Bipolar Plate Intermediate Zone Design for Fuel Cell Reactant Bypass

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Solution Overview

Problem

In electrochemical reactors with membrane electrode assemblies, such as fuel cell stacks and electrolysers, fluid short-circuits occur due to manufacturing tolerances and flow configurations, leading to parasitic flows that do not participate in the electrochemical reaction, and existing solutions complicate manufacturing or alter coolant flow significantly.

Innovation Solution

The design incorporates bipolar plates with conductive sheets, coolant and reactant flow channels, and an intermediate zone with alternating ribs and indentations to reduce short-circuit flows while maintaining coolant storage outside the reactive zone, using complementary shapes and reliefs to manage flow and compression.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If peripheral spaces are maintained between the peripheral gasket and the reactive zone to satisfy manufacturing tolerances, then assembly and positioning tolerances are accommodated, but parasitic short-circuit flows of reactants increase

Engineering Contradiction:
Improvepositioning toleranceVSAvoidparasitic flow
Core Design Contradiction:
Manufacturing precisionVSLoss of energy

Solution Approach 1:

The bipolar plate is divided into multiple functional zones: a reactive zone with flow channels, an intermediate zone with alternating ribs and indentations, and a peripheral zone with the gasket. This segmentation allows the intermediate zone to act as a flow barrier, blocking parasitic reactant flows through the peripheral space while maintaining manufacturing tolerances. The ribs and indentations create a tortuous path that prevents direct short-circuiting of reactants.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The intermediate zone with alternating ribs and indentations serves as an intermediary structure between the reactive zone and the peripheral gasket. This intermediate structure blocks parasitic flows of reactants while allowing coolant to pass through, thus mediating between the conflicting requirements of maintaining peripheral spaces for manufacturing tolerances and preventing energy loss through short-circuit flows.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Loss of energy

If existing solutions are implemented to limit short-circuit flows, then parasitic flows are reduced, but manufacturing complexity increases significantly

Engineering Contradiction:
Improveparasitic flowVSAvoidmanufacturing complexity
Core Design Contradiction:
Loss of energyVSDevice complexity

Solution Approach 1:

The flow channel structure and the short-circuit prevention structure are merged into a single bipolar plate design. The alternating ribs and indentations are integrated directly into the bipolar plate manufacturing process, combining the functions of reactant distribution and parasitic flow blocking in one component, thus avoiding additional manufacturing steps or assembly operations.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The design changes the geometric parameters of the bipolar plate by introducing alternating ribs and indentations in the intermediate zone. These parameter changes create a tortuous flow path that blocks parasitic flows while maintaining compatibility with standard manufacturing processes for bipolar plates, such as embossing or machining, without requiring complex multi-step manufacturing procedures.

Inventive Principle:
Principle #35Parameter changes

3Loss of energy

If existing solutions are implemented to limit short-circuit flows, then parasitic flows are reduced, but coolant flow is significantly altered

Engineering Contradiction:
Improveparasitic flowVSAvoidcoolant flow
Core Design Contradiction:
Loss of energyVSEase of operation

Solution Approach 1:

The alternating ribs and indentations are placed specifically in the intermediate zone between the reactive zone and the peripheral gasket, while leaving the reactive zone flow channels and coolant flow paths unchanged. This localized modification blocks parasitic reactant flows without interfering with the main coolant flow, thus maintaining ease of coolant operation while reducing energy loss.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This design effectively reduces short-circuit flows for both reactants and coolant, maintaining coolant storage outside the reactive zone and minimizing the impact on manufacturing complexity and coolant flow, thereby enhancing the efficiency of electrochemical reactions.

Implementation Method 1

Each cell comprises an electrolytic membrane that allows only protons to pass through and not electrons

Methodology Applied
Scientific EffectIon exchange: Ion Exchange

Implementation Method 2

The bipolar plates are also electrically conductive so as to form collectors of the electrons generated at the anode

Methodology Applied
Scientific EffectElectrical conduction: Conduction (electrical)

Implementation Method 3

The passage of the reactants from an inlet manifold to an outlet manifold, through the flow channels of a reactive zone, induces a pressure drop in this flow

Methodology Applied
Scientific EffectPressure gradient: Pressure Gradient

Data Source

PatentUS10243220B2Bipolar plates for limiting the bypassing of the flow channels by the reactants
Publication Date: 2019.03.26 COMMISSARIAT A LENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES
  • US10243220B2 patent drawing
  • US10243220B2 patent drawing
  • US10243220B2 patent drawing

AI summary

An electrochemical cell includes a membrane electrode assembly and a bipolar plate. The membrane electrode assembly includes a proton exchange membrane and first and second electrodes. The bipolar plate includes conductive sheets, coolant flow channels are made between the conductive sheets. An outer face of a conductive sheet includes reactant flow channels and a first rib extending on the side of the reactant flow channels. A gasket extends on the first rib. The bipolar plate includes an intermediate zone extending between the first rib and the first electrode, a first band in which the sheets have complementary shapes nested one in the other over the entire length of a coolant flow channel, and a second band in which a sheet includes reliefs in contact with the membrane electrode assembly.