Binder Solution for All-Solid-State Batteries

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Solution Overview

Problem

All-solid-state batteries face limitations in energy density and output compared to conventional lithium ion batteries, and the addition of binders to electrodes can reduce uniformity and ion transmission in these batteries.

Innovation Solution

A binder solution comprising a polymer binder, a first solvent, and an ion-conductive additive, including lithium salt and a second solvent, is used to enhance binding and ion transmission in electrodes, allowing for larger electrodes and higher-temperature operation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If a binder is added to the electrode to provide binding force between components, then the binding strength is improved, but the uniformity of the electrode and ion transmission are reduced

Engineering Contradiction:
Improvebinding strengthVSAvoidelectrode uniformity
Core Design Contradiction:
StrengthVSManufacturing precision

Solution Approach 1:

The patent changes the chemical composition parameters of the binder solution by incorporating specific ratios of cyclic carbonate and chain carbonate solvents, along with lithium salt additives. This parameter optimization allows the binder to provide adequate binding strength while maintaining electrode uniformity and ion transmission pathways, resolving the contradiction between binding strength and uniformity

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses a composite binder solution system combining polymer binder, cyclic carbonate solvent, chain carbonate solvent, and lithium salt additive. This composite formulation achieves both binding function and ion conductivity, allowing the electrode to maintain uniformity while providing sufficient binding force between active material and solid electrolyte

Inventive Principle:
Principle #40Composite materials

2Quantity of substance

If the electrode size is increased to improve battery capacity, then the charge and discharge capacity is improved, but the manufacturing complexity and time increase

Engineering Contradiction:
Improvebattery capacityVSAvoidmanufacturing time
Core Design Contradiction:
Quantity of substanceVSLoss of time

Solution Approach 1:

The patent optimizes the viscosity and composition parameters of the binder solution to enable effective coating and formation of large-area electrodes. The controlled solvent ratios and additive concentrations allow for uniform distribution over large areas, increasing battery capacity while maintaining efficient manufacturing processes without excessive time loss

Inventive Principle:
Principle #35Parameter changes

3Strength

If the binder solution contains high polymer concentration to improve binding, then the binding strength is improved, but the ion transmission path formation is impeded

Engineering Contradiction:
Improvebinding strengthVSAvoidion transmission
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent creates a composite binder solution where polymer binder is combined with cyclic carbonate, chain carbonate, and lithium salt additives. This composite system maintains appropriate viscosity and ion conductivity even at effective binding concentrations, ensuring both strong binding and reliable ion transmission paths in the electrode

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The lithium salt and carbonate solvents act as intermediaries in the binder solution, facilitating ion transmission while the polymer provides binding. This intermediary system allows the binder to function effectively without impeding ion pathways, resolving the contradiction between binding strength and ion transmission reliability

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution significantly increases the charge and discharge capacity and lifespan of all-solid-state batteries, enabling their use in high-temperature environments and reducing manufacturing time.

Implementation Method 1

the binder solution includes a polymer binder, a first solvent, and an ion-conductive additive. The ion-conductive additive may include lithium salt and a second solvent

Methodology Applied
Scientific EffectIon conduction: Conduction (electrical)

Implementation Method 2

a lithium element of the lithium salt may exist in the state of being bonded with the oxygen element in the second solvent

Methodology Applied
Scientific EffectCoordinate bonding: Chemical Bonding

Data Source

PatentUS11652210B2Binder solution for all-solid-state batteries, electrode slurry including the binder solution, and method of manufacturing all-solid-state battery using the electrode slurry
Publication Date: 2023.05.16 HYUNDAI MOTOR CO LTD
  • US11652210B2 patent drawing
  • US11652210B2 patent drawing
  • US11652210B2 patent drawing

AI summary

The present disclosure relates to a binder solution for all-solid-state batteries. The binder solution includes a polymer binder, a first solvent, and an ion-conductive additive, wherein the ion-conductive additive includes lithium salt and a second solvent, which is different from the first solvent.