Bio-Based Microcapsule Shells for Stable Controlled Release

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Solution Overview

Problem

Existing encapsulated compositions struggle to balance robustness, biodegradability, and benefit-agent release properties while using sustainable and biodegradable materials, failing to meet 'clean label' requirements and consumer safety expectations.

Innovation Solution

The encapsulated composition comprises a core-shell microcapsule with a shell formed by a combination of a bio-based polymeric surfactant, aminosilane, a bio-based and biodegradable hydrocolloid, and a linker derived from a bio-based epoxy resin, enhancing stability and controlled release.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional shell materials are used to ensure robustness and stability, then microcapsule stability is improved, but biodegradability and sustainability deteriorate

Engineering Contradiction:
Improvemicrocapsule stabilityVSAvoidbiodegradability
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent employs a composite shell system combining multiple bio-based polymers (pectin, hydroxyethyl cellulose, gelatin) with crosslinking agents and surfactants. This composite approach allows the shell to achieve both robustness through intermolecular crosslinking and biodegradability through natural polymer composition, resolving the contradiction between stability and environmental compatibility.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies the physical and chemical parameters of bio-based polymers through controlled crosslinking (changing molecular structure), adjustment of polymer ratios, and modification of functional groups. These parameter changes enable the shell to achieve optimal balance between mechanical stability and biodegradation rate, allowing both robustness and sustainability to coexist.

Inventive Principle:
Principle #35Parameter changes

2Object-generated harmful factors

If bio-based and biodegradable materials are used to meet clean label requirements, then sustainability is improved, but robustness and leak resistance deteriorate

Engineering Contradiction:
ImprovebiodegradabilityVSAvoidmicrocapsule robustness
Core Design Contradiction:
Object-generated harmful factorsVSReliability

Solution Approach 1:

The patent introduces intermediary substances including crosslinking agents (isocyanates, polyfunctional isocyanates) and surfactants that mediate between the bio-based polymers. These intermediaries facilitate intermolecular crosslinking and stabilize the shell structure, preventing leakage while maintaining the biodegradable nature of the base polymers.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

By creating a multi-component composite system combining pectin, hydroxyethyl cellulose, gelatin, crosslinking agents, and surfactants, the patent achieves synergistic effects where the combination provides both robustness (through crosslinking network) and biodegradability (through natural polymer composition), resolving the contradiction between sustainability and structural integrity.

Inventive Principle:
Principle #40Composite materials

3Reliability

If shell materials are made more impervious to prevent leakage, then microcapsule stability is improved, but benefit agent release control deteriorates

Engineering Contradiction:
Improvemicrocapsule stabilityVSAvoidrelease control
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The patent creates a dynamic shell system where the crosslinked network can undergo structural changes in response to environmental stimuli such as pH, temperature, or enzyme action. This dynamic behavior allows the shell to maintain imperviousness during storage (preventing leakage) while enabling controlled release of the benefit agent under specific conditions, resolving the contradiction between stability and release control.

Inventive Principle:
Principle #15Dynamics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition achieves improved biodegradability, robustness, and effective benefit-agent release, meeting 'clean label' standards and consumer safety expectations.

Implementation Method 1

a polymeric stabilizer that is formed by combination of a bio-based polymeric surfactant with at least one aminosilane

Methodology Applied
Scientific EffectSurfactant: Surfactant

Implementation Method 2

a linker derived from a bio-based and biodegradable epoxy resin

Methodology Applied
Scientific EffectChemical Bonding: Chemical Bonding

Data Source

PatentUS12539261B2Encapsulated compositions
Publication Date: 2026.02.03 GIVAUDAN SA
  • US12539261B2 patent drawing

AI summary

The present invention provides an encapsulated composition comprising at least one core-shell microcapsule, wherein the at least one core-shell microcapsule comprises a core comprising at least one benefit agent and a shell surrounding the core, wherein the shell comprises:a) a polymeric stabilizer that is formed by combination of a bio-based polymeric surfactant with at least one aminosilane;b) a bio-based and biodegradable hydrocollolid; andc) a linker derived from a bio-based and biodegradable epoxy resin.The invention also provides a method for preparing the encapsulated composition, a consumer product comprising the encapsulated composition and the use of the encapsulated composition to improve the perception or enhance the performance of the benefit agent in a consumer product.