Biocide Activation via Chemical Reaction for Safe Storage

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Solution Overview

Problem

The oil and gas industry faces challenges in safely storing, transporting, and handling biocides due to their hazardous nature, and there is a need for biocides to be activated only when needed to prevent microbial growth and hydrogen sulfide production in wells, which can be corrosive and foul treatment fluids.

Innovation Solution

Converting an inactive biocide into an active biocide through a chemical reaction with an activating agent, such as a reduction-oxidation reaction, acid, or base, allowing for safe storage and handling, and reversing the process with a deactivating agent after use.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If biocides are stored and handled in active form, then microbial growth prevention is effective, but safety risks and environmental harm increase

Engineering Contradiction:
Improvebiocide effectivenessVSAvoidsafety risks
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The biocide is prepared in advance in an inactive form for safe storage and transport, then converted to active form just before application. This preliminary preparation in a safe state resolves the contradiction by maintaining effectiveness while eliminating safety risks during storage and handling.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The biocide undergoes chemical parameter changes between inactive and active forms. By changing the chemical state parameter, the substance can be safely stored in one form and become effective in another, resolving the contradiction between safety during storage and effectiveness during use.

Inventive Principle:
Principle #35Parameter changes

2Object-affected harmful factors

If biocides are stored in inactive form, then safety during storage is improved, but activation timing and control become more complex

Engineering Contradiction:
Improvesafety during storageVSAvoidactivation control
Core Design Contradiction:
Object-affected harmful factorsVSDevice complexity

Solution Approach 1:

A chemical activating agent serves as an intermediary that converts the inactive biocide to active form. This intermediary mechanism simplifies activation control by using a straightforward chemical reaction rather than complex control systems, resolving the contradiction between safety and control complexity.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The biocide system performs self-activation through chemical reaction with the activating agent, eliminating the need for external control mechanisms. This self-service approach reduces device complexity while maintaining safety during storage.

Inventive Principle:
Principle #25Self-service

3Reliability

If biocides are used continuously, then microbial growth is prevented, but environmental impact and safety risks increase

Engineering Contradiction:
Improvemicrobial growth preventionVSAvoidenvironmental impact
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The biocide is activated periodically only when needed for microbial growth prevention, rather than continuously. This periodic activation maintains effectiveness while reducing environmental impact and safety risks during periods when the biocide is inactive.

Inventive Principle:
Principle #19Periodic action

Solution Approach 2:

The inactive biocide can be discarded or recovered after use, eliminating persistent environmental contamination. This approach reduces environmental impact while maintaining effective microbial growth prevention during the active period.

Inventive Principle:
Principle #34Discarding and recovering

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables safe storage, transportation, and handling of biocides, ensuring they are only active when needed, reducing safety risks and environmental impact while effectively preventing microbial growth and hydrogen sulfide production in wells.

Implementation Method 1

The chemical reaction can be a reduction-oxidation reaction

Methodology Applied
Scientific EffectReduction-oxidation reaction: Redox Reactions

Implementation Method 2

The chemical reaction can be a reduction-oxidation reaction or a reaction with an acid or a base

Methodology Applied
Scientific EffectAcid-base reaction:

Data Source

PatentUS8791054B2Methods of converting an inactive biocide into an active biocide using a chemical reaction
Publication Date: 2014.07.29 HALLIBURTON ENERGY SERVICES INC

AI summary

A method of converting an inactive biocide into an active biocide comprises: contacting the inactive biocide with an activating agent, wherein the activating agent is capable of chemically reacting with the inactive biocide; and causing or allowing a chemical reaction to take place between the inactive biocide and the activating agent, wherein the chemical reaction produces the active biocide. The methods can also include deactivating the active biocide via a chemical reaction between the active biocide and a deactivating agent.