Biodegradable Plasticizer Molecular Structure for PLA Durability

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Solution Overview

Problem

Biodegradable plastics, such as polylactic acid, lack durability, heat resistance, impact resistance, and flexibility, and their degradation rates are insufficient, posing environmental concerns due to slow degradation in typical conditions.

Innovation Solution

A biodegradable plasticizer with a molecule structure featuring a benzene derivative or amino acid central structure, connected by amine and carboxyl groups, and grafted with side-chain structures of multiple carbon atoms, forming amide and ester bonds, which enhances biodegradability and compatibility with polyester plastics.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional additives are added to change the flexibility and durability of biodegradable plastics, then the flexibility and durability are improved, but the biodegradation rate remains insufficient and the cost increases

Engineering Contradiction:
Improveflexibility and durabilityVSAvoidbiodegradation rate
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent changes the chemical structure parameters of the additive by introducing a specific molecular structure containing a central structure (benzene derivative or amino acid), two connecting structures (amine group and carboxyl group), and side-chain structures with specific carbon atom ratios. This structural parameter change enables the additive to simultaneously improve flexibility and durability while enhancing biodegradation rate, resolving the contradiction between reliability and productivity.

Inventive Principle:
Principle #35Parameter changes

2Object-affected harmful factors

If biodegradable plastics are used to solve environmental problems, then environmental friendliness is improved, but the degradation rate is too slow for practical application

Engineering Contradiction:
Improveenvironmental harmVSAvoiddegradation time
Core Design Contradiction:
Object-affected harmful factorsVSLoss of time

Solution Approach 1:

The patent introduces a specially structured additive as an intermediary substance that facilitates the degradation process. The additive contains functional groups (amine and carboxyl) that can interact with the plastic matrix and promote hydrolysis, acting as a mediator that accelerates the transformation of biodegradable plastics into harmless substances, thus reducing degradation time while maintaining environmental friendliness.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Shape

If polylactic acid is used for plastic products, then rigidity and transparency are improved, but durability, heat resistance, impact resistance, and flexibility are insufficient

Engineering Contradiction:
Improverigidity and transparencyVSAvoiddurability, heat resistance, impact resistance, and flexibility
Core Design Contradiction:
ShapeVSReliability

Solution Approach 1:

The patent creates a composite material system by combining polylactic acid with a specially designed additive containing a central structure (benzene derivative or amino acid), connecting structures (amine and carboxyl groups), and side-chain structures. This composite structure allows the material to maintain the rigidity and transparency of PLA while incorporating the improved properties (durability, heat resistance, impact resistance, and flexibility) provided by the additive, thus resolving the contradiction between shape and reliability.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The plasticizer improves the durability, heat resistance, and flexibility of biodegradable plastics, accelerating their degradation and ensuring they can safely return to the natural environment without harming it, while being non-toxic and cost-effective.

Implementation Method 1

an amide bond is formed as the at least one side-chain structure connected to the amine group, and an ester bond is formed as the at least one side-chain structure connected to the carboxyl group

Methodology Applied
Scientific EffectHydrolysis: Hydrolysis

Data Source

PatentUS12173135B2Plasticizer and plastic product
Publication Date: 2024.12.24 LARGAN MEDICAL CO LTD
  • US12173135B2 patent drawing
  • US12173135B2 patent drawing
  • US12173135B2 patent drawing

AI summary

A plasticizer, which is biodegradable, has a molecule including a central structure, at least two connecting structures and at least one side-chain structure. The central structure includes at least one of a benzene derivative and at least one amino acid. The connecting structures are respectively connected to the central structure, wherein the connecting structures include a first connecting structure and a second connecting structure. The first connecting structure is an amine group, and the second connecting structure is a carboxyl group. The side-chain structure is a chain of multiple carbon atoms, and the side-chain structure is connected to at least one of the first connecting structure and the second connecting structure. An amide bond is formed as the side-chain structure connected to the amine group, and an ester bond is formed as the side-chain structure connected to the carboxyl group.