Binder Mixture for Powder Injection Molding Flowability

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Solution Overview

Problem

The existing binder mixtures in powder injection molding (PIM) processes limit the achievable geometries and sizes of molded parts due to insufficient flowability and strength, particularly in components with undercuts or large dimensions, restricting the weight and size of manufactured components.

Innovation Solution

A binder mixture comprising polymeric compounds like polyethylene and polypropylene, polyvinyl acetate, and non-polymeric compounds like waxes, specifically formulated to provide excellent flowability and green strength, allowing for the production of large-sized components with undercuts, and featuring a solvent-based debinding process that minimizes burr formation and dimensional instability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If conventional binders are used in PIM processes, then the mixture achieves sufficient green strength, but the flowability is limited which restricts achievable geometries and component sizes

Engineering Contradiction:
ImproveflowabilityVSAvoidgreen strength
Core Design Contradiction:
Ease of operationVSStrength

Solution Approach 1:

The invention uses a composite binder system combining polyethylene (or polypropylene) with polyvinyl acetate and wax. This composite approach allows the mixture to achieve both high flowability during injection and sufficient green strength after molding, resolving the contradiction between these two properties that limits PIM process application.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The invention modifies the binder composition parameters by incorporating specific ratios of polyethylene (10-60 wt%), polyvinyl acetate (10-65 wt%), and wax (10-65 wt%). These parameter changes optimize the balance between flowability and green strength, enabling production of larger and more geometrically complex components.

Inventive Principle:
Principle #35Parameter changes

2Adaptability or versatility

If the binder mixture is formulated for high flowability to enable complex geometries, then the achievable geometries expand, but the green strength may be compromised

Engineering Contradiction:
Improveachievable geometriesVSAvoidgreen strength
Core Design Contradiction:
Adaptability or versatilityVSStrength

Solution Approach 1:

The multi-component binder system provides both the flowability needed for complex geometries including undercuts and the green strength required to maintain structural integrity. The synergistic combination of polyethylene, polyvinyl acetate, and wax achieves properties that single-component binders cannot provide.

Inventive Principle:
Principle #40Composite materials

3Adaptability or versatility

If larger and more complex components are produced using existing binders, then the application range expands, but dimensional stability and crack resistance deteriorate

Engineering Contradiction:
Improveapplication rangeVSAvoiddimensional stability
Core Design Contradiction:
Adaptability or versatilityVSManufacturing precision

Solution Approach 1:

By optimizing the binder composition parameters and ratios, the invention achieves sufficient green strength and dimensional stability even for large-scale components. This allows expansion of the PIM application range to include larger and more complex parts without sacrificing manufacturing precision.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The binder mixture enables the production of large, complex components with enhanced flowability and green strength, reducing the tendency for cracks and burr formation, and providing sufficient dimensional stability for subsequent sintering, thus expanding the application range of PIM processes.

Implementation Method 1

the compound B and the compound C in a solvent selected from a group comprising acetone, xylene, turpentine, tetrahydrofuran and/or ethyl acetate, at a temperature in a range from about 20°C to about 90°C, preferably about 30°C to about 85°C preferably about 35 °C to about 70 °C, are soluble

Methodology Applied
Scientific EffectSolvation: Solvation

Implementation Method 2

with a first softening range, measured according to DIN ISO 4625, and with a first Melt viscosity, measured according to DIN 54811; at least one polymeric compound B selected from a group comprising at least one polyvinyl acetate in an amount of about 10% by weight to about 65% by weight, preferably about 20% by weight to about 45% by weight, based on the total amount the binder mixture, with a second softening range, measured according to DIN ISO 4625, and a second melt viscosity

Methodology Applied
Scientific EffectMelting: Melting

Data Source

PatentEP2739417B1Binder mixture for producing moulded parts using injection methods
Publication Date: 2015.10.07 GNK SINTER METALS GMBH & CO KG

AI summary

The aim of the invention is to provide a binder mixture, by which means the application range, more particularly of the PIM method, is expanded in terms of the moulded parts thereby produced. To this end, such a mixture is provided, comprising at least one polymer compound A, selected from a group comprising polyolefins, in a quantity in a range of approximately 10 wt. % to approximately 60 wt. % of the total quantity of binder mixture, with a first softening range and a first melt viscosity; at least one polymer compound B in a quantity of approximately 10 wt. % to approximately 65 wt. % of the total quantity of binder mixture, with a second softening range and a second melt viscosity; and at least one non-polymer compound C in a quantity of approximately 10 wt. % to approximately 65 wt. % of the total quantity of binder mixture. The first softening range of compound A and the second softening range of compound B are between approximately 80°C and approximately 200°C; the second melt viscosity of compound B is approximately 2 times to 100 times higher than the first melt viscosity of compound A; and compound B and compound C can be dissolved in a solvent, selected from a group comprising acetone, xylene, turpentine, tetrahydrofuran and/or ethyl acetate, within a temperature range of between approximately 20°C and approximately 90°C.