Bipolar Lead Acid Cell Architecture for Higher Energy Density

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Solution Overview

Problem

Traditional lead acid batteries have limited energy density and specific energy due to the inclusion of non-electrochemically functional metallic lead and conductive links, which increase internal resistance and reduce the utilization efficiency of active materials.

Innovation Solution

The development of a bipolar lead acid battery with a titanium substrate coated in titanium silicide for the positive electrode and a lead-plated copper substrate for the negative electrode, along with a separator and perforated laminations for electrical connectivity, eliminates non-electrochemically functional metallic lead and reduces internal resistance, allowing for increased energy storage capacity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If traditional lead acid battery construction with lead grids and conductive links is used, then reliable operation and good sealing are achieved, but energy density and specific energy are limited due to increased weight and volume of non-electrochemically functional materials

Engineering Contradiction:
Improvereliable operationVSAvoidenergy density
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

The patent removes traditional lead grids and conductive links from the battery structure. Instead, it uses bipolar cells where the separator with electrolyte provides both separation and electrical connectivity between adjacent cells, eliminating the need for separate current collectors and inter-cell connectors. This extraction of non-essential components directly increases energy density by replacing dead weight with active energy storage materials.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The separator in the bipolar cell configuration serves multiple functions simultaneously: it acts as the physical barrier between positive and negative electrodes, provides the electrolyte medium for ion transport, and serves as the current collector that conducts electricity between cells. This multi-functionality eliminates the need for separate components, reducing overall battery mass and volume while maintaining reliable operation.

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Power

If conductive links (lugs and connecting straps) are included in the battery, then electrical connectivity between cells is achieved, but internal resistance increases and power delivery is limited

Engineering Contradiction:
Improvepower deliveryVSAvoidinternal resistance
Core Design Contradiction:
PowerVSLoss of energy

Solution Approach 1:

The patent eliminates traditional conductive links including lugs, straps, and inter-cell connectors. Electrical connectivity is achieved through the bipolar cell architecture where the separator with electrolyte directly conducts current between adjacent cells. This removal of intermediate conductive components reduces the number of electrical interfaces and contact resistances, thereby lowering overall internal resistance and improving power delivery capability.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent merges the functions of the separator and the current collector into a single integrated component. The separator, saturated with electrolyte, simultaneously provides ion transport pathways and electrical conduction between cells. This consolidation eliminates the need for separate conductive links and reduces the total resistance by creating a more direct and fewer-numbered electrical pathway between cells.

Inventive Principle:
Principle #5Merging (Combining)

3Strength

If heavy lead current collectors/substrates are used, then mechanical support for active materials is provided, but utilization efficiency of active mass is reduced and specific energy is limited

Engineering Contradiction:
Improvemechanical supportVSAvoidspecific energy
Core Design Contradiction:
StrengthVSQuantity of substance

Solution Approach 1:

The patent removes traditional heavy lead grids from the electrode structure. Instead, it employs thin bipolar plates with catalytic coatings that serve as current collectors. The active materials are applied directly onto these lightweight bipolar plates, which provide sufficient mechanical support and electrical conductivity without the excessive weight of conventional lead grids, thereby increasing the proportion of active mass and improving specific energy.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent uses composite bipolar plates consisting of conductive substrates with catalytic coatings. These composite structures provide the necessary mechanical strength and electrical conductivity while being significantly lighter than traditional lead grids. The catalytic coatings enhance the electrochemical activity at the bipolar plate surfaces, maximizing the utilization of active materials and improving overall specific energy.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This design achieves higher energy density and specific energy, with energy density of 70 Wh/kg and specific energy of 200 Wh/L at the cell level, and 60 Wh/kg and 150 Wh/L at the battery level, while extending deep discharge cycles to 50 cycles, making it competitive with lithium-ion batteries.

Implementation Method 1

a separator between the negative and positive electrodes, wherein the separator includes an electrolyte for transferring charge between the negative and positive electrodes

Methodology Applied
Scientific EffectIonic conduction: Conduction (electrical)

Implementation Method 2

The positive electrode plate comprises a titanium substrate with a titanium silicide coating thereon

Methodology Applied
Scientific EffectElectrical conduction: Conduction (electrical)

Implementation Method 3

a lead-plated copper substrate for the negative electrode

Methodology Applied
Scientific EffectElectrical conduction: Conduction (electrical)

Data Source

PatentUS11837701B2Bipolar lead acid battery cells with increased energy density
Publication Date: 2023.12.05 ESKRA TECHN PRODS
  • US11837701B2 patent drawing
  • US11837701B2 patent drawing
  • US11837701B2 patent drawing

AI summary

A bipolar lead acid battery with increased energy density is provided. The battery includes a number of lead acid wafer cell that each comprise a negative electrode having a negative electrode plate and a negative active material positioned on the negative electrode plate, as well as a positive electrode having a positive electrode plate and a positive active material positioned on the positive electrode plate. The positive electrode plate comprises a metal foil with a conductive film thereon, such as a titanium foil or substrate with a titanium silicide coating thereon. The lead acid wafer cell also includes a separator between the negative and positive electrodes, wherein the separator includes an electrolyte for transferring charge between the negative and positive electrodes.