Bio-based MEG Composition for Transparent PET Bottles

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Solution Overview

Problem

Conventional polyethylene terephthalate (PET) production relies on petrochemical sources, which do not meet the growing consumer demand for bio-based and sustainable alternatives, and results in PET bottles with lower transparency compared to bio-based PET bottles.

Innovation Solution

The development of bio-based monoethylene glycol (MEG) compositions, produced from plant sources such as sugar cane, corn, and agricultural waste, which are then reacted with terephthalic acid to form bio-based PET, incorporating minor diol components that enhance transparency and processability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If conventional petrochemical-based MEG is used to produce PET, then the production process is well-established and cost-effective, but the product transparency is lower and it does not meet consumer demand for bio-based alternatives

Engineering Contradiction:
Improveproduction process maturityVSAvoidproduct transparency
Core Design Contradiction:
Ease of manufactureVSIllumination intensity

Solution Approach 1:

The patent changes the chemical composition parameters of MEG by incorporating specific C3-C12 1,2-diols (1,2-propanediol, 1,2-butanediol, 1,2-pentanediol) in controlled amounts (1-5000 ppm each). This compositional modification transforms the optical properties of the final PET product, achieving superior transparency while maintaining the condensation reaction process with terephthalic acid.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite MEG composition by combining conventional MEG with minor amounts of specific diol components derived from bio-based sources. This composite approach allows the mixture to exhibit enhanced optical properties (transparency) while maintaining the fundamental chemical reactivity needed for PET synthesis, effectively merging the benefits of established processing with improved product properties.

Inventive Principle:
Principle #40Composite materials

2Illumination intensity

If bio-based MEG is produced from plant sources, then consumer demand for sustainable products is met and transparency is improved, but the production process becomes more complex

Engineering Contradiction:
Improveproduct transparencyVSAvoidproduction process complexity
Core Design Contradiction:
Illumination intensityVSDevice complexity

Solution Approach 1:

The patent extracts and isolates specific diol components (C3-C12 1,2-diols) from bio-based feedstocks and incorporates them in precisely controlled concentrations (1-5000 ppm). This extraction approach allows the beneficial optical properties to be achieved while avoiding the need to completely redesign the production process, as the core condensation reaction with terephthalic acid remains unchanged.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent applies local quality modification by introducing specific diol components only in minor amounts (trace concentrations) rather than completely replacing MEG. This localized modification targets the specific property (transparency) that needs improvement while leaving the bulk composition and fundamental reaction pathway intact, thereby minimizing process complexity.

Inventive Principle:
Principle #3Local quality

3Illumination intensity

If pure MEG is used without additional diol components, then the polyester composition is simple and consistent, but the transparency and optical properties are inferior

Engineering Contradiction:
ImprovetransparencyVSAvoidcomposition simplicity
Core Design Contradiction:
Illumination intensityVSStability of the object's composition

Solution Approach 1:

The patent modifies the compositional parameters of MEG by adding specific diol components at controlled concentrations. This parameter change transforms the optical properties (transparency) of the final PET product while maintaining composition stability through precise specification of component ranges (1-5000 ppm for each diol type), ensuring reproducible results.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Bio-based PET bottles exhibit significantly lower transmission haze percentages compared to petroleum-based PET bottles, making them more transparent and aligning with consumer preferences for clear visibility, while also being produced from renewable resources.

Implementation Method 1

contacting the C4-C12 alpha,beta-unsaturated carboxylic acid with a catalyst system and hydrogen to produce a saturated C4-C12 carboxylic acid

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 2

Conventional PET polyester is usually produced from the condensation reaction of terephthalic acid with monoethylene glycol (MEG)

Methodology Applied
Scientific EffectCondensation reaction: Condensation

Data Source

PatentUS11352463B2Bio-based MEG and polyester compositions and methods of making the same
Publication Date: 2022.06.07 CHANGCHUN MEIHE SCI & TECH DEV CO LTD
  • US11352463B2 patent drawing
  • US11352463B2 patent drawing

AI summary

Disclosed are bio-based mono-ethylene glycol (MEG) compositions containing from about 1 ppm to about 5000 ppm of at least one C3-C12 1,2-diol, bio-based polyester compositions made therefrom, and methods of making the same are disclosed. Preforms and blow-molded polyester containers prepared from the bio-based MEG and polyester are described.