Bio-based Polyamide for Sustainable Material Production

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Solution Overview

Problem

Current polyamides used in manufacturing various items, such as contact lenses and motor vehicle fittings, rely on fossil-based materials, contributing to environmental concerns by releasing CO2 back into the atmosphere upon disposal, and lack sustainable development considerations.

Innovation Solution

Development of polyamides incorporating renewable starting materials like vegetable oils and natural polysaccharides through polycondensation with cycloaliphatic diamines and bio-derived aliphatic dicarboxylic acids, ensuring a high content of organic carbon from sustainable sources, thereby reducing CO2 emissions and aligning with sustainable development goals.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-generated harmful factors

If fossil-based materials are used in polyamide production, then mechanical properties and durability are maintained, but CO2 emissions increase and environmental sustainability deteriorates

Engineering Contradiction:
ImproveCO2 emissionsVSAvoidmaterial durability
Core Design Contradiction:
Object-generated harmful factorsVSReliability

Solution Approach 1:

The patent changes the origin parameter of the dicarboxylic acid from fossil-based to renewable/bio-based, transforming the environmental characteristics of the polyamide while maintaining its mechanical and durability properties through careful selection of renewable acid components

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates composite polyamide materials combining cycloaliphatic diamines with renewable dicarboxylic acids, producing a new material class that integrates the durability of traditional polyamides with the sustainability of bio-based components

Inventive Principle:
Principle #40Composite materials

2Object-generated harmful factors

If renewable starting materials are used in polyamide production, then environmental sustainability improves, but material availability and consistency may worsen

Engineering Contradiction:
ImproveCO2 emissions reductionVSAvoidmaterial availability
Core Design Contradiction:
Object-generated harmful factorsVSEase of manufacture

Solution Approach 1:

The patent modifies the source parameter of raw materials from fossil to renewable origins, achieving carbon cycle sustainability while establishing quality standards to ensure manufacturing consistency

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces renewable dicarboxylic acids as intermediary components that bridge between natural renewable resources and the final polyamide product, enabling sustainable material production with controlled and consistent properties

Inventive Principle:
Principle #24Intermediary (Mediator)

3Duration of action of stationary object

If polyamides are designed for long-term durability, then product lifetime increases, but CO2 sequestration duration increases and end-of-life emissions worsen

Engineering Contradiction:
Improveproduct lifetimeVSAvoidend-of-life CO2 emissions
Core Design Contradiction:
Duration of action of stationary objectVSObject-generated harmful factors

Solution Approach 1:

The patent changes the carbon origin parameter from fossil to renewable sources, transforming the carbon cycle behavior of the material so that even long-duration products return CO2 to the atmosphere rather than adding fossil carbon, effectively resolving the end-of-life emissions issue while maintaining durability

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of renewable materials in polyamide production reduces CO2 emissions by at least 44% compared to fossil-based polyamides, aligning with sustainable development objectives and providing materials with comparable mechanical, chemical, and thermal properties.

Implementation Method 1

Transparent amorphous polyamides obtained by polycondensation of diamines and of diacids

Methodology Applied
Scientific EffectPolycondensation: Chemical Bonding

Data Source

PatentUS9599512B2Polyamide, composition comprising such a polyamide, and uses thereof
Publication Date: 2017.03.21 ARKEMA FRANCE SA
  • US9599512B2 patent drawing
  • US9599512B2 patent drawing
  • US9599512B2 patent drawing

AI summary

The invention relates to a polyamide comprising at least one repeat unit corresponding to the general formulation: X·Y in which: X represents a cycloaliphatic diamine and Y represents an aliphatic dicarboxylic acid chosen from dodecanedioic (C12) acid, tetradecanedioic (C14) acid and hexadecanedioic (C16) acid, characterized in that said dicarboxylic acid comprises organic carbon of renewable origin, determined according to Standard ASTM D6866. The invention also relates to a composition comprising this polyamide and also to the use of this polyamide and of such a composition.