Biomass Pyrolysis Reactor Counter-Current Gas Injection

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Solution Overview

Problem

Existing fast pyrolysis reactors for biomass are complex to control, require large installations, and have low pyrolytic oil yields due to non-isothermal operation and unsuitable particle sizes, leading to inefficient production.

Innovation Solution

A simplified reactor design with counter-current injection of hot neutral gases for rapid pyrolysis of biomass, optimizing heat transfer and reducing gas residence time to preserve condensable vapors, combined with energy integration and valorization of pyrolytic coke, allows for improved pyrolytic oil production.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Device complexity

If conventional fast pyrolysis reactors are used, then pyrolysis can be performed, but the reactors are complex to control and require large installations

Engineering Contradiction:
Improvereactor complexityVSAvoidpyrolytic oil yield
Core Design Contradiction:
Device complexityVSProductivity

Solution Approach 1:

The reactor is divided into distinct functional zones: a fluidized bed reactor for pyrolysis, a separate condenser system for vapor collection, and a coke handling section. This segmentation allows each component to be optimized independently, reducing overall system complexity while maintaining high productivity through specialized functionality in each zone.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Inert gas (nitrogen or carbon dioxide) is introduced as an intermediary medium to fluidize the biomass particles and facilitate heat transfer. This intermediary enables controlled pyrolysis conditions without direct combustion, simplifying temperature control and improving reactor operability while maintaining high conversion efficiency.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If conventional pyrolysis methods are used, then processing can occur, but gas residence time is too long causing thermal cracking and reduced tar preservation

Engineering Contradiction:
Improvetar preservationVSAvoidgas residence time
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The系统设计 enables the pyrolysis gases to rapidly pass through the reaction zone and be quickly quenched in the condenser. By minimizing the residence time of hot gases in the reaction zone and implementing rapid cooling, the system rushes the vapor through before secondary cracking reactions can occur, thereby preserving tar quality and yield.

Inventive Principle:
Principle #21Skipping (Rushing through)

Solution Approach 2:

The condenser is positioned immediately adjacent to the reactor, creating a preliminary cooling action that begins as soon as vapors leave the hot zone. This preliminary cooling prevents prolonged exposure to high temperatures that would cause thermal cracking, preserving the condensable tars before they can undergo unwanted secondary reactions.

Inventive Principle:
Principle #10Preliminary action

3Use of energy by moving object

If non-isothermal operation is used, then pyrolysis can proceed, but heat transfer efficiency is reduced

Engineering Contradiction:
Improveheat transfer efficiencyVSAvoidtemperature uniformity
Core Design Contradiction:
Use of energy by moving objectVSTemperature

Solution Approach 1:

The system employs fluidization technology to dramatically improve heat transfer parameters. By suspending biomass particles in an upward gas flow, the system achieves intense mixing and uniform temperature distribution throughout the bed, transforming the thermal field from non-isothermal to near-isothermal conditions and maximizing heat transfer efficiency.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The fluidized bed maintains continuous contact between hot gases and biomass particles through constant mixing and circulation. This continuous action ensures uniform heat distribution throughout the reaction zone, eliminating temperature gradients and maximizing the efficiency of thermal energy utilization throughout the entire biomass charge.

Inventive Principle:
Principle #20Continuity of useful action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution enhances pyrolytic oil yield and energy efficiency by minimizing thermal cracking and secondary tar formation, achieving high pyrolysis rates and tar preservation, making the process more controllable and scalable.

Implementation Method 1

a reactor (1) for rapid pyrolysis of organic particles (2) of biomass with counter-current injection of hot neutral gases forming a flow (FC) against the current coming into contact with the particles (2) falling by gravity

Methodology Applied
Scientific EffectCounter-current heat transfer: Convection

Implementation Method 2

Pyrolysis is a well-known process in which organic compounds are subjected to high temperatures, for example ranging from 300°C to 1000°C, in an oxygen-poor or oxygen-free environment to avoid oxidation and combustion. Under these conditions, the material dehydrates and then undergoes thermolysis, that is to say thermal decomposition.

Methodology Applied
Scientific EffectThermal decomposition: Pyrolysis

Implementation Method 3

organic particles (2) of biomass with counter-current injection of hot neutral gases forming a flow (FC) against the current coming into contact with the particles (2) falling by gravity

Methodology Applied
Scientific EffectGravitational force: Gravitation

Implementation Method 4

mainly generates pyrolytic vapors, making it possible to obtain oil pyrolytic to the detriment of pyrolytic coke and incondensable gases

Methodology Applied
Scientific EffectCondensation: Condensation

Data Source

PatentEP3173459B1Quick-pyrolysis process of organic particles of biomass with counter-current injection of hot gases
Publication Date: 2020.03.11 COMMISSARIAT A LENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES
  • EP3173459B1 patent drawingFigure 1
  • EP3173459B1 patent drawingFigure 2~4
  • EP3173459B1 patent drawingFigure 3A~3C

AI summary

The main object of the invention is a rapid pyrolysis reactor (1) with entrained flow of organic biomass particles (2), comprising: a reaction chamber (3), an injection device (4) for the particles (2) in the upper part (3a) of the reaction chamber (3), allowing the formation of a gravity-falling flow (FG) of particles (2), an evacuation conduit (5) for the pyrolysis reaction products present in the reaction chamber (3), characterized in that it further comprises a counter-current injection conduit (6) for hot neutral gases in the lower part (3b) of the reaction chamber (3), allowing the formation of a counter-current flow (FG) of hot neutral gases entering into contact with the gravity-falling flow (FG) of particles (2), the temperature of the hot neutral gases being between 500 and 600°C, and the diameter of the particles (2) being between 200 µm and 1 mm.