Biodegradable Paper Laminate Oxygen Moisture Barrier

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Solution Overview

Problem

Conventional paper-based laminates for packaging are not biodegradable, leading to environmental issues in landfills, and existing biodegradable polymers like PLA and PHA are difficult to process due to moisture and temperature sensitivity.

Innovation Solution

A multi-layered paper-based laminate with biodegradable materials such as polyvinyl alcohol, polylactic acid, and polyhydroxyalkanoate, applied through coextrusion with a primer and fillers like calcium carbonate to achieve oxygen and moisture barrier properties, and using antiblock materials to prevent layer sticking.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional polymeric materials like LDPE, PET, and EVOH are used to coat paper-based substrates to improve barrier properties and physical strength, then the packaging performance is enhanced, but the biodegradability is lost

Engineering Contradiction:
Improvebarrier propertiesVSAvoidnon-biodegradability
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent changes the chemical composition parameters of the polymeric layers from conventional non-biodegradable materials (LDPE, PET, EVOH) to biodegradable alternatives (PLA, PHA, PVOH) while maintaining the barrier functional properties through careful selection and combination of biodegradable polymer types and their coating parameters

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates composite laminates by combining paper-based substrates with multiple biodegradable polymeric layers, where each layer serves specific functions (e.g., PLA for structural integrity, PVOH for moisture barrier, PHA for compostability) to achieve overall biodegradability while maintaining packaging performance

Inventive Principle:
Principle #40Composite materials

2Object-generated harmful factors

If biodegradable polymers like PLA and PHA are used instead of LDPE to improve environmental friendliness, then biodegradability is achieved, but processing difficulty increases due to moisture and temperature sensitivity

Engineering Contradiction:
ImprovebiodegradabilityVSAvoidprocessing difficulty
Core Design Contradiction:
Object-generated harmful factorsVSEase of manufacture

Solution Approach 1:

The patent applies preliminary action by using aqueous primers containing adhesion promoters on the paper substrate before applying biodegradable polymer coatings. This pre-treatment ensures proper adhesion and protects the moisture-sensitive biodegradable polymers during the coating process, facilitating easier manufacturing

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent introduces intermediary substances including aqueous primers with adhesion promoters and potential master batches as processing aids. These intermediaries mediate between the moisture-sensitive biodegradable polymers and the processing environment, enabling easier handling and application while maintaining biodegradability

Inventive Principle:
Principle #24Intermediary (Mediator)

3Reliability

If multiple layers of biodegradable materials are applied to achieve oxygen and moisture barrier properties, then barrier performance is improved, but manufacturing complexity increases

Engineering Contradiction:
Improvebarrier propertiesVSAvoidlaminate structure
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent segments the barrier function into multiple specialized biodegradable layers: one layer optimized for oxygen barrier (e.g., PVOH), another for moisture barrier (e.g., PLA or PHA), and potentially a third for UV protection or additional barrier properties. Each segment addresses specific barrier requirements while maintaining overall biodegradability

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent designs the biodegradable polymeric layers to serve multiple functions simultaneously: structural reinforcement of the paper substrate, oxygen barrier, moisture barrier, and compostability. This multi-functionality reduces the need for additional separate layers, simplifying the overall laminate structure while achieving comprehensive barrier properties

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The laminate is fully biodegradable and compostable, providing effective barrier properties while reducing processing challenges and costs, making it suitable for various packaging applications.

Implementation Method 1

A multi-layered paper-based laminate with biodegradable materials such as polyvinyl alcohol, polylactic acid, and polyhydroxyalkanoate, applied through coextrusion with a primer and fillers like calcium carbonate to achieve oxygen and moisture barrier properties

Methodology Applied
Scientific EffectBarrier properties: Permeation

Implementation Method 2

The laminate is fully biodegradable and compostable

Methodology Applied
Scientific EffectBiodegradation: Decomposition (biological)

Data Source

PatentUS8637126B2Biodegradable paper-based laminate with oxygen and moisture barrier properties and method for making biodegradable paper-based laminate
Publication Date: 2014.01.28 GRAPHIC PACKAGING INTERNATIONAL LLC
  • US8637126B2 patent drawing
  • US8637126B2 patent drawing
  • US8637126B2 patent drawing

AI summary

Biodegradable laminates including biodegradable polymers have oxygen and moisture barrier properties. The oxygen and moisture barrier layers are biodegradable. If the barrier layers have poor adhesion, degradable tie layers can be included to improve adhesion. Combination of laminate structures can be formed to increase the overall oxygen and moisture barrier characteristics. The biodegradable laminates can be formed by extrusion.