Biodegradable Battery Barrier Layer for Moisture Retention

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Solution Overview

Problem

Conventional biodegradable batteries face challenges such as low ionic conductivity, lengthy manufacturing processes, and moisture retention issues due to the use of non-biodegradable materials and thick foil pouches, which limit their compatibility with high-throughput printing processes and increase environmental waste.

Innovation Solution

A biodegradable electrochemical device with a water vapor barrier using polylactic acid and a metalized coating, which includes multiple layers to reduce water vapor transmission rates, thereby improving moisture retention and extending the device's service life while maintaining biodegradability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-generated harmful factors

If conventional biodegradable polymer electrolytes are used, then the battery can be biodegradable, but the ionic conductivity is low and manufacturing process is lengthy

Engineering Contradiction:
Improveenvironmental wasteVSAvoidmanufacturing throughput
Core Design Contradiction:
Object-generated harmful factorsVSProductivity

Solution Approach 1:

The patent changes the physical and chemical parameters of the polymer electrolyte by using radiatively curable compositions that can be rapidly cured at room temperature or elevated temperatures. This transforms the manufacturing process from slow solvent evaporation (hours) to rapid radiative curing (minutes), enabling high-throughput printing while maintaining biodegradability through the use of biodegradable polymers like PCL, PLA, PHB, and starch-based polymers.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces the traditional solvent evaporation mechanism (thermal/mechanical process requiring hours) with radiative curing (optical/chemical process completing in minutes). This substitution enables compatibility with high-throughput printing processes while maintaining the biodegradable nature of the electrolyte through careful selection of radiatively curable biodegradable polymers and initiators.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Reliability

If thick non-biodegradable foil pouches are used to seal batteries, then moisture retention is improved, but biodegradability is compromised

Engineering Contradiction:
Improvemoisture retentionVSAvoidenvironmental waste
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent employs composite material structures where thin biodegradable polymer layers are combined with metalized coatings (such as aluminum) to create an effective moisture barrier. This composite approach provides sufficient moisture protection for battery operation while maintaining overall biodegradability, as the biodegradable polymer matrix can decompose and the metal coating can be recovered or disposed of separately, avoiding the need for thick non-biodegradable foil pouches.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent uses thin biodegradable polymer films instead of thick foil pouches, relying on the metalized coating to provide the primary moisture barrier function. This thin-film approach reduces material usage and maintains flexibility while achieving adequate moisture protection for the electrochemical device, enabling biodegradability without sacrificing reliability.

Inventive Principle:
Principle #30Flexible shells and thin films

3Ease of manufacture

If solvent evaporation is used to produce polymer electrolyte, then solid polymer electrolyte film is formed, but the process takes several hours

Engineering Contradiction:
Improveelectrolyte film formationVSAvoidevaporation time
Core Design Contradiction:
Ease of manufactureVSLoss of time

Solution Approach 1:

The patent replaces the slow thermal evaporation process with rapid radiative curing using UV or other radiative energy sources. This substitution transforms the electrolyte formation process from a hours-long evaporation process to a minutes-long curing process, enabling high-throughput manufacturing while maintaining the quality of solid polymer electrolyte films through controlled radiative crosslinking or polymerization of biodegradable monomers and oligomers.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent changes the fundamental mechanism of electrolyte film formation from solvent removal (evaporation) to polymerization/crosslinking (radiative curing). This parameter change enables rapid processing compatible with high-throughput printing, as the radiatively curable composition transforms from a liquid or soft gel state to a solid electrolyte film in minutes rather than hours, while maintaining biodegradability through careful material selection.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively reduces water vapor transmission rates, enhancing the longevity of biodegradable batteries by preventing moisture loss and maintaining environmental sustainability through the use of biodegradable materials.

Implementation Method 1

a water vapor barrier which may include a biodegradable material and a metalized or aluminum metalized coating

Methodology Applied
Scientific EffectReflection: Reflection

Implementation Method 2

the water vapor barrier is disposed to prevent water vapor escaping from the electrochemical device

Methodology Applied
Scientific EffectPermeation barrier: Permeation

Data Source

PatentUS20240178490A1Biodegradable electrochemical device with barrier layer
Publication Date: 2024.05.30 XEROX CORP
  • US20240178490A1 patent drawing
  • US20240178490A1 patent drawing
  • US20240178490A1 patent drawing

AI summary

An electrochemical device is disclosed and may include an electrolyte composition disposed between the anode and the cathode and a water vapor barrier which may include a biodegradable material, where the water vapor barrier is disposed to prevent water vapor escaping from the electrochemical device. The water vapor barrier further may include poly lactic acid or a metalized coating. The water vapor barrier further may further include multiple layers and have a water vapor transmission rate (WVTR) less than or equal to 2 wt % over 24 hours. Embodiments of the water vapor barrier may also include a polymeric biodegradable material or a metalized coating disposed onto the biodegradable material. The water vapor barrier may also include multiple layers and may have a water vapor transmission rate (WVTR) less than or equal to 1 mg per cm2 over 24 hours.