Biofuel-Resistant Lubricating Oil Composition

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Solution Overview

Problem

Lubricating oils used in internal combustion engines fueled with biofuels, such as biodiesel and bioethanol, experience increased oxidation due to contamination with biofuel decomposition products, leading to corrosive acid formation and viscosity increase, which shortens their useful life.

Innovation Solution

A lubricating oil composition containing a polybutenyl succinic acylating agent-derived additive, combined with a Group III base stock, is formulated to provide improved antioxidant properties, reducing oxidation and extending the life of the lubricant when used in engines fueled with biofuels.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If lubricating oil is used in engines fueled with biofuels, then the engine can operate with renewable fuel sources, but the lubricating oil experiences increased oxidation and shortened useful life

Engineering Contradiction:
Improveability to use biofuelVSAvoidlubricant useful life
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent applies preliminary action by incorporating specific antioxidant additives into the lubricating oil composition before the oxidation problem occurs. The composition includes additives from groups (i) through (iv) that are pre-formulated to prevent oxidation caused by biofuel decomposition products, rather than attempting to treat oxidation after it begins

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent uses composite materials by creating a lubricating oil composition that combines base oil with multiple types of additives in specific combinations. The composite formulation includes antioxidants, dispersants, and other additives working together to provide enhanced protection against oxidation while maintaining compatibility with biofuel operation

Inventive Principle:
Principle #40Composite materials

2Adaptability or versatility

If biofuel decomposition products are present in the lubricating oil, then the engine can run on biofuel, but corrosive acids form and viscosity increases

Engineering Contradiction:
Improvebiofuel compatibilityVSAvoidlubricant composition stability
Core Design Contradiction:
Adaptability or versatilityVSStability of the object's composition

Solution Approach 1:

The patent applies the intermediary principle by using antioxidant additives as mediators between the biofuel decomposition products and the lubricating oil base. These additives intercept and neutralize the harmful oxidation reactions, preventing corrosive acids from forming and protecting the oil composition from degradation

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent applies parameter changes by carefully controlling the chemical composition parameters of the lubricating oil, including the types and concentrations of antioxidants and other additives. The formulation specifies particular chemical groups and their proportions to maintain composition stability despite the presence of biofuel decomposition products

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The additive significantly enhances the antioxidant properties of the lubricating oil, reducing oxidation and extending its useful life in engines fueled with biodiesel and bioethanol, thereby improving engine performance and reducing maintenance needs.

Implementation Method 1

the presence of biodiesel fuel and the decomposition products thereof in the crankcase lubricant promotes the oxidation of the lubricant

Methodology Applied
Scientific EffectOxidation: Oxidation

Data Source

PatentEP2371932B1A lubricating oil composition
Publication Date: 2018.10.17 INFINEUM INT LTD
  • EP2371932B1 patent drawing
  • EP2371932B1 patent drawing
  • EP2371932B1 patent drawing

AI summary

A lubricating oil composition comprising: (A) an oil of lubricating viscosity in a major amount; (B) an oil-soluble polymeric additive component (B) as an additive in a minor amount. The lubricating oil composition exhibits enhanced oxidative stability when used to lubricate a spark-ignited or compression-ignited internal combustion engine which is fuelled with a biofuel.