Biomass Thermal Depolymerization for Hydrophobic Fuel

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Solution Overview

Problem

Current biomass treatment methods fail to produce stable, dry, and hydrophobic fuels with high energy efficiency for long-term storage, as they are prone to biological degradation and do not facilitate grinding and compression, leading to suboptimal combustion quality.

Innovation Solution

A continuous thermal depolymerization process in a drying column with countercurrent flows, where biomass passes through zones of drying, distillation, and thermal depolymerization at temperatures below 250°C, resulting in irreversible drying and transformation of organic matter, making the biomass hydrophobic and easily compressible.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional biomass treatment methods are used, then biomass can be processed, but the products are prone to biological degradation and cannot be stored long-term

Engineering Contradiction:
Improvestability of biomass productVSAvoidstorage duration
Core Design Contradiction:
ReliabilityVSDuration of action of stationary object

Solution Approach 1:

The patent applies parameter changes by controlling the drying process to achieve specific moisture content thresholds (below 20% or 30% depending on the embodiment) and temperature parameters that induce irreversible structural changes in biomass. These parameter changes transform the biomass from a biodegradable state to a stable, storage-ready state by modifying its physical and chemical properties through controlled thermal treatment.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates composite material structures by combining dried biomass particles with binding agents or treating them to form agglomerates with specific physical properties. This composite approach enhances structural stability and resistance to biological degradation while maintaining the energy content and combustion properties of the original biomass.

Inventive Principle:
Principle #40Composite materials

2Loss of energy

If biomass is not dried thoroughly, then energy is conserved during processing, but the product absorbs moisture from the environment and degrades

Engineering Contradiction:
Improveenergy consumption during dryingVSAvoidmoisture absorption and biological degradation
Core Design Contradiction:
Loss of energyVSObject-affected harmful factors

Solution Approach 1:

The patent implements continuous drying processes where biomass is continuously fed through drying zones with controlled temperature and airflow parameters. This continuous action ensures thorough moisture removal without energy waste from intermittent processing, and the resulting product maintains low moisture content that prevents subsequent moisture absorption and biological degradation during storage.

Inventive Principle:
Principle #20Continuity of useful action

Solution Approach 2:

The patent replaces conventional mechanical drying methods with thermal field-based drying using controlled heat and airflow. This substitution achieves more efficient and uniform moisture removal by utilizing thermal energy transfer and convective airflow patterns, reducing energy consumption while ensuring the biomass reaches moisture levels that prevent hygroscopic behavior.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Shape

If biomass is not treated thermally, then the structure is preserved, but grinding and compression are difficult and combustion quality is suboptimal

Engineering Contradiction:
Improvestructural integrity of biomassVSAvoidgrinding and compression ease
Core Design Contradiction:
ShapeVSEase of manufacture

Solution Approach 1:

The patent applies preliminary thermal treatment to biomass before grinding and compression operations. This pre-treatment partially modifies the structural properties of biomass, making it more brittle and easier to process mechanically. The thermal action creates favorable physical conditions that facilitate subsequent size reduction and densification while preserving sufficient structural characteristics for maintaining combustion quality.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent employs dynamic control of thermal processing parameters, adjusting temperature, duration, and atmosphere conditions to achieve the desired balance between structural modification and preservation. By dynamically optimizing these parameters, the process enhances biomass processability for grinding and compression while maintaining the energy content and combustion characteristics required for high-quality fuel production.

Inventive Principle:
Principle #15Dynamics

4Productivity

If high temperatures are used for drying, then water is removed faster, but organic matter is lost and energy efficiency decreases

Engineering Contradiction:
Improvedrying speedVSAvoidorganic matter loss
Core Design Contradiction:
ProductivityVSLoss of substance

Solution Approach 1:

The patent applies local quality by creating different thermal zones within the drying system, with varying temperature and airflow conditions optimized for specific drying stages. This localized approach allows rapid moisture removal in high-temperature zones while protecting organic matter in lower-temperature zones, achieving high productivity without excessive organic matter loss or energy waste.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent applies partial thermal action by using moderate temperatures for the majority of the drying process, supplemented by brief high-temperature exposure only when necessary to remove bound moisture. This partial action approach achieves sufficient drying speed while minimizing organic matter degradation and energy consumption, avoiding the excessive heating that would cause substance loss.

Inventive Principle:
Principle #16Partial or excessive action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The process produces high-energy fuels that are resistant to biological degradation, allowing for long-term storage and improved combustion quality, with a mass yield of around 90% and maintaining energy content, while eliminating water and organic matter irreversibly.

Implementation Method 1

treatment of non-food biomass in a continuous way by thermal depolymerization according to drying resulting in the irreversibility of the biomass in its structure

Methodology Applied
Scientific EffectThermal depolymerization: Pyrolysis

Implementation Method 2

heat treatment is carried out according to a continuous process using two flows circulating in countercurrent in the drying and thermal depolymerization column

Methodology Applied
Scientific EffectHeat transfer by convection: Convection

Implementation Method 3

allowing the elimination of water from the biomass in an irreversible manner

Methodology Applied
Scientific EffectEvaporation: Evaporation

Data Source

PatentEP2516947B1Continuous method for irreversibly drying lignocellulosic biomass by means of thermal depolymerization
Publication Date: 2016.04.13 AREVA ENERGIES RENOUVELABLES
  • EP2516947B1 patent drawingFigure 1
  • EP2516947B1 patent drawingFigure 2

AI summary

The method for producing a fuel from non-food biomass is characterized in that the method begins with inserting the lignocellulosic biomass in a drying column, followed by moving the biomass from the top to the bottom of the column according to phases corresponding to three consecutive drying areas, then distillation and thermal depolymerization, the latter being carried out at a temperature less than 250° C that enables hemicellulose decomposition and breakdown by modifying the parietal architecture of the lignocellulosic biomass, thus causing suppression of the humidity absorption capacity by the hemicellulose and also causing removal of water from the biomass. The method then involves converting a portion of the organic material by evaporating the volatile organic materials. The method is also characterized in that the heat treatment is carried out according to a continuous process implementing two countercurrent flows flowing within the drying and thermal depolymerization column, namely, a gas flow progressing from the bottom to the top and moreover a solid material flow resulting from the biomass and progressing from the top to the bottom. Said method is moreover characterized in that the thermal depolymerization area is located at the bottom of the drying column or at the upper portion of a lower grating located in the column. Said method is furthermore characterized in that the depolymerization method causes changes in the molecular structure of the biomass by totally removing the water, the obtained materials having an irreversible, dry, hydrophobic structural state and not being modifiable in the structure and composition thereof.