Bio-Based Liquid Crystalline Polymer for High-Flow Molding

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Solution Overview

Problem

Current high flow liquid crystalline polymer compositions used in electrical components are not sustainable, as they are derived from crude oil, and there is a need for carbon-neutral alternatives that maintain high flow properties.

Innovation Solution

A polymer composition is developed using a bio-LCP matrix with monomers derived from bio-naphtha, which achieves low melt viscosity and high melting temperature, along with excellent mechanical and flame retardant properties, by carefully controlling the composition and processing conditions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If high flow LCP compositions are used to achieve fast filling and low molded-in stress, then productivity and dimensional stability are improved, but carbon emissions increase due to crude oil-based raw materials

Engineering Contradiction:
Improvefilling rateVSAvoidcarbon emissions
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The patent changes the source parameter of raw materials from petroleum-based to bio-based (bio-naphtha derived), maintaining the chemical structure and flow properties while altering the environmental impact parameter to achieve carbon neutrality

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent converts the traditionally harmful petroleum extraction process into a beneficial bio-based process where plant oils are transformed into high-performance polymer feedstocks, turning environmental harm into environmental benefit while maintaining technical performance

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

2Object-generated harmful factors

If bio-based materials are used to reduce carbon emissions, then sustainability is improved, but melt viscosity and flow properties may deteriorate

Engineering Contradiction:
Improvecarbon emissionsVSAvoidflow properties
Core Design Contradiction:
Object-generated harmful factorsVSReliability

Solution Approach 1:

The patent carefully controls the molecular weight and chemical composition parameters of the bio-based monomers to match those of conventional petroleum-based LCPs, ensuring that melt viscosity and flow properties remain within the required range for high-performance molding

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite polymer system combining bio-based monomers with specific liquid crystalline polymer structures, leveraging the self-organizing properties of liquid crystals to achieve both sustainability and superior flow characteristics

Inventive Principle:
Principle #40Composite materials

Data Source

PatentUS20250011591A1Sustainable, High Flow Liquid Crystalline Polymer Composition
Publication Date: 2025.01.09 TICONA LLC
  • US20250011591A1 patent drawing
  • US20250011591A1 patent drawing
  • US20250011591A1 patent drawing

AI summary

A polymer composition that comprises a polymer matrix containing a first liquid crystalline polymer that includes one or more monomers derived from bio-naphtha is provided. The polymer composition exhibits a melt viscosity of about 60 Pa-s or less as determined in accordance with ISO 11443:2021 at a shear rate of 1,000 seconds−1 and temperature that is 15° C. higher than the melting temperature of the composition.