Biodegradable Cellulose Acetate Films for Industrial Composting

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Solution Overview

Problem

There is a global issue with waste disposal, particularly of non-biodegradable consumer plastics that accumulate in landfills, leading to environmental concerns, prompting a need for recyclable, reusable, or compostable alternatives for single-use products like plastics, straws, and packaging materials.

Innovation Solution

A biodegradable cellulose acetate composition is developed, comprising cellulose acetate, a plasticizer, and additional components such as fillers, additives, or biodegradable polymers, which is melt-processable and can be formed into films that disintegrate over 90% within 12 weeks under industrial composting conditions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If conventional plastics are used for single-use products, then manufacturing cost and performance are maintained, but environmental persistence and waste accumulation worsen

Engineering Contradiction:
Improveenvironmental persistenceVSAvoidproduct performance
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent uses composite materials by combining cellulose acetate with biodegradable polymers (PLA, PHA, PCL) and various additives to create a material that maintains the mechanical performance needed for single-use products while ensuring biodegradability and compostability. This resolves the contradiction by integrating multiple material functions into a single composite system that addresses both performance and environmental concerns.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies the chemical composition parameters of the material by controlling the degree of substitution of cellulose acetate (DS 1.5-2.5) and incorporating specific ratios of biodegradable polymers (0-50 wt%). These parameter changes enable the material to achieve both adequate mechanical properties for product functionality and enhanced biodegradation rates, thus resolving the contradiction between performance and environmental persistence.

Inventive Principle:
Principle #35Parameter changes

2Object-affected harmful factors

If biodegradable polymers are added to cellulose acetate, then compostability improves, but manufacturing complexity increases

Engineering Contradiction:
ImprovecompostabilityVSAvoidmanufacturing process complexity
Core Design Contradiction:
Object-affected harmful factorsVSDevice complexity

Solution Approach 1:

The patent segments the material formulation into distinct functional components: cellulose acetate as the base polymer, biodegradable polymers (PLA, PHA, PCL) as compostability enhancers, and various additives (plasticizers, stabilizers, fillers) for property optimization. This segmentation allows each component to be selected and processed independently, simplifying the overall manufacturing process while achieving the desired compostability.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent optimizes manufacturing by controlling specific parameters: biodegradable polymer content (0-50 wt% of total polymer), plasticizer content (10-25 wt%), and processing temperature ranges. These parameter specifications provide clear manufacturing guidelines that reduce process complexity while ensuring consistent compostability performance across production batches.

Inventive Principle:
Principle #35Parameter changes

3Ease of manufacture

If plasticizer content is increased to improve processability, then melt processability improves, but mechanical strength decreases

Engineering Contradiction:
Improvemelt processabilityVSAvoidmechanical strength
Core Design Contradiction:
Ease of manufactureVSStrength

Solution Approach 1:

The patent optimizes plasticizer content within the specific range of 10-25 wt% of total composition, which provides adequate melt processability for manufacturing while maintaining sufficient mechanical strength for single-use product applications. This parameter optimization resolves the contradiction by identifying the optimal balance point where both processability and strength requirements are satisfied.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite materials by combining cellulose acetate with reinforcing biodegradable polymers (particularly PHA and PCL) that compensate for the strength reduction caused by plasticizer addition. This composite approach allows the formulation to achieve both good processability (through plasticizers) and adequate mechanical strength (through reinforcing polymers) simultaneously.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The cellulose acetate composition effectively addresses the need for biodegradable and compostable single-use products by ensuring high disintegration rates in composting environments, reducing waste accumulation and environmental impact.

Implementation Method 1

the cellulose acetate composition is biodegradable according ASTM D6400 when tested under industrial composting conditions

Methodology Applied
Scientific EffectBiodegradation: Decomposition (biological)

Implementation Method 2

the film exhibits a disintegration of at least 90 percent within not more than 12 weeks, as measured according to the Disintegration Test Protocol

Methodology Applied
Scientific EffectDisintegration: Decomposition (biological)

Data Source

PatentUS20230045673A1Biodegradable compositions and articles made from cellulose acetate
Publication Date: 2023.02.09 EASTMAN CHEM CO
  • US20230045673A1 patent drawing
  • US20230045673A1 patent drawing

AI summary

Thermoformable and biodegradable cellulose acetate compositions comprising at least one cellulose acetate at least one plasticizer, and at least one additional component chosen from a filler, additive, biodegradable polymer, stabilizer, or odor modifier are disclosed. The compositions are formed into films, sheets, and articles.