Bipyridine-Based Electron Transport Layer for OLED Voltage Reduction

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Solution Overview

Problem

Conventional organic light emitting diodes (OLEDs) have insufficient driving voltage, current density, efficiency, and lifetime characteristics due to the limitations of traditional electron transport layers.

Innovation Solution

The use of bipyridine-based compounds with specific structural modifications, such as Formula 1, which enhance electron transporting capabilities by optimizing the positions of substituents and linkages, is employed in the electron transport layer of OLEDs.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Use of energy by moving object

If conventional electron transport materials (oxadiazole, thiadiazole compounds) are used in OLEDs, then the device structure can be maintained, but the driving voltage is high and efficiency is insufficient

Engineering Contradiction:
Improvedriving voltageVSAvoiddevice performance
Core Design Contradiction:
Use of energy by moving objectVSReliability

Solution Approach 1:

The patent changes the chemical structure parameters of electron transport materials by introducing bipyridine-based compounds with specific molecular configurations (Formula 1 with various substituents R1-R6). This structural parameter change results in improved electron mobility and lower driving voltage while maintaining device reliability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite material strategies by combining bipyridine core structures with various aromatic substituents (phenyl, naphthyl, anthryl groups) to create hybrid electron transport materials that exhibit superior electrical properties compared to conventional single-structure materials

Inventive Principle:
Principle #40Composite materials

2Productivity

If conventional electron transport materials are used, then manufacturing processes remain simple, but current density and efficiency are insufficient

Engineering Contradiction:
Improvecurrent densityVSAvoidmaterial complexity
Core Design Contradiction:
ProductivityVSEase of manufacture

Solution Approach 1:

The patent modifies molecular parameters of electron transport materials through systematic variation of substituents on the bipyridine core, achieving enhanced current density while maintaining compatibility with existing vacuum deposition and solution processing manufacturing techniques

Inventive Principle:
Principle #35Parameter changes

3Duration of action of stationary object

If conventional materials are used in OLEDs, then device structure remains standard, but lifetime characteristics are insufficient

Engineering Contradiction:
Improvedevice lifetimeVSAvoidmaterial structure
Core Design Contradiction:
Duration of action of stationary objectVSDevice complexity

Solution Approach 1:

The patent optimizes molecular parameters of electron transport materials by adjusting substituent positions and types on the bipyridine core, achieving improved device lifetime through enhanced material stability and reduced degradation while maintaining standard OLED device architecture

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach results in OLEDs with lower driving voltage, higher current density, improved efficiency, and extended lifetime, as demonstrated by the comparison of OLEDs using bipyridine-based compounds versus traditional materials.

Implementation Method 1

a bipyridine-based compound has excellent electron transporting capability

Methodology Applied
Scientific EffectElectron transport: Conduction (electrical)

Implementation Method 2

When the excitons drop from an excited state to a ground state, a fluorescent material in the EML emits light

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS9296695B2Bipyridine-based compound and organic light emitting diode employing organic layer comprising the same
Publication Date: 2016.03.29 SAMSUNG DISPLAY CO LTD
  • US9296695B2 patent drawing
  • US9296695B2 patent drawing
  • US9296695B2 patent drawing

AI summary

The invention is directed to bipyridine-based compound and organic light emitting diodes (OLED) including organic layers having the bipyridine-based compound. OLEDs including organic layers having the bipyridine-based compounds can have low driving voltages, high current densities, high efficiencies and long lifetimes.