by incorporating specific resin components (vinyl acetate resin, carboxymethyl cellulose) and controlling the water content (5-20 mass%), which reduces viscosity and improves discharge stability from the inkjet head

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses a composite binder system combining multiple resin types (vinyl acetate resin with carboxymethyl cellulose) to achieve optimal balance between viscosity, adhesion, and discharge properties, resolving the contradiction between ease of operation and material resistance

Inventive Principle:
Principle #40Composite materials

2Strength

If conventional object forming liquid is used, then binding can occur, but the bending strength of green bodies is insufficient

Engineering Contradiction:
Improvebending strengthVSAvoidgreen body integrity
Core Design Contradiction:
StrengthVSEase of manufacture

Solution Approach 1:

The patent employs a composite resin system where vinyl acetate resin provides primary adhesion and carboxymethyl cellulose enhances green body strength and structural integrity, achieving sufficient bending strength for handling and sintering

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent optimizes the concentration ratios and molecular weights of resin components to enhance the mechanical properties of the green body, ensuring adequate bending strength while maintaining manufacturability

Inventive Principle:
Principle #35Parameter changes

3Force

If conventional object forming liquid is used, then sintering can proceed, but the sintering density of sintered bodies is low

Engineering Contradiction:
Improvesintering densityVSAvoidsintered body quality
Core Design Contradiction:
ForceVSManufacturing precision

Solution Approach 1:

The patent controls the water content (5-20 mass%) and resin concentration to ensure optimal porosity and binding during sintering, which enables high sintering density and improved manufacturing precision of the final sintered body

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution results in improved bending strength and sintering density of pre-sintering and post-sintering objects, enabling stable and accurate production of metal objects using inkjet methods.

Implementation Method 1

heating (see Japanese Translation of PCT International Application Publication No. JP-T-2020-511593)

Methodology Applied
Scientific EffectThermal decomposition: Pyrolysis

Implementation Method 2

an object forming liquid containing specific structural units in resins and an organic solvent, free of water

Methodology Applied
Scientific EffectSolvation: Solvation

Data Source

PatentUS12570845B2Object forming liquid and object producing method
Publication Date: 2026.03.10 RICOH CO LTD
  • US12570845B2 patent drawing
  • US12570845B2 patent drawing
  • US12570845B2 patent drawing

AI summary

Provided is an object forming liquid containing a resin containing at least one structural unit selected from the group consisting of a structural unit represented by a predetermined structural formula (1) and a structural unit represented by a predetermined structural formula (2), and an organic solvent, and substantially free of water. The object forming liquid is applied to a layer of a powder containing metal particles.