Biogas to Liquid Fuel Conversion Process

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Solution Overview

Problem

Current methods for converting biogas to liquid fuel often result in products with particulate emissions and odors, failing to provide a clean-burning alternative to crude oil.

Innovation Solution

A continuous process scheme utilizing a gas-liquid reaction vessel with a transition metal catalyst grid and supplementary gas-phase reaction vessel, where biogas is converted to a liquid hydrocarbon fuel using a liquid petroleum fraction, producing a clean-burning fuel with minimal particulate emissions and odor.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-generated harmful factors

If current methods for converting biogas to liquid fuel are used, then biogas can be converted to liquid fuel, but the product contains particulate emissions and odors

Engineering Contradiction:
Improveparticulate emissions and odorVSAvoidconversion process simplicity
Core Design Contradiction:
Object-generated harmful factorsVSEase of manufacture

Solution Approach 1:

The conversion process is divided into two distinct stages: a gas-liquid reaction stage followed by a gas-phase catalytic stage. This segmentation allows each stage to address specific aspects of the conversion, with the second stage specifically targeting the removal of harmful components that cause particulate emissions and odors.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

A supplementary gas-phase reaction vessel with transition metal catalyst acts as an intermediary stage between the main gas-liquid reactor and the final product. This intermediate processing step transforms harmful byproducts into cleaner components, eliminating particulate emissions and odors without requiring complete redesign of the entire conversion system.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Productivity

If a continuous process is implemented, then prolonged production can be maintained, but additional reactants are needed to supplement liquid level

Engineering Contradiction:
Improvecontinuous production capabilityVSAvoidliquid petroleum fraction consumption
Core Design Contradiction:
ProductivityVSQuantity of substance

Solution Approach 1:

The system maintains continuous operation by implementing a recycle loop where unreacted biogas is captured and returned to the reaction vessel. This continuous circulation allows the process to operate indefinitely without interruption, maintaining steady production rates while minimizing the need for additional liquid petroleum fraction additions.

Inventive Principle:
Principle #20Continuity of useful action

Solution Approach 2:

The system incorporates feedback mechanisms to monitor and control the liquid level in the reaction vessel. Based on this feedback, liquid petroleum fraction is added only when necessary to maintain optimal levels, rather than continuous addition, thereby reducing overall consumption while supporting continuous production.

Inventive Principle:
Principle #23Feedback

3Productivity

If transition metal catalyst is used, then conversion efficiency is improved, but device complexity increases

Engineering Contradiction:
Improvebiogas conversion efficiencyVSAvoidcatalyst system complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The transition metal catalyst serves multiple functions: it catalyzes the main gas-liquid reaction in the primary reactor and also facilitates the secondary gas-phase reactions in the supplementary vessel. This multi-functionality improves overall conversion efficiency while avoiding the need for separate catalyst systems for each stage, thereby limiting the increase in device complexity.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The process efficiently converts biogas to a clean-burning liquid hydrocarbon fuel, significantly reducing particulate emissions and odor, while maintaining a stable operation over prolonged periods with minimal additional reactants.

Implementation Method 1

Mounted inside the reaction vessel are a grid of transition metal catalyst and gas distributors for both the feed gas and the recycle gas

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 2

one such conduit transferring vaporized product from the reaction vessel through a condenser and then to the product vessel

Methodology Applied
Scientific EffectCondensation: Condensation

Data Source

PatentUS8203027B2Continuous process and plant design for conversion of biogas to liquid fuel
Publication Date: 2012.06.19 GUNNERMAN RUDOLF W
  • US8203027B2 patent drawing
  • US8203027B2 patent drawing

AI summary

Biogases such as natural gas and other gases capable of being biologically derived by digestion of organic matter are converted to a clean-burning hydrocarbon liquid fuel in a continuous process wherein a biogas is fed to a reaction vessel where the biogas contacts a liquid petroleum fraction and a transition metal catalyst immersed in the liquid, vaporized product gas is drawn from a vapor space above the liquid level, condensed, and fed to a product vessel where condensate is separated from uncondensed gas and drawn off as the liquid product fuel as uncondensed gas is recycled to the reaction vessel.